• 한국안전학회지
• /
• 제21권1호
• /
• pp.59-64
• /
• 2006

In this study, adsorption characteristics of PCBs on granular activated carbon were experimentally investigated in a batch reactor and in a fixed bed reactor. Granular activated carbon removed above 98.4% of initial concentration, 1000mg/L, of PCBs. It was estabilished that the adsorption equilibrium of PCBs on granular activated carbon was more successfully fitted by Freundlich isotherm equation in the concentration range from 1 to 1000mg/L. Because Freundlich parameter, ${\beta}$ is 0.346, removall treatment of PCBs by activated carbon accounts for the fact that toxicity reduction can be achieved through this process. Appearance time of breakthrough curve is faster with the increase flow rate and inflow concentration of liquid. The utility of granular activated carbon is enhanced with the increase of bed height and with the decrease of inflow rate.

• 상하수도학회지
• /
• 제20권1호
• /
• pp.63-70
• /
• 2006

Biosorption characteristics were investigated at various temperature and pH conditions in order to establish lead(II) removal using Zoogloea ramigera 115SLR. Biosorption equilibrium isotherms and kinetics were obtained from batch experiments. The Freundlich and Langmuir model could be described the biosorption equilibrium of lead(II) on Z. ramigera 115SLR, Ca-alginate bead and immobilized Z. ramigera 115SLR. The maximum biosorption capacity of Z. ramigera 115SLR increased from 325 to 617mg $pb^{2+}/g$ biomass as temperature increased from 288.15 K to 308.15K from the Langmuir model. Fixed-bed column breakthrough curves for lead(II) removal were also obtained. For regeneration of the biosorbent, complete lead(II) desorption was achieved using 5mM HCl in fixed-bed column. This study shows the possibilities that well-treated immobilized Z. ramigera 115SLR with the mechanical intensity like TEOS (Tetraethyl orthosilicate) treatment and the optimum acid solution for desorption can be used for the effective treatment for lead(II) containing wastewater.

• 대한토목학회논문집
• /
• 제11권3호
• /
• pp.85-93
• /
• 1991

실트질 접토의 심강(沈降) 특성(特性)에 미치는 초기농도(初期濃度)($C_o$) 및 저면전단응력(底面剪斷應力)(${\tau}_b$)의 효과에 대한 연구를 하기 위해 황해안 영광해역에서 채취한 실트질 점토를 사용하여 순환식 개수로에서 퇴적실험(堆積實驗)을 하였다. 상대농도(相對濃度) $C/C_o$(C=수심 평균한 농도) 및 상대평형농도(相對平衡濃度) $C_{eq}/C_o$($C_{eq}$=평형상태에서 수심 평균한 농도)는 저면전단응력(底面剪斷應力)에 강하게 좌우되며, 초기농도(初期濃度)에는 큰 영향을 받지 않는 것으로 나타났고, 또한 이들 값은 저면전단응력(底面剪斷應力)이 클수록 증가하였다. 황해안 영광해역 퇴적물(堆積物)의 퇴적한계저면전단응력(堆積限界底面剪斷應力)의 최소치는 ${\tau}_{bmin}{\simeq}0.017N/m^2$, 퇴적한계저면전단응력(堆積限界底面剪斷應力)의 최대치는 ${\tau}_{bmax}{\simeq}1.25N/m^2$이며, 이들 값은 퇴적물(堆積物)의 구성성분에 강하게 좌우된다. ${\tau}_b{\geq}{\tau}_{bmin}$ 범위에서 상대농도(相對濃度)($C_{eq}/C_o$)와 겉보기 중앙심강속도(中央沈降速度)($W_{s50}{^{\prime}}$)에 대한 식을 유도하였다. 겉보기 중앙심강속도(中央沈降速度)는 초기농도(初期濃度)보다 저면전단응력(底面剪斷應力)에 훨씬 더 강한 영향을 받고, 저면전단응력(底面剪斷應力)이 증가할수록 지수적으로 감소하였다.

