• Title/Summary/Keyword: environmental tracer

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Application of single-well push-drift-pull tests using dual tracers (SF6 and salt) for designing CO2 leakage monitoring network at the environmental impact test site in Korea

  • Kim, Hong-Hyun;Lee, Seong-Sun;Ha, Seung-Wook;Lee, Kang-Kun
    • Geosciences Journal
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    • v.22 no.6
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    • pp.1041-1052
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    • 2018
  • A single-well push-drift-pull tracer test using two different tracers ($SF_6$ and salt) was performed at the Environmental Impact Test (EIT) site to determine suitable locations for monitoring wells and arrange them prior to artificial $CO_2$ injection and leak tests. Local-scale estimates of hydraulic properties (linear groundwater velocity and effective porosity) were obtained at the study site by the tracer test with two tracers. The mass recovery percentage of the volatile tracer ($SF_6$) was lower than that of the non-volatile tracer (salt) and increased drift time may make degassing of $SF_6$ intensified. The $CO_2$ leakage monitoring results for both unsaturated and saturated zones suggest that the $CO_2$ monitoring points should be located near points at which a high concentration gradient is expected. Based on the estimated hydraulic properties and tracer mass recovery rates, an optimal $CO_2$ monitoring network including boreholes for monitoring the unsaturated zone was constructed at the study site.

The Evaluation of Petroleum Contamination in Heterogeneous Media Using Partitioning Tracer Method (분배성 추적자 시험법을 이용한 불균질 지반의 유류 오염도 평가)

  • Kim, Eun-Hyup;Rhee, Sung-Su;Park, Jun-Boum
    • Proceedings of the Korean Geotechical Society Conference
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    • 2009.09a
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    • pp.1372-1377
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    • 2009
  • For the remediation of the subsurface contaminated by nonaqueous phase liquids(NAPLs), it is important to characterize the NAPL zone properly. Conventional characterization methods provide data at discrete points. To overcome the weak points of conventional characterization methods, the partitioning tracer method has been developed and studied. The average saturation of NAPL($S_n$), which is the representative and continuous saturation value within contaminated site, can be calculated by comparing the transport of the partitioning tracers to that of the conservative tracer in the partitioning tracer method. In this study, the application of the partitioning tracer method in heterogeneous media was investigated. To represent the heterogeneous condition of subsurface, a two-dimensional soil box was divided into four layers and each layer contained different sized soils. Soils in the soil box were contaminated by the mixture of kerosene and diesel, and partitioning tracer tests were conducted before and after the contamination using methanol as conservative tracer and 4-methyl-2-pentanol, 2-ethyl-1-butanol, and hexanol as partitioning tracers. The response curves of partitioning tracers from contaminated soils were separated and retarded in comparison with those from non-contaminated soils. The contamination of soils by NAPLs, therefore, can be detected by partitioning tracer method considering these retardations of tracers. From our experiment condition, the average saturation of NAPLs calculated by partitioning tracer method using the methanol as conservative tracer and hexanol as partitioning tracer showed the highest accuracy, though all results were underestimated. Further studies, therefore, were needed for improving the accuracy using the partitioning tracer test in heterogeneous media.

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Removal Efficiency of Cryptosporidium Tracer in Drinking Water Treatment Process (정수처리 공정에서 Cryptosporidium Tracer의 제거효율)

  • Lee, Shun-Hwa;Kim, Yun-Hee
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.12
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    • pp.1304-1309
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    • 2006
  • In this study, removal efficiencies of treatment processes with C. tracer which is similar to the characteristics of Cryptosporidium were investigated. The highest removal efficiency of C. tracer was 97.16% when the input dose of PACI(Poly aluminium chloride, $Al_2O_3$(10%)) was 10 mg/L. The higher turbidity and SS removal efficiencies were, the more C. tracer cohesion efficiency increased. Also when pH of the raw water was high, removal efficiency of C. tracer increased. As the correlationship($R^2$) between effluent turbidity after coagulation-precipitation and removal efficiency of C. tracer was 0.9506, removal efficiency of Cryptosporidium could be evaluated by effluent turbidity after coagulation-precipitation. Also the range of C. tracer removal efficiency by sand filtration was $94.00{\sim}95.83%$ and the correlationship($R^2$) between effluent turbidity after filtration and removal efficiency of C. tracer was 0.8704. Therefore, when filtration-effluent turbidity is good under the optimized coagulation condition, removal efficiencies of Cryptosporidium by coagulation-precipitation, sand rapid filtration and sand rapid filtration after coagulation-precipitation are estimated as 1.55 log(97.16%), 1.38 log(95.83%) and 2.31 log(99.51%) respectively.

