• Title/Summary/Keyword: equilibria

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Application of Thermodynamic Models for Analysis on SI Thermochemical Hydrogen Production Process (SI 열화학 수소 생산 공정의 분석을 위한 열역학 모델의 적용)

  • Lee, Jun Kyu;Kim, Ki-Sub;Park, Byung Heung
    • Journal of Institute of Convergence Technology
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    • v.2 no.2
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    • pp.30-34
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    • 2012
  • The SI thermochemical cycle process accomplishes water splitting through distinctive three chemical reactions. We focused on thermodynamic models applicable to the process. Recently, remarkable models based on the assumed ionic species have been developed to describe highly nonideal behavior on the liquid phase reactions. ElecNRTL models with ionic reactions were proposed in order to provide reliable process simulation results for phase equilibrium calculations in Section II and III. In this study, the current thermodynamic models of SI thermochemical cycle process were briefly described and the calculation results of the applied ElecNRTL models for phase equilibrium calculations were illustrated for binary systems.

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Game Theoretic Analysis of the Direct Marketing Channel Strategy of a Manufacturer (게임이론을 이용한 제조업체의 직접마케팅 진입전략 분석)

  • Rhee, Min-Ho;Cho, Hyung-Rae
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.32 no.3
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    • pp.168-177
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    • 2009
  • The proliferation of the internet and electronic commerce has given the manufacturers the opportunity of direct marketing. This study analyzes the decision of manufacturers regarding whether to sell the products through independent sales company or to sell the products to the consumer directly. To do this, a new demand function is proposed and sub and super games are modeled and analyzed based on the demand function. By analyzing the Nash equilibria, it is shown that the manufacturers' decision of direct or indirect marketing not only depends on the competitiveness between the products but the absolute and relative marketing capabilities of the manufacturers. It is also shown that, in some cases, the manufactures have incentive to rise the competitiveness between the products to maximize the channel profit.

Theory vs. Experiment of Static Characteristics of Contrarotating Hydrostatic Journal Bearing with Overhung-Type Loads (외팔형 하중지지 이중 반전 정압 베어링의 정특성 이론 및 실험 연구)

  • 이용복;김창호;권오관;최동훈;이강복
    • Tribology and Lubricants
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    • v.12 no.3
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    • pp.92-99
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    • 1996
  • Energy-efficient contrarotating propeller systems have been recently reviewed as one of alternative means in marine car-carrier applications. Contrarotating rotors preclude the usage of conventional plain journal bearings due to the lack of load carrying capacity. A new multi-recess hydrostatic contrarotating journal beating test facility has been designed and installed to test the static load carrying capacity. Measurements of flow rates and orbits have been investigated by testings on a overhung-type contrarotating rotor system which is supported by a hydrostatic journal bearing. Numerical results of static equilibria were compared with test results. Various contrarotating speed combinations, and supply pressure conditions were selected. The numerical predictions of orbit centers and flow rates are generally accurate.

HDTMA-Bentonite로부터 페놀류 화합물의 경쟁탈착

  • 신원식;김영규;송동익
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.04a
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    • pp.15-18
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    • 2001
  • Sorption/desorption studies were conducted to determine sorption/desorption characteristics of phenolic compounds (phenol and 4-chlorophenol) in organically modified natural bentonite. The cationic exchange capacity (CEC) of bentonite was exchanged with a cationic surfactant, hexadecyltrimethylammonium (HDTMA), to enhance the removal capacity of organic phenol contaminants dissolved in aqueous solution. This modification produces a change of the surface property of bentonite from hydrophilic to organophilic. The single-solute and bi-solute competitive adsorptions were performed In batch mode to investigate the removal of two toxic organic Phenols, chlorophenol and 4-chlorophenol on the HDTMA-bentonite. The adsorption affinity of the 4-chlorophenol was higher than phenol due to higher octanol:water partition coefficient (Kow). The single-solute and bi-solute competitive desorptions were also performed investigate the competitive desorption of the phenolic compounds from HDTMA-bentonite. Freundlich model was used to analyze the single-solute adsorption/desorption results, while the IAST model predicted the hi-solute adsorption/desorption equilibria. The IAST model well predicted hi-solute competitive adsorption/desorption behaviors.

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Individual role of manufacturing steps in PDP system contamination and their specific impact on ultimate operational parameters

  • Riva, Mauro;Bonucci, Antonio;Tominetti, Stefano;Carretti, Corrado;Han, Yong-Gyu;Hong, Sung-Hee;Choi, Eun-Ha
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.1448-1451
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    • 2008
  • In this paper we investigate, on the basis of experimental data, the correlations between contamination issues occurring during production process steps and final PDP operational parameters: these reciprocal relations are the result of dynamic equilibria established within the PDP system, amongst residual gases and sorbed species interacting with heat, ions and photons.

