• Title/Summary/Keyword: ether alcohol

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Performance Study of Membrane Capacitive Deionization Installed with Sulfonated Poly(ether ether ketone) and Poly(vinyl amine)/poly(vinyl alcohol) Membranes (Sulfonated Poly(ether ether ketone) 및 Poly(vinyl amine)/poly(vinyl alcohol) 혼합막이 장착된 막결합형 축전식 탈염공정의 성능 연구)

  • Kim, Ka young;Rhim, Ji Won
    • Membrane Journal
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    • v.26 no.1
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    • pp.62-69
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    • 2016
  • In this study, sulfonated poly(ether ether ketone) (SPEEK) as cation exchange membrane and blended and crosslinked poly(vinyl amine) (PVAm) with poly(vinyl alcohol) (PVA) membrane as anion exchange membrane were used and then the performance experiments of the membrane capacitive deionization (MCDI) installed with both membranes were carried out. The newly prepared anion exchange membrane were characterized through water content, ion exchange capacity and FT-IR. The crosslinking time of 3 h to 5 h indicated that the salt removal was reduced from 81.3, 65.7% to 53.8%. The effect of PVAm contents from 40, 60, to 80% on the salt removal was shown 81.3, 75.2 and 37.7%, respectively. As a result, it was concluded that the crosslinking time and the content of PVAm had an influence on the salt removal efficiency.

The Effect of Korean Ginseng Components on the Alcohol Fermentation by Zymomonas mobilis (인삼성분이 Zymomonas mobilis의 알코올 발효에 미치는 영향)

  • 김준형;정동효;양재원
    • Microbiology and Biotechnology Letters
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    • v.13 no.3
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    • pp.213-221
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    • 1985
  • The effects of ginseng extract, crude saponin and ether layer fraction on the alcohol fermentation and the growth of Zymomonas mobilis studied. The growth of Zymomonas mobilis was inhibited by the addition of ginseng extract, crude saponin and ether layer fraction, of which the last was shown to have the most inhibitory effect. The pH cultural broth recorded a significant decrease during 36 hrs alcohol fermentation, followed by a slower decrease in pH after 36 hrs. The alcohol fermentation was stimulated most remarkably by the addition of 0.305% crude saponin, while inhibited most by the addition of 0.228% ether layer fraction.

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서울귀룽나무 잎의 배당체에 관한 연구 제1보

  • 한구동
    • YAKHAK HOEJI
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    • v.2 no.1_2
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    • pp.1-8
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    • 1953
  • The leaves of prunus padus L. var. Seoulensis Nakai distributed widely in Korea, were extracted with boiling alcohol(95%) after being mixed with calcium carbonate. The aqueous solution distilled off alcohol from the above filtered extract under the reduced pressure was evaporated to the dryness. The residue was extracted with acetic ether on the water-bath and the acetic ether solution extract was allowed to stand for a weck after removing out of acetic ether almostly, then a colorless necdles were Crystalized out which has the following characteristics : $C_{14}$ $H_{17}$ $O_{6}$ N, began to melt at 138-139.deg. bitter taste [.alpha.]$_$ $D^{20}$ ]=-26.99.deg. soluble in water, alcohol acetone acetic ether etc. slightly soluble in chloroform. It was proved to be identical with prunasine due to above characteristics and determination of Benzal-dehyde HCN and glucose respectively which was obtained on hydrolysis of this glycoside with emulsine.

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Synthesis and Photopolymerization of Vinyl Ether and Epoxy-Functionalized Silicones

  • Pyun, Sang-Yong;Kim, Whan-Gi
    • Macromolecular Research
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    • v.11 no.3
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    • pp.202-205
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    • 2003
  • The reactive precursors, vinyl ethers, and epoxy-silicones, were synthesized. The vinyl ether monomers were prepared from primary alcohol and ethyl vinyl ether with mercury (II) acetate. The epoxy-functionalized silicones have been achieved by the controlled, rhodium-catalyzed, chemoselective hydrosilation of vinyl ether with siloxanes or silane. It was shown that the hydrosilation proceeds exclusively at the vinyl ether group of alkenyl vinyl ether without participation at the alkenyl group. The photoinduced cationic polymerization of these monomers was studied and found to be all highly reactive.

