• 제목/요약/키워드: epoxy

검색결과 3,675건 처리시간 0.034초

에폭시수지의 경화제 변화량에 따르는 열분해 영향 (The Effect of Thermal Decomposition of Epoxy Resin for a Variation of Hardener)

  • 박근호;이용숙;송주영;이수;김성일
    • 한국응용과학기술학회지
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    • 제24권4호
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    • pp.393-398
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    • 2007
  • We investigated heat stability of epoxy resin products and epoxy resin according to the influence hardener. The heat flow which shows the degree of thermal decomposition of the epoxy resin product and epoxy resin measured by using the differential scanning calorimeter (DSC). As a result, we found that in the case of heat stability for epoxy resin as hardener was added, the ratio of one to one (epoxy resin : hardener) was the most suitable in air condition and nitrogen atmosphere.

초음파 분산을 이용한 Epoxy-Organoclay 나노콤포지트 구조적 그리고 유전특성에 관한 연구 (Structural and Dielectric Properties of Epoxy-Organoclay Nanocomposites using Power Ultrasonic Dispersion)

  • 박재준
    • 전기학회논문지
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    • 제57권9호
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    • pp.1572-1578
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    • 2008
  • The effect of the organoclay_10A nanoparticles on the DSC and Structural and Dielectrics Properties(1Hz-1MHz) for epoxy/Organoclay_10A Nanocomposites has been studied. Dielectric properties of epoxy-Organoclay nanocomposites were investigated at 1, 3, 5, 7, 9 filler concentration by weight. Epoxy nanocomposites samples were prepared with good dispersion of layered silicate using power ultrasonic method in the particles. As structural analysis, the interlayer spacing have decreased with filled nanoparticles contents increase using power ultrasonic dispersion. The maximum increase interlayered spacing was observed to decease for above 5wt% clay loading. The other hand, as decrease with concentration filler of the layered silicate were increased dispersion degree of nanoparticles in the matrix. The interesting dielectric properties for epoxy based nanocomposites systems are attributed to the large volume fraction of interfacesin the bulk of the material and the ensuring interactions between the charged nanoparticle surface and the epoxy chains.

Effect of chemically reduced graphene oxide on epoxy nanocomposites for flexural behaviors

  • Lee, Seul-Yi;Chong, Mi-Hwa;Park, Mira;Kim, Hak-Yong;Park, Soo-Jin
    • Carbon letters
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    • 제15권1호
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    • pp.67-70
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    • 2014
  • In this work, nanocomposites of epoxy resin and chemically reduced graphene oxide (RGO) were prepared by thermal curing process. X-ray diffractions confirmed the microstructural properties of RGO. Differential scanning calorimetry was used to evaluate the curing behaviors of RGO/epoxy nanocomposites with different RGO loading amounts. We investigated the effect of RGO loading amounts on the mechanical properties of the epoxy nanocomposites. It was found that the presence of RGO improved both flexural strength and modulus of the epoxy nanocomposites till the RGO loading reached 0.4 wt%, and then decreased. The optimum loading achieved about 24.5 and 25.7% improvements, respectively, compared to the neat-epoxy composites. The observed mechanical reinforcement might be an enhancement of mechanical interlocking between the epoxy matrix and RGO due to the unique planar structures.

Effect of surface treatment of graphene nanoplatelets for improvement of thermal and electrical properties of epoxy composites

  • Kim, Minjae;Kim, Yeongseon;Baeck, Sung Hyeon;Shim, Sang Eun
    • Carbon letters
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    • 제16권1호
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    • pp.34-40
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    • 2015
  • In this study, in order to improve the thermal and electrical properties of epoxy/graphene nanoplatelets (GNPs), surface modifications of GNPs are conducted using silane coupling agents. Three silane coupling agents, i.e. 2-(3,4-epoxycyclohexyl)-ethyltrimethoxysilane (ETMOS), 3-glycidoxypropyltriethoxysilane (GPTS), and 3-glycidoxypropyltrimethoxysilane (GPTMS), were used. Among theses, GPTMS exhibits the best modification performance for fabricating GNP-incorporated epoxy composites. The effect of the silanization is evaluated using transmission electron microscopy (TEM), scanning electron microscopy, thermogravimetric analysis, and energy dispersive X-ray spectroscopy. The electrical and thermal conductivities are characterized. The epoxy/silanized GNPs exhibits higher thermal and electrical properties than the epoxy/raw GNPs due to the improved dispersion state of the GNPs in the epoxy matrix. The TEM microphotographs and Turbiscan data demonstrate that the silane molecules grafted onto the GNP surface improve the GNP dispersion in the epoxy.