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Effect of pH on the Extraction Characteristics of Succinic and Formic Acids with Tri-n-octylamine Dissolved in 1-Octanol

  • Hong, Yeon-Ki;Hong, Won-Hi;Chang, Yong-Keun
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.6 no.5
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    • pp.347-351
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    • 2001
  • A study was made on the extraction equilibria of succinic and formic acids from aqueous solutions using tri-n-octylamine (TOA) in 1-octanol. It was shown that the loading values of TOA decreased with increasing pH values. The apparent equilibrium constants for each acidamine complex were determined by an equilibrium model. In the case succinic acid, the formation of a bisuccinate anion played an important role in the stoichiometry of the acid-amine complex.

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Ultrasonic Studies of Proton-Exchange Reaction Between Hydrogen Phosphate Ions and Imidazole

  • Choi, Chang-Ha;Chung, Myung-Kiu
    • The Journal of the Acoustical Society of Korea
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    • v.16 no.1E
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    • pp.24-28
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    • 1997
  • Ultrasonic relaxation measurements for imidazole and its derivative in phosphate buffer exhibit a high peak of absorption at neutral pH. Near neutral pH, protolysis and hydrosis may be neglected and the essential reaction only consists of a direct proton-exchange. The kinetics constants and the volume changes for the proton transfer reaction with the protonated imidazole and 2-methylimidazole have been determined at 25℃. The kinetics constants are 7.2×108s-1M-1for imidazole and 1.7×108s-1M-1 for 2-methylimidazole. The kinetics constants are used to estimate the spectrum of relaxation times and acoustic relaxation amplitude associated with intermolecular and intramolecular proton-exchange reactions in bilogical media. It is concluded that the magnitude of the acoustic absorption reasonalbly attributable to the perturbation of proton-transfer equilibria between imidazole and inorganic phosphate is comparable in magnitude with the acoustic absorption observed in some intact tissues.

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Attitude control of space robots with a manipulator using time-state control form

  • Sampei, Mitsuji;Kiyota, Hiromitsu;Ishikawa, Masato
    • 제어로봇시스템학회:학술대회논문집
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    • 1995.10a
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    • pp.468-471
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    • 1995
  • In this paper, we propose a new strategy for a space robot to control its attitude. A space robot is an example of a class of non-holonomic systems, a system of which cannot be stabilized into its equilibria with continuous static state feedbacks even in the case that the system is, in some sense, controllable. Thus, we cannot design stabilizing controllers for space robots using conventional control theories. The strategy presented here transforms the non-holonomic system into a time-state control form, and allows us to make the state of the original system any desired one. In the stabilization, any conventional control theory can be applied. For simplicity, a space robot with a two-link manipulator is considered, and a simulated motion of the controlled system is shown.

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Diffusion Kinetics of Si in GaAs and Related Defect Chemistry (GaAs에서의 Si의 확산기구와 그에 관련된 격자 결함 화학)

  • Lee, Gyeong-Ho
    • ETRI Journal
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    • v.11 no.4
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    • pp.75-83
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    • 1989
  • The diffusion mechanism of Si in GaAs was investigated using different diffusion sources based on the Si-Ga-As ternary phase equilibria. The Si profiles are measured with secondary ion mass spectrometry and differ significantly for sources taken from the different phase fields in the ternary phase diagram. Neutral As vacancy diffusion is proposed for acceptor Si diffusion anneals using a Ga - Si - GaAs source. Donor Si diffusion using As - rich sources and a Si -GaAs tie line source shows concentration dependent diffusion behavior. Concentration dependent diffusion coefficients of donor Si for As - rich source diffusion were found to be related to net ionized donor concentration and showed three regimes of different behavior: saturation regime, intermediate regime,and intrinsic regime. Ga vacancies are proposed to be responsible for donor Si diffusionin GaAs: $Si_Ga^+V_Ga^-$ (donor Si -acceptor Gavacancy) complex for the extrinsic regime and neutral $V_G$a, for the intrinsic regime.The Si - GaAs tie line source resulted in two branch profiles, intermediate between the As - rich and the Ga - rich source diffusion cases.

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EEFORMATION BEHAVIOR OF STAINLESS STEEL-CLAD ALUMINUM SHEET METALS UNDER UNIAXIAL TENSION (스테인리스 강 클리드 알루미늄 판재의 일축인장시 변형거동)

  • 최시훈;김근환;오규환;이동녕
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 1995.10a
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    • pp.69-75
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    • 1995
  • The deformation behavior of stainless steel-clad aluminum sheet metals under uniaxial tension has been investigated. The differences in mechanical properties such as elastic modulus, flow stress and plastic strain ratio, of component layers of the composite sheet gave rise to warping of the tensile specimens. The warping has been analyzed by FEM and the total force and momentum equilibria. The analyzed radii of curvature of the warped specimens were smaller than the measured data possibly due to elastic recovery during unloading. The differences in mechanical properties may also give rise to transverse stresses in the component layers. The transverse stresses have been analyzed on the assumption of isostrain and by the FEM in which the warping has been taken into account. The transverse stresses calculated by the FEM were lower than those by the isostrain hypothesis due to stress relaxation by the warping and turned out to be negligible compared with the longitudinal stresses. Consequently, the flow stresses of the composite sheets follow the rule of mixtures.

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