Pharmacognostical Studies on the Rhizome of Polygonum robustum Nakai (왕둥굴레의 생약학적연구(生藥學的硏究))

  • Kim, Joung-Kyu;Lee, Yong-Joo
    • Korean Journal of Pharmacognosy
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    • v.11 no.2
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    • pp.69-74
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    • 1980
  • The rhizome of Polygonatum robustum Nakai (Liliaceae) has been used as a crude drug for the purpose of tonic and thirst cure in Korea. The dried rhizomes were extracted with hot ether, then the residue was extracted with hot alcohol. 1) The three kinds of chemical constituents, substance, I, II and III were isolated by silicagel column chromatography from ether and alcohol extracts of the rhizomes. Substance I was confirmed as ${\beta}-sitosterol$, $C_{29}H_{50}O$ by mass and IR spectroscopy. Substance II was identified as stigmasterol by GLC. 2) Substance III was obtained by crystallization from the column chromatography of alcohol fraction. It was suggested as diosgenin based on chemical and spectral discussions. 3) The concentration of blood sugar was significantly decreased in the group administered the ether extract with 20% dextrose and adrenaline in comparison to that of 20% dextrose and adrenaline along.

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Synthesis and Photopolymerization Characterization of Propenyl Ether Monomers (프로페닐 에테르 단량체들의 합성과 광중합 특성)

  • Kim, Ki-Sang;Shim, Sang-Yeon
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.2
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    • pp.203-209
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    • 2017
  • The propenyl ether-type monomers which are applicable for cationic photo-polymerization were synthesized by the condensation reaction of mono and di-functional alcohol with allyl bromide. To examine photo-curable reactivity, these monomers were combined with cationic photoinitiator to prepare coating composition. As a result, the initial rate of polymerization of POMB in mono propenyl ether type was 10.2, which was relatively lower than BPOB in di-propenyl ethers type. However, POMB containing 1.5mol% photoinitiator almost quantitatively reacted within 90 seconds. In addition, Sulfonium salt type photo-initiators containing long-alkyl group showed good solubility with monomers and apperaed to have comparatively higher rate of polymerization and conversion ratio when applying DPSA and DPST which have high acidity on all monomers.

Effect of Methyl tert-butyl Ether and Its Metabolites on the Microbial Population: Comparison of Soil Samples from Rice Field, Leek Patch and Tidal Mud Flat (다양한 토양 환경에서 Methyl tert-Butyl Ether와 그의 대사산물이 노출되었을 때 미생물 군집에 미치는 영향: 논, 밭, 갯벌 시료 비교)

  • Cho, Won-Sil;Cho, Kyung-Suk
    • Journal of Environmental Health Sciences
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    • v.34 no.6
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    • pp.403-413
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    • 2008
  • Toxic effect of methyl tert-butyl ether (MTBE), tert-butyl alcohol (TBA) and formaldehyde (FA) on microbial activity and diversity was compared in rice field, leek patch, and tidal mud flat soil samples. MTBE, TBA and FA with different concentrations were added into microcosms containing these soil samples, and placed at room temperature for 30 days. Then the microbial activities such as dehydrogenase and viable cell numbers and microbial community using a DGGE (Denaturing gradient gel electrophoresis) fingerprinting method were measured. Among the samples, dehydrogenase activity in rice field was inhibited the most by MTBE, TBA and FA. The toxic effect was higher according to the following orders: FA > MTBE > TBA. Dominant species in the microcosms contaminated with MTBE, TBA and FA were Chloroflex, Bacilli, gamma-proteobacteria in the rice field sample, Sphingobacteria, Flavobacteria, Actinobacteria, Bacilli, gamma-proteobacteria in the leek patch sample, and Sphingobacteria, Flavobacteria, delta-proteobacteria, gamma-proteobacteria in the tidal mud flat sample.

