• Economic and Environmental Geology
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• v.27 no.1
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• pp.29-39
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• 1994

Gabbroic rocks in which titanomagnetite orebodies are embedded were emplaced in Precambrian metasedimentary rocks. Hornblende K-Ar ages for equigranula and gneissic gabbros were obtained to be $1021.8{\pm}14.5$ Ma and $1468.4{\pm}20.8$ Ma, respectively. Biotite-granite has an age of 116.4 Ma, which has corresponded to Daebo granite. Amphibole minerals of the gabbroic rock and the magnetite orebodies belong to calcic amphibole group such as ferroan pargasite, pargasite, and ferro-pargasite. The gabbroic rocks have unusually high content of $TiO_2$ ranging from 0.88 to 6.03 wt.% with an average value of 3.46 wt.% as compared to normal gabbroic rock with 1.32 wt.% in $TiO_2$. Incompatible elements such as Ba and Sr of the gabbros are negatively correlated with $SiO_2$. In contrast, Co and Cr have a positive correlation with $SiO_2$, suggesting a normal differentiation trend of gabbroic magma.

• Environmental Engineering Research
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• v.15 no.2
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• pp.85-91
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• 2010

Romania aims to adopt and implement the European Union's legislation, also including that for the field of water management. Like other countries, groundwater in Romania is locally polluted from point sources, such as leaking landfills, as well as from diffuse pollution sources, include fertilizers, pesticides and leakages from sewers, in urbanized areas. Diffuse pollution can also occur indirectly, by over-exploitation of groundwater wells, resulting in salt water intrusion, as well as from mining and exploitation of mineral aggregates. Romania has quite an intensive monitoring scheme to measure groundwater quality in phreatic and confined aquifers. The purpose of the work resumed in this paper was to derive natural background levels (NBL) for groundwater in order to distinguish the natural elevated concentrations of some substances (natural phenomena) from point and diffuse pollution (anthropogenic phenomena). Based on these NBLs, threshold values (TV) for groundwater will be set according to the requirements of the European Water Framework Directive and the related Groundwater Directive. This paper describes the results of a study for the derivation of NBL and TV in a pilot Groundwater Body. Also, the process and draft results for extrapolating this work for all Romanian groundwater bodies is explained, as well as points for future consideration with respect to monitoring and management.

• Economic and Environmental Geology
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• v.20 no.1
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• pp.61-75
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• 1987

The Daejang mine is one of the representatives of Cu-Pb-Zn-(Ag) vein deposit related genetically to late Cretaceous granitoid in Korea. Sericite from an alteration halo of the mine yielded a K-Ar date of $95{\pm}3.5Ma$. Based on macrostructures of vein filling, three major mineralization stages (I, II and III) are distinguished by tectonic breaks. Major ore constituents are arsenopyrite, pyrite, pyrrhotite, sphalerite, chalcopyrite, galena, boulangerite, with small amounts of Ag-bearing tetrahedrite, pyrargyrite, native bismuth, marcasite, siderite, ankerite, gudmundite and calcite. Characteristic feature of each mineralization stage and compositional variation of sphalerite and arsenopyrite are discussed in relation to the genetic environments. The FeS contents of sphalerites are 20.5~14.9 mole % in stage I, 17.9~11.9 mole % in stage IIA, 17.0~9.2 mole % in stage IIB, and 6.9~4.7 mole % in stage III. Their results are indicative of decreasing FeS contents during mineralization process in sphalerite coexisting with sulfur-rich sulfide assemblages, such as monoclinic pyrrhotite and pyrite, and is agreement with the conclusions shown by Scott and Kissin(1973). The composition of arsenopyrite decrease also in As content from stage I to stage III, and the compositional variation correlate with position of the associated minerals in the paragenesis. Temperature and pressure of the mineralization are determined as $250{\sim}430^{\circ}C$ and 4.0~0.3kb respectively, based on the chemistry of the minerals.

