• Title/Summary/Keyword: ethylene-vinyl acetate

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Characteristics of Complex Foaming Composites' Normal Pressure Foaming of Using Rubber and Bio-Degradable Materials

  • Dong Hun Han;Young Min Kim;Dan Bi Lee;Kyu Hwan Lee;Han-Seong Kim
    • Korean Journal of Materials Research
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    • v.33 no.8
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    • pp.323-329
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    • 2023
  • There are many types of foam molding methods. The most commonly used methods are the pressure foaming method, in which foam resin is mixed with a foaming agent at high temperature and high pressure, and the normal pressure foaming method, which foams at high temperature without pressure. The polymer resins used for foaming have different viscosities. For foaming under normal pressure, they need to be designed and analyzed for optimal foaming conditions, to obtain resins with low melt-viscosity or a narrow optimal viscosity range. This study investigated how changes in viscosity, molding temperature, and cross-link foaming conditions affected the characteristics of the molded foam, prepared by blending rubber polymer with biodegradable resin. The morphologies of cross sections and the cell structures of the normal pressure foam were investigated by SEM analysis. Properties were also studied according to cross-link/foaming conditions and torque. Also, the correlation between foaming characteristics was studied by analyzing tensile strength and elongation, which are mechanical properties of foaming composites.

The Compressive Strength and Durability Properties of Polypropylene Fiber Reinforced EVA Concrete (폴리프로필렌 섬유 보강 EVA 콘크리트의 압축강도 및 내구성)

  • Nam, Ki Sung;Sung, Chan Yong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.57 no.4
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    • pp.11-19
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    • 2015
  • The important properties of EVA (ethylene vinyl acetate) redispersible polymer was waterproof, densification of internal pore space of concrete and ball bearing and micro filler. Also, the significant role of polypropylene(PP) fiber was crack control and blockade of movement for deterioration factors. The most studies for EVA were limited in the field of mortar and PP fiber reinforced concrete had been studied in the state of being restricted unit water content, rich mix and mixing much of the fiber without considering construction site. Therefore, the control mix design were applied in ready mixed concrete using 10 % fly ash of total cement weight used in batch plant. On the basis of control mix design, EVA contents ranging from 0 % to 10 % of total cement weight and PP fiber contents ranging from 0 % to 0.5 % of EVA concrete volume were used in the mix designs. The results showed the maximum compressive strength value was measured at EVA 5.0 % and PP fiber 0.1 %, the minimum water absorption ratio was at EVA 10 % and PP fiber 0 %, the durability factor for freezing and thawing resistance was at EVA 5.0 % and PP fiber 0.3 % and the minimum weight reduction ratio of resistance to sulfuric acid attack was at EVA 10 % and PP fiber 0.5 % after curing age 42days. Meanwhile, From these results, PP fiber reinforced EVA concrete would be very benefit, if each optimal mix types were used in hydraulic structures, underground utilities and agricultural structures.

Evaluation of Mechanical Performance and Flame Retardant Characteristics of Biomass-based EVA Composites using Intumescent Flame Retardant Technology

  • Park, Ji-Won;Kim, Hoon;Lee, Jung-Hun;Jang, Seong-Wook;Kim, Hyun-Joong
    • Journal of the Korean Wood Science and Technology
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    • v.46 no.2
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    • pp.189-201
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    • 2018
  • Intumescent system is a highly effective flame retardant technology that takes advantage of the mechanism of foaming and carbonization. In order to materialize Intumescent system, it is necessary to use reinforcement material to improve the strength of the material. In this study, we used kenaf as a natural fiber to manufacture intumescent/EVA (ethylene vinyl acetate) composites to improve mechanical and flame retardant performance. Finally two materials with different particle shape are applied to one system. Therefore, the influence factors of the particles with different shapes on the composite material were analyzed based on the tensile test. For this purpose, we have used the tensile strength analysis model and confirmed that it can only act as a partial strength reinforcement due to weak binding force between the matrix and particles. In the combustion characteristics analysis using cone calorimeter and UL 94, the combustion characteristics were enhanced as the content of Intuemscent was increased. As the content of kenaf increased, combustion characteristics were strengthened and carbonization characteristics were weakened. Through the application of kenaf, it can be confirmed that elastic modulus improvement and combustion characteristics can be strengthened, which confirmed the possibility of development of environmentally friendly flame retardant materials.