Effect of Ether-Typed Alcohols on Pore Formation in Preparing an Asymmetrically Porous Polysulfone Membrane (다공성 폴리술폰 비대칭막 제조시 에테르형 알코올의 공경형성에 미치는 영향)

  • Choi, Yong-Jin;Kang, Byung-Chul
    • Membrane Journal
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    • v.20 no.2
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    • pp.135-141
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    • 2010
  • Various asymmetric Polysulfone membranes were prepared for a MBR process. Ether-typed alcohols (co-solvent) were added into a dope solution in order to control the pore size of membrane, whose effect on water permeability were investigated. Pore size of the prepared membranes were more affected by molecular-structure of co-solvent than by boiling point of theirs. With the increasing order of methoxy ($CH_3$-O-) < secondary propanol ($-CH_2$-CH(OH)$-CH_3$) < ethoxy ($CH_3-CH_2$-O-), water permeability of the prepared membrane increased. The phenomenon might attribute to the difference of molecularly steric hinderance of co-solvent (eg, Methoxy propanol, Ethoxy ethanol, Methoxy ethanol) in dope solution during the phase inversion. By the addition of ether typed alcohol into a dope solution, the pore size of MF (microfiltration) could be controlled. Also, Membrane prepared was applied to a MBR process and the system was stably operated for 2 months.

Enzymatic Formation of Guaiacylglycerol 8-O-4'-(Coniferyl Alcohol) Ether from Coniferyl Alcohol with Enzyme Preparations of Eucommia ulmoides

  • Alam, Md. Shameul;Katayama, Takeshi;Suzuki, Toshisada;Sultana, Deeder;Sultana, Saima;Hossain, Md. Daud
    • Journal of Crop Science and Biotechnology
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    • v.11 no.1
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    • pp.45-50
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    • 2008
  • Lignans and neolignans are optically active plant secondary metabolites. Research on biosynthesis of lignans has already been advanced especially for the formation of (+) pinoresinol but information on the biosynthesis of 8-O-4'- neolignans is still limited. Moreover, the chemical structure(position of substituents on aromatic rings) and stereochemistry of 8-O-4' neolignans is not clear. Katayama and Kado discovered that incubation of cell-free extracts from E. ulmoides with coniferyl alcohol in the presence of hydrogen peroxide gave (+)-erythro- and (-)-threo- guaiacylglycerol 8-O-4'-(coniferyl alcohol) ether (GGCE)(diastereomeric ratio, 3:2) which is the first report on enzymatic formation of optically active -8-O-4' neolignans from an achiral monolignol. In this aspect, enzymatic formation of guaiacyl 8-O-4' neolignan is noteworthy to clarify its stereochemistry from incubation of coniferyl alcohol with enzyme prepared from Eucommia ulmoides. In this experiment, soluble and insoluble enzymes prepared from E. ulmoides were incubated with 30 mM coniferyl alcohol(CA) for 60 min. The enzyme catalyzed GGCE, dehydrodiconiferyl alcohol(DHCA), and pinoresinol identified by reversed phase HPLC. Consequently, diastereomeric compositions of GGCE were determined as erythro and threo isomer. Enantiomeric composition was determined by the chiral column HPLC. Both enzyme preparations enantioselectively formed (-)-erythro, (+)-erythro and (+)-threo, (-)-threo-GGCEs respectively.

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A Study on the Growth Inhibition of Human Colon Cancer Cells by Eucommial Lea Extract (두충의 인체 암세포 증식억제 효과 연구)

  • 황우익
    • The Korean Journal of Food And Nutrition
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    • v.5 no.1
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    • pp.13-22
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    • 1992
  • This study was divised to observe the inhibitory effect of growth rate of human colon cancer cells by Eucommial leaf extract, in vitro. Three species of human colon cancer cells, HRT-18, HCT-48 and HT-29, were used for the experiment. Each extract of Eucommial leaf was prepared by extraction with water, 95% alcohol, acetone, chloroform and petroleum ether, and then the inhibitory effect of each extract on the growth rate of cells was compared with control group and each other. The experimental results obtained are summarized as follows; 1. Inhibitory effects on growth rate of human colon cancer fells were strongest in the petroleum ether extract and next in the chloroform extract. 2. Inhibitory effects on the growth rate of the cancer cells by extracts of water, 95% alcohol and acetone were weaker than that of petroleum ether and chloroform. 3. Inhibitory effect of each extract on the cancer cell growth was shown most strong activity in HT-29, and was in order of HRT 18 and HCT-48. In view of the results, it could be suggested that inhibitory effects of non-polar solvent's extracts against the cancer cell growth were more stronger than that of polar solvents and the effects were indicated difference according to the species of the cells.

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