• Economic and Environmental Geology
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• v.33 no.5
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• pp.353-365
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• 2000

After their first appearance on Earth, bacteria have exerted significant influence on geochemical behavior of elements. Numerous evidence of their control on geochemistry through geologic history has been observed in a variety of natural environments. They have mediated weathering rate, formation of secondary minerals, redox transformation of metals and metalloids, and thus global cycling of elements. Such ability of bacteria receives so considerable attention from microbiologists, mineralogists, geologists, soil scientists, limnologists, oceanographers, and atmospheric scientists as well as geochemists that a new and interdisciplinary field of research called 'geomicrobiology' is currently expanding. Some recent subjects of geomicrobiology which are studied extensively are as follows: 1) Functional groups distributed on bacterial cell walls adsorb dissolved cations onto cell surfaces by electrostatic surface complexation, which is followed by hydrous mineral formation. 2) Dissimilatory metal reducing bacteria conserve energy to support growth by oxidation of organic matter coupled to reduction of some oxidized metals and/or metalloids. They can be effectively used in remediating environments contaminated with U, As, Se, and Cr. 3) Bacteria increase the rate of mineral dissolution by excreting proton and ligands such as organic acids into aqueous system. 4) Thorough investigation on the effects of biofilm on geochemical processes is needed, because most bacteria are adsorbed on solid substrates and form biofilms in natural settings.

• Economic and Environmental Geology
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• v.54 no.2
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• pp.213-232
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• 2021

Ore criteria at the Sheba Deposit indicate orogenic mineralization type. Rocks and mineral assemblages suggest low formation-temperature of green-schist facies. Pyrite found in two generations; Type1 is irregular grains, contains higher arsenic and gold contents, compared to the relatively younger phase Type2 pyrite, which is composed of euhedral grains, found adjacent to late quartz-carbonate veins or at rims of type1 pyrite. Two gold generations were identified; type1 found included in sulphides (mainly pyrite). The second gold type was remobilized (secondary) into free-lodes within silicates (mainly quartz). Gold fineness is high, as gold contains up to 95 wt. % Au, Ag up to 3.5 wt. %, and traces of Cu, Ni, and Fe. Pyrite type2 contains tiny mineral domains (rich in Al, Mn, Hg, Se, Ti, V, and Cr). Zoning, and replacement textures are common, suggesting multiple mineralization stages. The distribution and relationships of trace elements in pyrite type2 indicate three formation patterns: (1) Al, Mn, Hg, Se, Ti, V, Cr, and Sn are homogeneously distributed in pyrite, reflecting a synchronous formation. (2) As, Ni, Co, Zn, and Sb display heterogeneous distribution pattern in pyrite, which may indicate post-formation existence due to other activities. (3) Au and Ag show both distribution patterns within pyrite, suggesting that gold is found both in microscopic phases and as chemically bounded phase.

• Economic and Environmental Geology
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• v.37 no.1
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• pp.49-59
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• 2004

The concectration and distribution of contaminants obtained from a contaminated land investigation or an environmental geochemistry survey constitutes the basis of a decision-making process on environmental policies or of scientific researches. As the quality of data determines the reliability of the result, the investigation plan should be adjusted according to the purpose of the investigation. In general, the effort to improve the data quality had been focused mainly on the QA/QC procedures in laboratories. The rapid progress of analytical instrument has also contributed toward improving the analytical precision to a sacrificable degree. Nevertheless, in many cases, it is not the analytical precision that needs improvement for the better precision of overall measurement process: it is rather during the sampling process in the field that is responsible for the poor precision. To assess the data quality on a measured value, ISO recommends to provide information on "measurement uncertainty" along with the measured value. The measurement uncertainty in an environmental measurement context can be explained as the statistical number that expresses the degree of the uncertainty stemming from the sampling and analytical procedures. There is a cost involved in order to improve the precision of sampling and analytical methods so as to decrease the degree of measurement uncertainty. The economical point of compromise in an investigation planning can be achieved when the allowable degree of uncertainty has been set before-hand. The investigation can then be planned accordingly not to exceed the uncertainty limit. Furthermore, if the measurement uncertainty estimated from the preliminary investigation can be separated into sampling and analytical uncertainties, it can be used as a criterion where the resources for the investigation should be allotted cost-effectively to reinforce the weakest link of the whole investigation process. This paper aims to present a method of estimating the level of measurement uncertainty of a measured contamination concentration at a site used as an example and to show how the estimated uncertainty can be applied to serve the particular purpose of an investigation.

