• Title/Summary/Keyword: evaporation zone

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Se Cracker를 이용하여 제작된 Cu(In,Ga)$Se_2 $ 박막 태양전지의 특성

  • Park, Su-Jeong;Jo, Dae-Hyeong;Kim, Ju-Hui;Jo, Yu-Seok;Yun, Jong-Man;Jeong, Yong-Deok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.427-427
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    • 2012
  • Cu(In,Ga)$Se_2 $ (CIGS) 박막 태양전지는 높은 효율과 낮은 생산 단가로 인해 많은 연구가 이루어지고 있다. 특히, Se flux는 박막의 특성에 가장 중요한 CIGS의 결정성, 결정립 크기, 결정방향을 형성하는데 영향을 주는 것으로 알려져 있다. 일반적인 co-evaporation에 사용되는 Se effusion cell의 경우, 높은 분자가를 가지는 Se 분자들이 공급되기 때문에 낮은 반응성을 보이지만 Se cracker cell을 사용할 경우 Se 분자들이 열적으로 크래킹되어 낮은 분자가를 가지므로 화학적으로 높은 반응성을 가진다. 따라서 적은 양의 Se으로도 양질의 CIGS 박막 제작이 가능하다. 본 연구에서는 Se effusion cell과 cracker cell을 이용하여 CIGS 광흡수층을 제작하였으며, 각각 제작된 CIGS 박막의 특성을 비교하였다. 또한 Se cracker cell의 reservoir zone(R-zone) 온도를 통해 Se flux를 변화시켜 Se flux에 따른 CIGS 박막 태양전지의 특성에 대해 알아보았다. SEM, EDS, XRD 측정을 통해 박막의 특성을 분석하였고, J-V 측정을 통해 태양전지의 특성에 대해 알아보았다. Se cracker를 사용하여 제작된 CIGS 박막의 결정립 크기가 effusion cell로 제작된 박막보다 더 크게 나타났고, Se flux가 증가할수록 결정립의 크기는 증가하였다. Se cracker의 flux가 $0.17{\'{{\AA}}}$/s일 때 반사방지막 없이 13.14%의 효율을 나타내었다.

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Water Balance and Flushing Time in the Restricted Indian River Lagoon (IRL), Florida USA

  • Kim, Young-Taeg
    • Ocean and Polar Research
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    • v.25 no.1
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    • pp.75-87
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    • 2003
  • The water balance calculation in the IRL shows that fresh groundwater discharge is the primary factor, with surface runoff from gaged and ungaged areas as the second freshwater contributor. Precipitation and evaporation are almost in balance fer the entire IRL. Due to high freshwater discharge from ground-water, the annual net flow is outward from the IRL to the continental shelf of the Atlantic Ocean resulting in a relatively short flushing time, denoted as $T_{0.5}$ (50% flushing time) and $T_{0.99}$ (99% flushing time). $T_{0.5}$, and. $T_{0.99}$ without a tidal effect in the Northern IRL are 17 and 114 days, respectively, during the dry season. During the wet season, they are 10 and 65 days, respectively. Tidal flushing effects are considered in central IRL due to the proximity to Sebastian Inlet. In the Northern Central zone during dry season, $T_{0.5}$, and. $T_{0.99}$ are 6 and 43 days, respectively and during the wet season 5 and 33 days. In the Southern Central zone they are 2 and 16 days for the dry season,2 and 15 days for the wet season. High groundwater seepage into the IRL is considered to be a positive effect in maintaining relatively good water quality condition even with few narrow inlets.

Effects of a Flow Guide on the Arcing History in a Thermal Puffer Plasma Chamber (유동 가이드가 열파퍼 플라즈마 챔버의 아크현상 이력에 미치는 영향)

  • Lee, Jong-Chul;Kim, Youn-Jea
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.31 no.10
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    • pp.832-839
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    • 2007
  • The geometry and dimensions of an expansion chamber are decisive factors in thermal puffer plasma chamber designs. Because they together dominate the temperature and speed at which the cooling gas from the chamber flows back through a flow channel to the arcing zone for the successful interruption of fault currents. In this study, we calculated the flow and mass transfer driven by arc plasma, and investigated the effects of a flow guide installed inside a thermal puffer plasma chamber. It is found that the existing cold gas of the chamber mixes with hot gases entrained from the arcing zone and is subjected to compression due to pressure build-up in the chamber. The pressure build-up with the flow guide is larger than that without due to a vortex which rotates clockwise around the chamber center. By the reverse pressure gradient, the mixing gas of the chamber flows back out for cooling down the residual plasma near current zero. In the case with the flow guide, the temperature just before current zero is lower than that without, and the Cu concentration with high electrical conductivity is also less than that without the flow guide.