• 한국환경과학회지
• /
• 제16권8호
• /
• pp.907-912
• /
• 2007

Ion exchange resin was used to remove silica ion at ultralow concentration. The effects of temperature, type of ion exchange resin and single/mixed-resin systems on removal efficiency were estimated. As temperature increased, the slope of concentration profile became stiff, and the equilibrium concentration was higher. In the single resin system, the removal of silica was continued up to 400 min, but the silica concentration was recovered to initial concentration after 400 min due to the effect of dissolved $CO_2$. In the mixed-resin system it took about 600 min to reach equilibrium. Because of faster cation exchange reaction than anion exchange reaction, the effect of $CO_2$ could be removed. Based on the experimental results carried out in the mixed-resin system, the selectivity coefficients of silica ion for each ion exchange resin were calculated at some specific temperatures. The temperature dependency of the selectivity coefficient was expressed by the equation of Kraus-Raridon type.

• 한국수자원학회:학술대회논문집
• /
• 한국수자원학회 2011년도 학술발표회
• /
• pp.17-17
• /
• 2011

As a method of countermeasure to bed degradation and armoring phenomena of bed material in the downstream area of dam reservoirs, sediment augmentation (replenished sediment) has been carried out in many Japanese rivers. In general, bed of the replenished sediment site is composed of rocks, because the site is located in the downstream area of the dams and sediment supply is very small. Bed deformation process has been researched by many researchers. As a method of countermeasure to bed degradation and armoring phenomena of bed material in the downstream area of dam reservoirs, sediment augmentation (replenished sediment) has been carried out in many Japanese rivers. In general, bed of the replenished sediment site is composed of rocks, because the site is located in the downstream area of the dams and sediment supply is very small. Bed deformation process has been researched by many researchers. However, most of them can treat movable bed only and cannot be applied to the bed deformation process of sediment on rocks. If the friction angle between the sediment and the bed surface is assumed to be the same as the friction angle between the sediment and the sediment, sediment transport rate must be smaller without sediment deposition layer on the rocks. As a result, the reproduced bed geometry is affected very well. In this study, non-equilibrium transport process of non-cohesive sediment on rigid bed is introduced into the horizontal two dimensional bed deformation model and the model is applied to the erosion process of replenished sediment on rock in the Nakagawa, Japan. Here, the Japanese largest scale sediment augmentation has been performed in the Nakagawa. The results show that the amounts of the eroded sediment and the remained sediment reproduced by the developed numerical model are $56300m^3$ and $26800m^3$, respectively. On the other hand, the amounts of the eroded sediment and the remained sediment measured in the field after the floods are $56600m^3$ and $26500m^3$, respectively. The difference between the model and field data is very small. Furthermore, the bed geometry of the replenished sediment after the floods reproduced by the developed model has a good agreement with the measured bed geometry after the floods. These results indicate that the developed model is able to simulate the erosion process of replenished sediment on rocks very well. Furthermore, the erosion speed of the replenished sediment during the decreasing process of the water discharge is faster than that during the increasing process of the water discharge. The replenished sediment is eroded well, when the top of the replenished sediment is covered by the water. In general, water surface level is kept to be high during the decreasing process of the discharge during floods, because water surface level at the downstream end is high. Hence, it is considered that the high water surface level during the decreasing process of the water discharge affects on the fast erosion of the replenished sediment.

• 한국신재생에너지학회:학술대회논문집
• /
• 한국신재생에너지학회 2009년도 춘계학술대회 논문집
• /
• pp.791-793
• /
• 2009

Hydrogen has been recognized of the energy source for the future, in terms of the most environmentally acceptable energy source. A pressurized fluidized bed reactor made of carbon steel with 0.076 m I.D. and 1.0 m in height was employed for the thermocatalytic decomposition of methane to produce amount of $CO_2$ - free hydrogen with validity from a commercial point of view. The fluidized bed was proposed for withdrawing of product carbons from the reactor continuously. The methane decomposition rate with the carbon black N330 catalyst was rapidly reached a quasi-steady state and remained for several hour. The methane thermocatalytic decomposition reaction was carried out at the temperature range of 850 - 950 $^{\circ}C$, methane gas velocity of 2.0 $U_{mf}$ and the operating pressure of 1.0 -3.0 bar. Effect of operating parameters such as reaction temperature, pressure on the reaction rates was investigated and predicted the effect of a change in conditions on a chemical equilibrium thermodynamically, according to Le Chatelier's principle.