Quantification of Diesel in Soils using the Partitioning Tracer Method with Two-dimensional Soil Box (분배성 추적자 기법을 이용한 디젤 오염 토양의 정량적 오염도 평가에 관한 2차원 토조 실험 연구)

  • Rhee, Sung-Su;Lee, Gwang-Hun;Park, Jun-Boum
    • Journal of Soil and Groundwater Environment
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    • v.15 no.1
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    • pp.66-72
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    • 2010
  • The partitioning tracer method is to estimate the residual saturation of nonaqueous phase liquid (NAPL) in soils by analyzing tracer's retardation induced by the reversible partitioning of tracer with NAPL. This study is to estimate the residual diesel saturation in soils using the partitioning tracer method. Two-dimensional soil box was used to represent the 2-dimensional flows of groundwater and tracer solution in the saturated aquifer, and the soil box was filled with soil and then saturated with water. The residual diesel saturation was induced in saturated soil, and the partitioning tracer method was applied. The results from batch-partitioning experiment indicated that the diesel-water partitioning was linear with respect to tracer's concentration, and the partition coefficient of tracer between diesel and water was measured by their linearities. The groundwater flow in the saturated aquifer was simulated in the 2-dimensional soil box, and the residual diesel contamination was visually identified. The results from the partitioning tracer method with or without diesel in soils confirmed that 4-methyl-2-pentanol, 2-ethyl-1-butanol and 1-hexanol, can be used as a detecting method for diesel contamination. By the accuracies of estimations for diesel contamination using the partitioning tracer method, 2-ethyl-1- butanol showed the highest accuracy with 83%.

Applicability of Relative Effective Porosity Model to Tracer Tests

  • Hwang, Hyeon-Tae;Lee, Gang-Geun;Suleiman, A.A.
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.341-345
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    • 2004
  • An attempt has been made in this study to evaluate an applicability of Relative Effective Porosity Model (REPM) as a method for estimating saturated hydraulic conductivity (K$_{s}$) for homogeneous coarse, medium, and fine sands. The saturated hydraulic conductivities obtained from REPM are converted into average linear velocities using Darcy's Law and compared with the results from experimental tracer tests for homogeneous coarse, medium, and fine sand layer. Two types of tracer tests analyses, analytical solution using CXTFIT and moment methods, are performed to obtain reasonable linear velocity range for each layer. For the coarse and medium sands, the converted average linear velocity from REPM is in the velocity range obtained from tracer tests. However, small difference between the results from REPM and tracer tests is found for the fine sands. These results show that REPM gives reasonable estimates of saturated hydraulic conductivity.y.

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Experimental und Numerical Sensitivity Analyses on Push Pull Tracer Tests

  • Hwang, Hyeon-Tae;Lee, Gang-Geun
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.09a
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    • pp.312-316
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    • 2004
  • Single-well tracer tests, especially push pull tracer tests, are more effective to estimate hydraulic parameters and microbial metabolic activities in terms of duration and cost compared to multi-well tracer tests. However, there are some drawbacks in accuracy, complicated data analysis and uniqueness. These shortages are thought to be derived from the applied conditions which affect mass recovery curve and breakthrough curve. Factors such as extraction rate, resting period, hydraulic conductivity and hydraulic gradient are considered as the major factors determining the mass recovery rate and shape of the breakthrough curve. The results of the sensitivity analysis are summarized as follows: 1) the significant change in concentration of breakthrough curve is obtained when the extraction rate increases. This effect would also be much higher if the hydraulic conductivity is lower; 2) the mass recovery rate decreases with the increase of resting time, and the difference of mass recovery rates for different resting times is inversely proportional to the hydraulic conductivity; 3) the sensitivity values decrease with time. The hydraulic conductivity affects not only the early period, but the later period of the breakthrough curves; 4) The influence of the hydraulic gradient on the breakthrough curves is greater at earlier stage than at later stage. The mass recovery rate is inversely proportional to the hydraulic gradient.