Development of Two Dimensional Chloride Ion Penetration Model Using Moving Mesh Technique (Moving Mesh Technique을 이용한 2차원 염해 침투 예측 모델의 개발)

  • Choi, Won;Kim, Hanjoong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.57 no.6
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    • pp.1-7
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    • 2015
  • Most of chloride diffusion models based on finite difference method (FDM) could not express the diffusion in horizontal direction at each elevation. To overcome these weakness, two dimensional chloride ion penetration model based on finite element method (FEM) to be able to combine various multi-physics simultaneously was suggested by introducing moving mesh technique. To avoid the generation of mesh being able to be distorted depending on the relative movement of water level to static concrete, a rectangular type of mesh was intentionally adopted and the total number of meshes was empirically selected. The simulated results showed that the contents of surface chloride decreased following to the increase of elevation in the top part of low sea level, whereas there were no changes in the bottom part of low level. In the DuraCrete model, the diffusion coefficient of splashed zone is generally smaller than submerged zone, whereas the trend of Life365 model is reverse. Therefore, it could be understood that the developed model using moving mesh technique effectively reflects $DuraCrete^{TM}$ model rather than $Life365^{TM}$ model. In the future, the model will be easily expanded to be combined with various multi-physics models considering water evaporation, heat of hydration, irradiation effect of sun and so on because it is based on FEM.

Effects of Sm:Ba:Cu Composition Ratio on the Superconducting Properties of SmBCO Coated Conductor Prepared by using a Composition Gradient Method (SmBCO 초전도 선재 특성에 대한 Sm:Ba:Cu 조성비의 영향)

  • Kim, H.S.;Oh, S.S.;Jang, S.H.;Min, C.H.;Ha, H.S.;Ha, D.W.;Ko, R.K.;Youm, D.J.;Moon, S.H.;Chung, K.C.
    • Progress in Superconductivity
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    • v.13 no.1
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    • pp.7-11
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    • 2011
  • The effects of Sm:Ba:Cu composition ratio in SmBCO coated conductor on their superconducting properties were investigated. The SmBCO coated conductors were fabricated by reactive co-evaporation method using EDDC(Evaporation using Drum in Dual Chamber) system. In this system, we could obtain various samples with different composition ratios in a batch by the technique providing composition gradient at deposition zone. From the specimens prepared by EDDC system, we found that composition ratio is uniform parallel to the drum axis, but gradient along the circumferential direction of the drum. We installed a shield having parallelogram open area between the deposition chamber and the evaporation chamber in EDDC system, and attached a 30 cm long template, which is parallel to drum axis, onto the drum surface. In this configuration, we could obtain SmBCO coated conductors having a gradient composition along the length of template. We measured the composition ratios and surface morphologies with periodic interval by SEM and EDAX, and confirmed the profile of composition ratio. We also measured critical current using non-contact Hall probe critical current measurement system and thereby could plot composition ratio vs. critical current. The maximum critical current was obtained, and the surface morphology with the shape of roof tile was observed at the corresponding composition ratio of Sm:Ba:Cu = 1.01:1.99:4.87. It was also found that composition ratio had an effect on not only critical current but also surface morphology.

Role of the Climatological Intertropical Convergence Zone in the Seasonal Footprinting Mechanism of El Niño-Southern Oscillation

  • Jae-Heung Park;Mi-Kyung Sung;Young-Min Yang;Jiuwei Zhao;Soon-Il An;Jong-Seong Kug
    • Journal of Climate Change Research
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    • v.34 no.13
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    • pp.5243-5256
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    • 2021
  • The North Pacific Oscillation (NPO), a primary atmospheric mode over the North Pacific Ocean in boreal winter, is known to trigger El Niño-Southern Oscillation (ENSO) in the following winter, the process of which is recognized as the seasonal footprinting mechanism (SFM). On the basis of the analysis of model simulations from phase 5 of the Coupled Model Intercomparison Project (CMIP5), we found that the SFM acts differently among models, and the correlation between the NPO and subsequent ENSO events, called the SFM efficiency, depends on the background mean state of the model. That is, SFM efficiency becomes stronger as the climatological position of the Pacific intertropical convergence zone (ITCZ) moves poleward, representing an intensification of the northern branch of the ITCZ. When the Pacific ITCZ is located poleward, the wind-evaporation-sea surface temperature (SST) feedback becomes stronger as the precipitation response to the SST anomaly is stronger in higher latitudes than that in lower latitudes. In addition, such active ocean-atmosphere interactions enhance NPO variability, favoring the SFM to operate efficiently and trigger an ENSO event. Consistent with the model results, the observed SFM efficiency increased during the decades in which the northern branch of the climatological ITCZ was intensified, supporting the importance of the tropical mean state of precipitation around the Pacific ITCZ.