A Study for impact absorption function of midsole in Cushioned Marathon Shoes (충격흡수용 마라톤화(Cushioned Shoes) 개발을 위한 중창·하지의 충격흡수기능 연구 -마라톤화 연구의 과거 & 현재를 중심으로-)

  • Park, Seung-Bum;Seo, Kuk-Woong;Kim, Yong-Jae
    • Korean Journal of Applied Biomechanics
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    • v.12 no.1
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    • pp.89-114
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    • 2002
  • The purpose of this study was to analyze impact absorption function of midsole in cushioned marathon shoes. The foot is made up of a complex interaction of bones, ligaments, and muscles. These structures help the foot alternate between being a mobile, flexible adaptor and a stable rigid lever. The foot is broken down into two functional parts, the forefoot and the rearfoot. Cushioned marathon shoes for high arches have generous cushioning for efficient and high-mileage runners. Cushioned marathon shoes are made for feet that have high arches or no excessive motion and don't roll inward or roll outward. This condition is known as underpronation. Especially, Cushioned marathon shoes are designed to reduce shock and generally have the softest (or most cushioned) midsoles and the least medial support. They are usually built on a semicurved or curved last to encourage foot motion, which is helpful for underpronators (who have rigid, immobile feet). Cushioning marathon shoes recommended for the high-arched runner, whose foot may roll outward (supinate) rather than the natural slight inward roll, or whose feet may be relatively rigid. Cushioning shoes emphasize flexibility and usually are built on a curved or semicurved last to encourage a normal motion of the foot. Cushioning shoes usually offer no medial (inner foot) support. Cushioned marathon shoes have the single-density midsole, which is stable and relatively firm for a cushioned shoe, stays the same. But the forefoot is more rounded, and the rearfoot now includes a new and supportive rearfoot cradle. A foam midsole, perhaps with layers of different densities, to provide cushioning and shock absorption. EVA (ethylene vinyl acetate) and PU (polyurethane), the materials from which these foams usually are made. EVA is slightly softer than PU. EVA and PU may be layered together in a shoe, or a shoe may have more than one density of EVA.

Microstructure Control and Mechanical Properties of Continuously Porous SiC-Si3N4 Composites (연속다공질 SiC-Si3N4 복합체의 미세구조 및 기계적 특성)

  • Paul Rajat Kanti;Gain Asit Kumar;Lee Hee-Jung;Jang Hee-Dong;Lee Byong-Taek
    • Korean Journal of Materials Research
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    • v.16 no.3
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    • pp.188-192
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    • 2006
  • The microstructures and mechanical properties of continuously porous $SiC-Si_3N_4$composites fabricated by multi-pass extrusion were investigated at different Si levels added. Si-powder with different weight percentages (0%, 5%, 10%, 15%, 20%) was added to the SiC powder to make the raw mixture powders, with $6wt%Y_2O_3-2wt%Al_2O_3$ as sintering additives, carbon ($10-15{\mu}m$) as a pore-forming agent, ethylene vinyl acetate as a binder and stearic acid ($CH_3(CH_2)_{16}COOH$) as a lubricant. In the continuously porous $SiC-Si_3N_4$ composites, $Si_3N_4$ whiskers like the hairs of nostrils were frequently observed on the wall of the pores. In this study, the morphology of the $Si_3N_4$ whiskers was investigated with the silicon addition content. In the composites containing of 10 wt% Si, a large number of $Si_3N_4$ whiskers was found at the continuous pore regions. In the sample to which 15 wt% Si powder was added, maximum values of about 101 MPa bending strength and 57.5% relative density were obtained.