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Evaluation of Gaussian Puff Model with Tracer Experiment under Nighttime Strong Stable Conditions (추적자 확산실험에 의한 야간 강안정층하에서의 가우시안 퍼프모델의 평가)

  • Lee, Chong-Bum;Kim, San;Kim, Young-Goog;Cho, Chang-Rae;Yu, Seung-Do
    • Journal of Korean Society for Atmospheric Environment
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    • v.12 no.5
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    • pp.529-540
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    • 1996
  • Dispersion experiment using SF$_{6}$ tracer was performed in the flat field of Chunchon Basin during four nights from August 29 to September 2, 1991. The purpose of this study is to analyze toe horizontal distribution of tracer concentration under the strong stable conditions and to evaluate the results calculated by INPUFF model. Incase of high wind speed, plume spread of SF$_{6}$ concentration appeared in narrow area of the downwind and the standard deviation of the horizontal wind angle (.sigma.$_{a}$) was amall. However, the SF$_{6}$ was spread widely in cases of low wind speed because of the large .sigma.$_{a}$. The result of the INPUFF model was similar to the observed distribution of the SF$_{6}$ concentration. It is proved that the Gaussian puff model is useful when wind direction varies significantly.tly.tly.tly.

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Construction of a Hydraulic Scale Model for Representing the Field Tracer Experiment in River (하천 현장 실험 재현을 위한 수리모형 장치 제작)

  • Chun, Il Young;Kim, Ki Chul;Lee, Jung Lyul;Suh, Kyung Suk
    • Journal of Radiation Industry
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    • v.2 no.3
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    • pp.155-161
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    • 2008
  • A hydraulic scale model was constructed to investigate the characteristics of flows and pollutant transport in laboratory. The distorted hydraulic scale model by assuming Froude similarity was adopted to represent hydrodynamics and dispersion in a river system. The scale model was composed of water reservoir, slope control part, booster pump, distributing plate and main channel. A constructed scale model will be used to present the overall concentration profiles of tracer and a research will be performed to convert the measured values using a hydraulic scale model to real field scale.

Variation of Tracer Distribution During the Antarctic Polar Vortex Breakup Shown in ILAS and ILAS-II Data (ILAS와 ILAS-II 자료에서 나타난 남극 와동 붕괴기간의 미량기체 분포변화)

  • Choi, Wookap;Lim, Kyungsoo
    • Atmosphere
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    • v.20 no.3
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    • pp.367-377
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    • 2010
  • Variation of tracer distribution during the vortex-breakup period in the Antarctic region was observed by the data from the Improved Limb Atmospheric Spectrometer (ILAS) and ILAS-II. All four trace species including methane, nitrous oxide, ozone, and water vapor show similar patterns of vertical gradient in spite of different structures of zonal mean mixing ratio. Timings of vortex breakup on each level are estimated by two different methods, and they are compared with zonal standard deviations following the latitude circle of each trace species. Although the tracers have different chemical life times and sink/source, the zonal standard deviation patterns show remarkable similarities. The zonal standard deviation shown here to measure the zonal asymmetry of tracer distribution is believed to diagnose the timing of the Antarctic polar-vortex breakup reasonably well.

Experiments for the Characteristic Evaluation of Pollutant Transport in Tidal Influenced Region (조파역내 오염물 이동특성 평가 실험)

  • Park, Geon Hyeong;Kim, Ki Chul;Jung, Sung Hee;Suh, Kyung Suk
    • Journal of Radiation Industry
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    • v.4 no.4
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    • pp.391-395
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    • 2010
  • The characteristics for pollutant transport in tidal influenced area was investigated using tidal wave hydraulic scale model. Hydraulic scale model was composed of the tidal generator, attenuation area and channel. Also, wave height, current meter and conductivity meter were used with the measured instruments in hydraulic scale model. NaCl with a tracer was used to evaluate the advection phenomena under the different velocity profiles. The arrival time of the maximum concentration in the condition of the relatively fast velocity was measured about 30 seconds faster than ones in the conditions of low velocity. The measured concentrations of the tracer were shown in the detection points of the flow direction consecutively.