Daily Streamfiow Model based on the Soil Water (유역 토양 수분 추적에 의한 유출 모형)

  • 김태일;여재경;박승기
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.33 no.4
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    • pp.61-72
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    • 1991
  • A lumped deterministic model(DAWAST model) was developed to predict the daily streamflow. Since the streamflow is dominantly determined by the soil water storage in the watershed, the model takes the soil water accounting procedures which are based on three linear reservoirs representing the surface, unsaturated, and saturated soil layers. The variation of soil water storage in the unsaturated zone is traced from the soil water balance on a daily basis. DAWAST model consists of 5 parameters for water balance and 3 parameters for routing. A optimization technique of unconstrained nonlinear Simplex method was applied for the determination of the optimal parameters for water balance. Model verification was carried out to the 7 hydrologic watersheds with areas of 5.89-7,126km$^2$ and the results were generally satisfactory. The daily streamflow can be arbitrarily simulated with the input data of daily rainfall and pan evaporation by the DAWAST model at the station where the observed streamflow data of short periods are available to calibrate the model parameters.

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Experimental and Numerical Study on Characteristics of Air-assisted Spray and Spray Flames (2유체 분무의 연소특성에 관한 실험 및 수치 해석적 연구)

  • Kim, Dong-Il;Oh, Sang-Huen
    • Journal of the Korean Society of Combustion
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    • v.3 no.2
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    • pp.51-63
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    • 1998
  • Air-assisted atomizer flames are investigated numerically to study spray structures in nonburning and burning conditions based on experimental data. A PDA is used to measure droplet size, velocity, and number density for both nonburning and burning spray. Computations utilize time-averaged gas-phase equations and $k-{\varepsilon}$ turbulence model for simplicity. The major features of the liquid-phase model are that a SSF approach is used to represent the effect of gas-phase turbulence on droplet trajectories and vaporization, an infinite-diffusion model is employed to represent the transient liquid-phase process. Computation and experiment results show that the droplet acceleration and evaporation proceed quickly in near the atomizer, characterizing high number densities and a strong convective effect. The primary combustion zone, however, is dorminated by the gas phase reaction and exhibits a sheath combustion.

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Development of Combustor for Combustible Hazardous Gas (가연성 유해가스 처리를 위한 연소기 개발)

  • 전영남;채종성;김미환
    • Journal of Korean Society for Atmospheric Environment
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    • v.12 no.4
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    • pp.479-485
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    • 1996
  • Volatile organic compounds are air pollutants exhausting from industrial process, evaporation of solvent, and so on. Most of VOCs are the combustible gas of low calorific value as it is diluted by air. The systems burning such a hazardous gas need to increase enthalpy in order to increase flame stability. In this study an incinerator with reciprocating flow in the honeycomb ceramic has been used for the experiment of VOCs control. By the reciprocating flow system, the enthalpy of combustion gas is effectively regenerated into the enthalpy increases of the combustible gas through the honeycomb ceramic, which provides a heat storage. The position of the reaction zone is strongly dependent on the parameters of mixture velocity and time frequency. Flame front is changed to the point where burning velocity is coincided with burning velocity in the honeycomb ceramic. In this system it is important that flame front should be located symmetrically at the center of honeycomb ceramic for the purpose of increasing the reaction rate at one point. Peak temperature becomes higher with decreasing time frequency, at which the flow direction is regularly reversed.

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Growth Behavior of Heteroepitaxial β-Ga2O3 Thin Films According to the Sapphire Substrate Position in the Hot Zone of the Mist Chemical Vapor Deposition System (미스트화학기상증착 시스템의 Hot Zone 내 사파이어 기판 위치에 따른 β-Ga2O3 이종 박막 성장 거동 연구)

  • Kyoung-Ho Kim;Heesoo Lee;Yun-Ji Shin;Seong-Min Jeong;Si-Young Bae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.36 no.5
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    • pp.500-504
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    • 2023
  • In this study, the heteroepitaxial thin film growth of β-Ga2O3 was studied according to the position of the susceptor in mist-CVD. The position of the susceptor and substrate was moved step by step from the center of the hot zone to the inlet of mist in the range of 0~50 mm. It was confirmed that the average thickness increased to 292 nm (D1), 521 nm (D2), and 580 nm (D3) as the position of the susceptor moved away from the center of the hot zone region. The thickness of the lower region of the substrate is increased compared to the upper region. The surface roughness of the lower region of the substrate also increased because the nucleation density increased due to the increase in the lifetime of the mist droplets and the increased mist density. Therefore, thin film growth of β-Ga2O3 in mist-CVD is performed by appropriately adjusting the position of the susceptor (or substrate) in consideration of the mist velocity, evaporation amount, and temperature difference with the substrate, thereby determining the crystallinity of the thin film, the thickness distribution, and the thickness of the thin film. Therefore, these results can provide insights for optimizing the mist-CVD process and producing high-quality β-Ga2O3 thin films for various optical and electronic applications.