콘크리트 균열 보수용 에폭시의 시공조건에 따른 성능 (Performance of Epoxy Resins for Repairing of Cracks in Concrete with Application Conditions)

  • 이찬영;심재원;김홍배
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2004년도 추계 학술발표회 제16권2호
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    • pp.813-816
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    • 2004
  • This study was performed to investigate bonding performance of epoxy resins for repairing of cracks in concrete, as a part of project to establish quality control standard for epoxy resins. In the slant shear strength test for hard and soft type epoxy, hard type was higher about 3 times than soft one. From the results, it is thought that hard type is suitable for load carrying. Injection of epoxy resin in the notch made flexural strength increase about $47\%$ over the specimen that epoxy resin is not injected. There were no differences in bonding performances with viscosity. Application of epoxy resin on the wet concrete surface made slant shear strength decrease about $46\%$, but similar performance to the case of application on the dry surface appeared by using epoxy resin for wet condition.

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Effect of Amino Silane Coupling Agent on the AC Electrical Breakdown Phenomena of Epoxy/Layered Silicate Nanocomposite in Needle-plate Electrodes

  • Park, Jae-Jun
    • Transactions on Electrical and Electronic Materials
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    • 제13권3호
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    • pp.149-152
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    • 2012
  • The effects of amino silane coupling agent on the AC electrical treeing and breakdown behaviors in an epoxy/layered silicate (1 wt%) were examined in needle-plate electrode geometry. A layered silicate was exfoliated in an epoxy base resin by using our AC electric field apparatus. To measure the tree initiation and propagation and the breakdown rate, an alternating current (AC) of 10 kV (60 Hz) was applied to the specimen in needle-plate electrode arrangement with a $30^{\circ}C$ insulating oil bath. In the epoxy/amino silane system, the tree initiation time was 11.5 times higher and the breakdown time was 17.9 times higher than those of the neat epoxy resin. The tree initiation time in the epoxy/layered silicate (1 wt%) system with the amino silane was 2.0 times higher, and the breakdown time was 1.5 times higher than those of the epoxy/layered silicate (1 wt%) system.

탄성형 에폭시를 사용한 변류기 개발에 관한 연구 (A Study of CT Development Applied Elastic Epoxy)

  • 이관우;이경용;장용무;최용성;박대희
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2004년도 추계학술대회 논문집 전기물성,응용부문
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    • pp.197-199
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    • 2004
  • In this paper, we studied a accuracy for CT using elastic epoxy. According to industry development, the quality where also the electric material is various is demanded. Insulation material is widely used because epoxy is superior to electrical and mechanical property. Until now, the possibility where the crack will occur is high because epoxy used to electrical products had high hardness. If thermal expansion is different of two material, contraction of epoxy heavily transformed turns ratio of CT. Elastic epoxy absorbed in expansion and contraction of substance material by temperature. So we could design more exacted CT. We had elastic test of elastic epoxy and made CT using elastic epoxy. At the result, We obtained turns ratio of within 4% superior to existing CT.

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Mechanical and Water Repellent Properties of Cycloaliphatic Epoxy/Microsilica/Nanosilica Composite

  • Park, Jae-Jun
    • Transactions on Electrical and Electronic Materials
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    • 제18권4호
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    • pp.203-206
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    • 2017
  • The effect of the content of microsilica and nanosilica continuously modified with hydroxy silane and epoxy-modified silicone in cycloaliphatic epoxy/microsilica/nanosilica composites (EMNCs) on the mechanical and water repellent properties was evaluated. Surface-modified micro- and nanosilica was well-mixed with a cycloaliphatic epoxy resin in the presence of polyester-modified polydimethylsiloxane (PEM-PDMS) as a dispersing agent using an ultrasonicator. Tensile and flexural tests were carried out using a universal testing machine (UTM). The water repellent property was evaluated by contact angle measurements of water on the composite surface. Tensile strength of the composite could be enhanced by 32.2% up to 91.4 MPa, and the flexural strength was raised to 122.0 MPa, which is 38.8% higher than that of neat epoxy. The contact angle of water on the composite was as high as $104.1^{\circ}$.