• 한국수소및신에너지학회논문집
• /
• 제23권5호
• /
• pp.448-454
• /
• 2012

In this paper, a three-dimensional hydrogen absorption model is applied to a thin double-layered annulus ZrCo hydride bed and validated against the temperature evolution data measured by Kang et al. The present model reasonably captures the bed temperature evolution behavior and the 99% hydrogen charging time. The equilibrium pressure expression for hydrogen absorption on ZrCo is derived as a function of temperature and the H/M atomic ratio based on the pressure-composition isotherm data given by Konishi et al. In addition, this present model provides multi-dimensional contours such as temperature and H/M atomic ratio in the thin doublelayered annulus metal hydride region. This numerical study provides fundamental understanding during hydrogen absorption process and indicates that efficient design of the metal hydride bed is critical to achieve rapid hydrogen charging performance. The present three-dimensional hydrogen absorption model is a useful tool for the optimization of bed design and operating conditions.

• 한국해안해양공학회지
• /
• 제6권4호
• /
• pp.375-388
• /
• 1994

폭이 좁은 조파 수조에서 해저지형변환에 대한 이동상실험을 수행할 때, 유체력과 해저지형변환은 파진행 방향으로의 2차원 평면내에 한하는 것으로 가정된다. 그러므로 해저지형이 수조내부 방향으로의 변환 등 3차원적인 형태 등은 대체로 무시되거나 또는 계측시의 평균지형 등으로 대표된다. 본 논문에서는 상당히 미세한 토사로 이루어진 해저지형변환에 대한 이동상실험을 통하여 (1)상대적으로 폭이 좁은 수로내에서 3차원 현상이 발생할 수 있는 지의 여부 및 (2) 3차원 현상 발생에 대한 여러 가지 원인 및 그들의 상관 관계 등을 조사하였다. 그 결과 유체력과 해저지형변환간에 서서히 발생하는 상호 간섭(slow feedback)을 통하여 해저지형의 수로내 폭 방향으로의 변환 등 3차원적인 형상 등이 발생 성장되며, 위 현상은 해저지형이 그 변환단계에 있어 평형상태(equilibrium)에 접근할 때 쉽게 발생한다는 것을 알게 되었다.

• 한국산학기술학회논문지
• /
• 제16권10호
• /
• pp.7089-7097
• /
• 2015

본 논문에서는 4대강 살리기 사업이 수행된 낙동강의 하상변동 양상을 해석하기 위해 과거 장기 모니터링 자료를 활용한 하상변동 분석을 수행하였다. 또한 4대강 살리기 사업 후 가장 큰 하상변동이 관측된 구간을 대상으로 향후 발생할 수 있는 장기 하상변동을 1차원 하상변동모형을 구축하여 예측하였다. 유입유사량 조건 및 유사이송공식에 따른 하상변동 예측 결과 값의 민감도 분석을 수행하였으며 단기 모니터링 실측자료와 하상변동 모의결과 값을 비교하여 모형 보정을 수행한 후 10년 장기 하상변동을 예측하였다. 모니터링 자료 분석 결과, 4대강 창녕 함안보-합천 창녕보 구간에서 전반적으로 가장 큰 최심하상고 변화가 나타났다. 1차원 하상변동 모형을 활용한 10년 동안의 장기 하상변동 수치모의에서는 창녕 함안보와 합천 창녕보 구간에서 구간별로 최대 2.07 m에서 3.26 m의 유사 퇴적이 발생하는 것으로 나타났다.

• 대한토목학회논문집
• /
• 제12권2호
• /
• pp.101-108
• /
• 1992

평형하상(平衡河床) 개념의 하천 실무에의 적용성 및 우리나라에서 평형하상경사를 추정하기 위해 널리 사용되어온 '안예(安藝)공식' 및 '물부(物部)공식'의 타당성에 대해 재고찰한다. 평형하천이란 장기간에 걸쳐 하천의 지배적인 수리(水理) 특성하에서 상류에서 공급되는 유사의 이송에 꼭 필요한 만큼의 유속이 생기도록 자연적으로 하상경사가 조정되어 실질적인 하상의 퇴적이나 침식이 없는 하천을 말하며, 평형하상이란 바로 그러한 하천의 하상상태를 지칭한다. 자연 상태에 있는 하천에 소위 '평형하상공식(平衡河床公式)'을 적용하여 그 하천의 하상상태를 분석하는 현재의 하천 실무는 지양되어야 할 것이다. 또한, 하천에서 안정하상 경사를 결정하기 위한 '안예(安藝)공식' 이나 '물부(物部)공식' 같은 소위 '평형하상공식'들은 그 타당성이 의심스러우며, 따라서 이러한 공식들의 하천 실무에의 적용은 지양되어야 할 것이다.