• Title/Summary/Keyword: equilibria

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Study on the Effect of Quantitative and Qualitative Easing(QQE) in Japan (日本の量的·質的金融緩和(QQE)の効果について)

  • Yeom, Dongho
    • Analyses & Alternatives
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    • v.2 no.2
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    • pp.143-162
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    • 2018
  • This paper focuses on the policy framework about "Quantitative and Qualitative Easing (QQE)" of Japan, and analyzes reasons why the policy goal was not reached. The QQE was introduced by the Bank of Japan in 2013 with the purpose of meeting the price stability target of 2% and getting out of deflation that prevents sustained price decline. However, despite the implementation of the bold monetary easing policy unprecedented in the world, the policy goal was not achieved as of June 2018. As a result of analyzing the causes, the following three structural factors were confirmed. 1) The rise in prices by QQE was limited because Japan's consumer price is strongly depending on import price. 2) The effect is high degree of uncertainty and limited because theoretical framework of reflationist which adopted QQE depends on "expectation formation" by "self-fulfilling expectation" and "multiple equilibria". 3) It was confirmed that the expansion of the monetary base did not lead to money stock due to the existence of Japanese liquidity trap, long-term low interest rate policy.

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Application of Polyurethane Foam Loaded with a Schiff Base Ligand for Determination of Trace Amounts of Copper in Water Samples by Flame Atomic Absorption Spectroscopy

  • Moftakhar, Mahdieh Koorehpazan;Yaftian, Mohammad Reza;Nahaei, Samaneh;Zamani, Abbas Ali
    • Journal of the Korean Chemical Society
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    • v.58 no.3
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    • pp.283-288
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    • 2014
  • A column solid phase extraction procedure based on modified polyurethane foam (PUF) by a newly synthesized Schiff base ionophore, named 2,2'-{iminobis[propane-3,1-diylnitrilo(1E)prop-1-yl-1-ylidene]}diphenol, was developed for preconcentration step of trace amounts determination of copper ions in water samples by atomic absorption flame spectroscopy. The influence of parameters on the adsorption process such as sample pH, amount of modified PUF packed in the column, type and volume of stripping reagent and its flow rate were investigated and optimized. Under optimum experimental conditions, the calibration graph was linear in a relatively wide range ($0.005-210{\mu}g/ml$) with a limit of detection $0.002{\mu}g/ml$ of copper. The proposed method allows achieving to a concentration factor of >133. The capacity of a column (1.6 cm i.d.) packed by 6 g of PUF modified by 12 mg of the Schiff base was found to be $247.7({\pm}2.1){\mu}g$ of copper. It was found that the adsorption process was highly selective towards copper ions with respect to some associated metal ions. The presented procedure was successfully applied for determination of copper in some water samples.

Ionic Equilibria and Comparison of Solvent Extraction of Cobalt(II) and Manganese(II) from HCl Solution by Alamine336 (염산용액(鹽酸溶液)에서 코발트(II)와 망간(II)의 이온 평형(平衡) 및 Alamine336에 의한 용매추출(溶媒抽出) 비교(比較))

  • Lee, Man-Seung;Shin, Shun-Myung
    • Resources Recycling
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    • v.19 no.4
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    • pp.29-34
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    • 2010
  • Distribution diagram of $CoCl_2$ and $MnCl_2$ was obtained by analyzing ionic equilibria of the two metals in HCl solution. In the HCl concentration range of 4 and 10 M, most of cobalt exists as $CoCl_2$, whereas Mn exists $MnCl_{3}^-$ and $MnCl_2$. Extraction isotherm of Co(II) and Mn(II) was calculated by using the equilibrium constant for the solvent extraction of the two metals by Alamine336. Although the equilibrium constant for the solvent extraction of Mn was higher than that of Co, extraction isotherm indicated that cobalt could be extracted more efficiently than manganese at the same initial extraction conditions.

Comparison of Ionic Equilibria Analysis of ZnSO4-Fe2(SO4)3-Na2SO4-H2SO4-NaOH-H2O System at 25℃ between Pitzer and Vasil'ev Equation (25℃에서 ZnSO4-Fe2(SO4)3-Na2SO4-H2SO4-NaOH-H2O계에 대해 Pitzer식과 Vasil'ev식에 의한 이온평형해석 비교)

  • Lee, Man-Seung;Lee, Kyoung-Ju;Nam, Sang-Ho
    • Analytical Science and Technology
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    • v.16 no.2
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    • pp.159-165
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    • 2003
  • To develop an ionic equilibria model applicable to the sulfuric acid leaching solutions of zinc oxide ore, the method of the Pitzer equation and that of the Vasil'ev equation were compared. As the ionic strength of the solution increased to 9 m, the results of ionic equilibria by the Pitzer equation were more accurate than those by Vasil'ev. To simulate the sulfuric acid leaching solutions of zinc oxide ore, the mixed solutions with the various composition of $ZnSO_4-Fe_2(SO_4)_3-Na_2SO_4-H_2SO_4-NaOH-H_2O$ were prepared. The pH values calculated in this study agreed well with those measured at $25^{\circ}C$.