EPOXY RESIN의 정확도와 인상재와의 친화성에 관한 연구 (DIMENSIONAL ACCURACY OF EPOXY RESINS AND THEIR COMPATIBILITY WITH IMPRESSION MATERIALS)

  • 장수경;장익태;임순호
    • 대한치과보철학회지
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    • 제37권3호
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    • pp.383-394
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    • 1999
  • The indirect technique for making cast restoration requires that dies be as accurate and durable as possible. Currently, stone is the most commonly used material for die. However, it has some problems such as the weakness in its strength and low abrasion resistance. Recently, epoxy resin die systems have become available. The purpose of this study was to examine two commercially available resin die systems and evaluate some characteristics for their clinical performance. This study evaluated the dimensional accuracy of epoxy resins and their wettability with impression materials. In this study, the first experiment was about dimensional accuracy of different die materials. The master model was made of stainless steel. 10 models were made of two epoxy resins (Die-epoxy, Tri-epoxy) and a die stone (Fujirock) each. Occlusal diameter (Dimension I), occluso-gingival height (Dimension II), and interabutment distance (Dimension III) were measured in each model. Next, the contact angles of die materials with impression materials were observed. The blocks were made of polyether, hydrophilic additional silicone, polysulfide impression materials. By drop-ping the same amount (0.05ml) of Tri-epoxy, Die-epoxy, and die stone on the blocks, 10 samples of each die material were made. After setting of materials, the contact angles were measured. The results of this study were as follows. 1. The expansion of stone die and the shrinkage of resin dies in occlusal diameter were observed, and stone and Tri-epoxy were expanded and Die-epoxy was shrinked in occluso-gingival height. There was little change among materials in interabutment distance (p<0.05). 2. In comparison with the master model Tri-epoxy had the least variation in measurement of the three die systems examined. Die-epoxy was next, and die stone showed the greatest variation. 3. The compatibility of die stone for polyether, hydrophilic additional silicone, polysulfide decreased in order, wherease epoxy materials had the decreased compatibility for polyether and polysulnde, hydrophilic additional silicone in order. It was not statistically different between polyether and polysulfide (p<0.05). 4. The contact angles of Tri-epoxy, Die-epoxy, die stone were getting bigger in order.

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산화 그래핀 나노플레이트릿을 강화제로 사용한 에폭시 도료의 역학적 특성 (Mechanical Properties of Epoxy Paint using Oxidized Graphene Nanoplatelet as a Reinforcement)

  • 서원우;김규용;윤민호;이보경;남정수
    • 한국건축시공학회지
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    • 제17권5호
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    • pp.465-471
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    • 2017
  • 본 연구에서는 그래핀 나노플레이트릿(Graphene nanoplatelet ; GNP)의 분산에 대한 문제를 해결하고자 질산으로 이를 산화시켜 GO를 제조하였다. 이렇게 제조한 GO를 에폭시 도료에 혼입하기 전, 푸리에변환적외선분광법(Fourier transform infrared spectroscopy; FT-IR)을 이용한 화학조성 분석과 용매에서의 분산안정성을 확인하였다. 그 후, GNP, GO를 에폭시 도료에 0.1, 0.3, 0.5, 1.0wt.% 혼입하여 GNP/Epoxy, GO/Epoxy 도료를 제조하고 역학적 특성을 평가하였다. 실험 결과, FT-IR 분석을 통해 GO에서 하이드록시기, 에폭시기, 카르복시기 기능기가 생성된 것을 확인할 수 있었다. 또한, GO는 GNP보다 증류수와 에탄올에서 분산안정성이 향상되는 것을 확인하였다. 한편, GO/Epoxy 도료는 Neat Epoxy, GNP/Epoxy에 비해 역학적 특성이 향상되었으며, 특히 0.3wt.% 혼입률에서 높은 역학적 특성을 나타내었다. 따라서 GO를 에폭시 수지에 강화제로써 혼입할 경우 에폭시 도료의 역학적 특성을 향상시키는데 효과적인 것으로 판단된다.