• Title/Summary/Keyword: epr

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The Flow Analysis of Arc in LG Hybrid Interrupter Using PHOENICS Code (PHOENICS Code를 이용한 자력팽창 소호부 내 아크유동해석)

  • Lee, J.C.;Lee, B.W.;Oh, I.S.
    • Proceedings of the KIEE Conference
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    • 2001.04a
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    • pp.44-46
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    • 2001
  • This paper describes the use of the PHOENICS CFD package for the simulation of the high-current period of the arcing process in a hybrid rotating arc/auto expansion by interrupter. The operating principle of this device depends on rapid arc rotation due to the magnetic field created by the fault current through a coil which is mounted on contacts and also relies on the principle of thermal expansion created by arc energy in extinguishing chamber and finally causes pressure rise in expansion volume. This paper is divided into three main sections. The first gives a brief overview of the interrupter. The second section gives a full description of the methods used in the calculation. The final section presents some sample results for the hybrid interrupter.

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Synthesis of Iminoxyl Biradical and the Spectroscopic Study (Iminoxyl Biradical의 합성과 분광학적인 연구)

  • Jung-Sung Yang;Hee Ju Chae;Chul-Hyun Yo
    • Journal of the Korean Chemical Society
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    • v.25 no.1
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    • pp.13-20
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    • 1981
  • Iminoxyl biradical may be useful biradical spin probe for the investigation of the dynamic distribution of the directors in some liquid crystal. The iminoxyl biradical has been synthesized by a new convenient method and the intermediate products of each step were identified by the measurement of melting point and spectroscopic methods such as IR, UV, NMR and Mass spectrometry. The final product, iminoxyl biradical, was identified by the electron paramagnetic resonance spectroscopy and the interaction between two spins of the radical was discussed based on the EPR peaks.

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Performance Analysis of a Refrigeration System with Parallel Control of Evaporation Pressure (증발압력 병렬제어 냉동시스템의 성능해석)

  • Lee, Jong-Suk
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.32 no.8
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    • pp.567-573
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    • 2008
  • The conventional refrigeration system is composed of a compressor, condenser, receiver, expansion valve or capillary tube, and an evaporator. The refrigeration system used in this study has additional expansion valve and evaporator along with an evaporation pressure regulator(EPR) at the exit side of the evaporator. The two evaporators can be operated at different temperatures according to the opening of the EPR. The experimental results obtained using the refrigeration system with parallel control of evaporation pressure are presented and the performance analysis of the refrigeration system with two evaporators is conducted.

A study on the interararanular corrosion behavir of stainless steel in molten carbonate salt EPR test (EPR 방법에 의한 용융탄산염 내에서의 스텐인레스강의 입계부식에 관한 연구)

  • 황응림;서병환;강성군
    • Journal of the Korean institute of surface engineering
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    • v.31 no.4
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    • pp.223-230
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    • 1998
  • The separator for a molten carbonate fuel cell(MCFC) is mode of stainless steel and known to the suscepibility to corrosion due to environments of high temperature molten carbonte electrolyte. Considering the sensitization of stainless steel in the temperature range of 425~$815^{\circ}C$, the separator is expected to be sensitized so that the interganular corrosion (IGC) occurs during the cell operation at about $650^{\circ}C$. In this study, EPR(electrochemical potentiokinetic reactivation) technique was examined by relating some elements(mainly C and Cr) to the degree of sensitization of austenitic stainless steels in the molten carbonate salt at $650^{\circ}C$and the possible mechanism of intergranular corrosion was analyzed.

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Epr Study of the 10-Tungsto-2-vanado(Ⅳ, Ⅴ)phosphate Anion, [PV(Ⅳ)VW$_{10}O_{40}]^{6-}$

  • Lee, Chul-Wee;So, Hyun-Soo;Lee, Kyu-Ryong
    • Bulletin of the Korean Chemical Society
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    • v.7 no.1
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    • pp.39-41
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    • 1986
  • The polycrystalline epr spectrum of ${\alpha}-1,\;2-[PV(IV)VW_{10}O_{40}]^{6-}$ doped into host crystals and its solution spectrum are reported. The solution spectrum consists of fifteen lines, indicating that the unpaired electron is hopping fast between the two vanadium atoms. The polycrystalline spectrum, which consists of three sets of fifteen lines, was analyzed as a spectrum of an I = 7 system and the epr parameters were determined. The spectrum cannot be interpreted by assuming that each line appears at the average magnetic field of two hyperfine lines expected for two uncoupled vanadium atoms.