Microstructures Of Continuously Porous SiC-Si3N4 Composites Fabricated Using Waste SiC Sludge (폐 SiC 슬러지를 이용하여 제조한 연속다공질 SiC-Si3N4 복합체의 미세조직)

  • Gain Asit Kumar;Lee Hee-Jung;Jang Hee-Dong;Lee Byong-Taek
    • Korean Journal of Materials Research
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    • v.15 no.3
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    • pp.177-182
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    • 2005
  • Large amounts of the waste SiC sludge containing small amounts of Si and organic lubricant were produced during the wire cutting process of the single silicon crystal ingots. The waste SiC sludge was purified by the washing process and the purified SiC powders were used to fabricate continuously porous $SiC-Si_3N_4$ composites using a fibrous monolithic process, in which carbon, $6wt\%\;Y_2O_3-2\;wt\%\;A1_2O_3$ and ethylene vinyl acetate were added as a pore-forming agent, sintering additives, and binder, respectively. In the burning-out process, carbon was fully removed and continuously porous $SiC-Si_3N_4$ composites were successfully fabricated. The green bodies containing SiC, Si particles and sintering additives were nitrided at $1410^{\circ}C$ in a flowing $N_2+10\%\;H_2$ gas mixture. Continuously porous composites were combined with SiC, ${\alpha}Si_3N_4,\;\beta-Si_3N_4$ and a few $\%$ of Fe phases. The pore size of the 2nd and the 3rd passed $SiC-Si_3N_4$ composites was $260\;{\mu}m$ and $35\;{\mu}m$ in diameter, respectively.

Durability of Polymers for Cement Modifier in Autoclave Cure (오토클래이브양생에 의한 시멘트 혼화용 폴리머의 내구성)

  • Joo, Myung-Ki;Lee, Youn-Su
    • Journal of the Korea Concrete Institute
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    • v.15 no.6
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    • pp.888-893
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    • 2003
  • The purpose of this study is to make clear the durability of the polymer films formed in the autoclaved polymer-modified mortars and concretes. The polymer films prepared with polymer dispersions such as a styrene-butadiene rubber (SBR) latex, a poly (ethylene-vinyl acetate)(EVA) emulsion and a polyacrylic ester (PAE) emulsion for polymeric admixtures are exposed to autoclaving at 18$0^{\circ}C$ in temperature and 1.01 MPa in vapor pressure, and subjected to tensile test and infrared spectroscopy. The durability of the polymer films is evaluated from the application of autoclaving to the polymer films under saturated Ca(OH)$_2$ solution immersion causes no degradation for SBR films and a significant degradation due to the saponification of the polymers for EVA and PAE films. Accordingly, in the application of autoclaving to polymer-modified mortars and concretes, it is suggested that SBR-modified mortars and concretes are hardly degraded but EVA- and PAE-modified mortars and concretes are markedly degraded by the saponification of the polymers.

Preparation of a Novel PU-LMO Adsorbent by Immobilization of LMO on Polyurethane Foam for Recovery of Lithium Ions (폴리우레탄 폼에 LMO를 고정화하여 리튬이온 회수를 위한 새로운 PU-LMO 흡착제의 제조)

  • You, Hae-Na;Lee, Min-Gyu
    • Clean Technology
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    • v.20 no.3
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    • pp.277-282
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    • 2014
  • In this study, PU-LMO was made by immobilization of LMO on urethane foam (PU) with using an EVA as a binder. PU-LMO was characterized by using X-Ray Diffractometer (XRD) and Scanning Electron Microscopy (SEM). The optimal ratio of EVA/LMO for preparation of PU-LMO was 0.26 gEVA/gLMO. The adsorption of lithium ions by PU-LMO was found to follow the pseudo-second-order kinetic model. The equilibrium data fitted well with Langmuir isotherm model and the maximum removal capacity of lithium ions was 17.09 mg/g. The PU-LMO was found to have a remarkably high selectivity of lithium ions and high adsorption capacity because the distribution coefficient ($K_d$) of lithium ion was higher than those of other metal ions.