Dielectric Properties and an EPR Study of Cu- or Zr-Doped BaTiO₃ Ceramics

  • 이미녕;박윤창
    • Bulletin of the Korean Chemical Society
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    • v.16 no.10
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    • pp.908-911
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    • 1995
  • The EPR spectra of Cu-or Zr-doped BaTiO3 ceramics exhibited absorption signals with g∥=2.380 and g⊥=2.063 which are assigned to Ba1+(Ba2+ + e'→Ba1+) ion reduced by an electron that was produced from the oxygen vacancy (VO..). The intensity of these signals decreased as the temperature increased indicating that Ba1+ was changed to Ba2+ as the temperature increased. These ceramics also showed the EPR signal with g=1.997 around TC which arises from ionized Ba-vacancies, VBa'(VBa + e'→VBa'. In the orthorhombic and tetragonal phase region g=1.997 signal was not seen. The electrons generating from the oxidation of Ba1+ and ionized Ba-vacancies may contribute to a space charge which is responsible for a dielectric relaxation of these samples.

The Low-Radiation Dosimetry Application of "tris" Lyoluminescence using Electron Paramagnetic Resonance at Low Temperature

  • Son, Phil-Kook;Choi, Suk-Won;Kim, Sung-Soo;Gwag, Jin-Seog
    • Journal of Magnetics
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    • v.17 no.3
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    • pp.172-175
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    • 2012
  • We present a method for detecting very weak radiation by analyzing the inner structure of irradiated tris (lyoluminescence) materials using electron paramagnetic resonance (EPR) at low temperature. Organic materials have been looked into for use in emergency dosimetry of inhabitants around radiation accidents. However, this technology has never been applied to imperceptible radiation doses (< 0.5 Gy) because there is no proper method for detecting the change of inner structure of the subject bombed by very weak radiation at room temperature. Our results show that tris materials can be applied as a radiation detectors of very small radiation doses below 0.05 Gray, if EPR is used at low temperature (130 K ${\leq}$ T ${\leq}$ 270 K). The EPR signal intensity from the irradiated-tris sample had barely faded at all after 1 year.

Temperature Dependence of Mn2+ Paramagnetic Ion in a Stoichiometric LiNbO3 Single Crystal

  • Yeom, Tae Ho;Lee, Soo Hyung
    • Journal of Magnetics
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    • v.18 no.3
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    • pp.221-224
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    • 2013
  • Electron paramagnetic resonance (EPR) spectra of $Mn^{2+}$ impurity ion in Stoichiometric $LiNbO_3$ single crystal (SLN) was investigated with an X-band EPR spectrometer in the temperature range of 3 K~296 K. The intensity of EPR spectrum of $Mn^{2+}$ ion was increased to 20 K and decreased again below 20 K as the temperature decreases. The zero-field splitting parameter D decreased as the temperature increases. It was suggested that $Mn^{2+}$ ion substitute for $Nb^{5+}$ ion instead of $Li^+$ ion. No changes for hyperfine interaction of $Mn^{2+}$ ion was obtained in the temperature range of 3 K~296 K.

질소강화 type 304L stainless steel 의 예민화 저항성 평가

  • 윤지현;오용준;류우석;홍준화
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.11b
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    • pp.551-556
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    • 1996
  • 본 연구에서는 정량적 전기화학 시험법인 DL-EPR test 와 ASTM 에 규정된 screening test 인 oxalic acid etch test 를 통해 질소강화 type 304L stainless steel 의 예민화 저항성을 평가하고, 두 시험법의 결과 사이의 상관관계를 알아보며, 질소함량이 예민화 저항성에 미치는 영향을 고찰하고자 하였다. 실험결과 일정수준에서 질소함량이 증가할수록 예민화가 지연되는 경향을 볼 수 있었고, 이런 현상은 두 시험법의 결과에서 공히 나타났다. 또한 DL-EPR test 와 oxalic acid etch test 간의 상관관계가 비례적으로 나타났으며, 각 oxalic acid etch 조직에 해당하는 DL-EPR test 결과값 (Ir/Ia) 을 얻을 수 있었다.

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Single Crystal EPR Spectra of $K_{12}[As_2W_18O_{66}Cu_3(H_2O)_2]{\cdot}11H_2O$, a Copper(II) Trimer

  • Jo, Yeong Hwan;So, Hyeon Su
    • Bulletin of the Korean Chemical Society
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    • v.16 no.3
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    • pp.243-248
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    • 1995
  • Single crystal EPR spectra of K12[As2W18O66Cu3(H2O)2]${\cdot}$11H2O exhibit an orientation-dependent fine structure of an S = 3/2 system which is accounted for by the exchange and magnetic dipole interactions among the three Cu2+ ions. The hyperfine structure and the lines from the S = 1/2 manifolds have not been observed. The isotropic exchange parameters determined from the magnetic susceptibility data at 5-300 K are J1 = J2 =-7.8 cm-1. The magnitude of J values suggests that the unpaired electrons on three Cu2+ ions interact through a sequence of six bonds involving two tungsten atoms and three oxygen atoms. The Cu-Cu distance, 4.37 $\AA$, determined from the EPR spectra is considerably smaller than the value from the X-ray crystal structure determination, 4.76 $\pm$ 0.03 $\AA$, indicating that the point-dipole model underestimates the dipolar interaction.