The Scattering Property of EVA/SiO2 Composite Film Formed Micro-aggregation Structure for Roll-to-roll Process (Roll-to-roll 적용 가능한 마이크로 응집 구조를 갖는 EVA/SiO2 복합 필름의 산란 특성)

  • Jo, Kuk Hyun;Yang, Jun Yeong;Lee, Si Woo;Park, Eun Kyoung;Choi, Geun Seok;Song, Ki Won;Kim, Hyo Jung
    • Textile Coloration and Finishing
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    • v.30 no.3
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    • pp.190-198
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    • 2018
  • We fabricated high transmission and high scattering poly(ethylene-co-vinyl acetate)(EVA) films embedding $SiO_2$ nanoparticles to improve outcoupling efficiency in organic display. The 800nm diameter $SiO_2$ nanoparticles aggregated and formed $1.56{\mu}m$ (with ${\pm}0.853{\mu}m$ standard deviation) diameter microparticles in EVA. The total transmission of scattering film was 83.3% on Polyethylene terephthalate(PET), which was higher than reference 82.8% PET substrate. The diffuse transmission and haze of the $SiO_2$ embedded EVA film were 76.1% and 91.4%, respectively. The optimized condition was 1:1 weight ratio of $SiO_2$ nanoparticles to EVA in Tetrahydrofuran(THF) solution. When the ratio of $SiO_2$ was larger than 1, the total transmission decreased by the increase in backscattering of light due to high scattering. With the optimized condition, we could succeed to fabricate a large scale film(35m in length) with a roll-to-roll process.

Enhanced Bioavailability of Ambroxol by Transdermal Administration of the EVA Matrix Containing Penetration Enhancer in Rats

  • Choi, Jun-Shik;Shin, Sang-Chul
    • Biomolecules & Therapeutics
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    • v.18 no.1
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    • pp.106-110
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    • 2010
  • The pharmacokinetics and bioavailability of ambroxol, an expectoration improver and mucolytic agent, were studied to determine the feasibility of enhanced transdermal delivery of ambroxol from the ethylene-vinyl acetate (EVA) matrix system containing polyoxyethylene-2-oleyl ether as an enhancer in rats. The ambroxol-010 matrix system (15 mg/kg) was applied to abdominal skin of rats. Blood samples were collected via the femoral artery for 28 hrs and the plasma concentrations of ambroxol were determined by HPLC. Pharmacokinetic parameters were calculated using Lagran method computer program. The area under the curve (AUC) was significantly higher in the enhancer group ($1,678{\pm}1,413.3\;ng/ml{\cdot}hr$) than that in the control group $1,112{\pm}279\;ng/ml{\cdot}hr$), that is treated transdermally without enhancer, showing about 151% increased bioavailability (p<0.05). The average $C_{max}$ was increased in the enhancer group ($86.0{\pm}21.5\;ng$/ml) compared with the control group ($59.0{\pm}14.8\;ng$/ml). The absolute bioavailability was 13.9% in the transdermal control group, 21.1% in the transdermal enhancer group and 18.1% in the oral administration group compared with the IV group. The $T_{max}$, $K_a$, MRT and $t_{1/2}$ of ambroxol in transdermal enhancer group were increased significantly (p<0.01) compared to those of oral administration. As the ambroxol-EVA matrix containing polyoxyethylene-2-oleyl ether and tributyl citrate was administered to rats via the transdermal routes, the relative bioavailability increased about 1.51-fold compared to the control group, showing a relatively constant, sustained blood concentration. The results of this study show that ambroxol-EVA matrix could be developed as a transdermal delivery system providing sustained plasma concentration.