• Economic and Environmental Geology
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• v.19 no.spc
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• pp.53-71
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• 1986

Detailed studies of regional geology and geochemistry of the tungsten mineralisation of Ogbang mine were carried out; in particular geochemical trends of major and trace elements of different lithological units, in comparison with those of the Sangdong area, together with igneous plutons in the area. The Ogbang deposit is in a pegmatitic association localised only in amphibolites whilst pegmatites in adjacent schists and gneisses are barren. The tungsten is geochemically accompanied by increase of $K_2O$, $Na_2O$ and Rb, and depletion of Sr. The trend of Rb/Sr ratio to the type of mineralisation, in commonly seen in the mineralised granites of the world, suggests that the tungsten in the Ogbang pegmatites was supplied by hydrothermal processes which at the same time caused Rb enrichment and Sr depletion. These trend could be of use in the search for new ore bodies in common with those of mineralised granitic or pegmatitic host rocks. There is no evidence that the granites in the area have any genetic influence spacially and temporarily on the initial scheelite formation.

• Economic and Environmental Geology
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• v.16 no.2
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• pp.83-109
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• 1983

The Cretaceous Palgongsan granite is a typical, calc-alkaline, subsolvus monzogranite and shows characteristics of "I-type" granite by mineralogy and chemical composition. Many of the major and trace element characteristics of the Palgongsan granite are consistent with a relationship by fractional crystallisation to form a chemically zoned pattern. The granite show light REE enrichment with (Ce/Yb)N ratios of 5.78-9.50. All the REE patterns show Eu negative anomalies which become larger from the margin ($Eu/Eu^*=0.75$) to the core ($Eu/Eu^*=0.24$) of the pluton, mainly due to feldspar fractionation. Mineral geochemistry (alkali-feldspar, plagioclase & biotite) studies also show the zonal structure of the Palgongsan granite. The two-feldspar geothermometer shows that the temperature difference between the margin and the core part of the pluton is about $200^{\circ}C$ at various assumed pressures.

• Economic and Environmental Geology
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• v.34 no.1
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• pp.71-88
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• 2001

The Geochemica] and isotope studies on the $CO_2$-rich water from the Shinchon area were carried out. The Shinchon $CO_2$-rich water belongs to Ca(Na)-$HCO_3$ type showing very high $P_{CO_{2}}$ ( $10^{-0.35}$ ~ $10^{0.29}$ atm) and TDS (835-3,144 mg/L). The results of geochemical and isotope analysis indicate that $CO_2$ gas is originated from the deep seated source such as mantle or magmatic gases. The $CO_2$-rich water was evolved by interaction with deep-seated granite and major water-rock interaction was dissolution of p]agioclase resulting high Na content of $CO_2$-rich water. Precipitation and dissolution of secondary calcite might be accompanied with the dissolution of plagioclase maintaining Na/Ca ratio. High contents of K and $SO_4$ indicate that the geochemical characteristics of $CO_2$-rich water were partially affected by interaction with upper sedimentary rock during uprising to surface. N03 and tritium contents suggest that the $CO_2$-rich water was mixed with low $CO_2$ groundwater at some locations. The oxygen-hydrogen isotopes show that all water samples were derived from meteoric waters and the $CO_2$-rich water was isotopically re-equilibrated with lighter $CO_2$ gas. Although some carbon isotope data show isotopically heavy values, carbon isotope data indicate that the $CO_2$ gas was possib]y derived by deep source.

• Journal of the Korean GEO-environmental Society
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• v.13 no.9
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• pp.31-44
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• 2012

Seasonal changes in groundwater geochemistry exist in Ddan-sum island. In the farming season of April, the spatial distribution of ions explains that $Fe^{2+}$, Fe(total), $Mn^{2+}$, $Ca^{2+}$, $Mg^{2+}$, $SiO_2$, ${HCO_3}^-$, and ${NO_3}^-$ are high in the center of the island, but $Na^+$ and $K^+$ are relatively low and these high anions indicates the effect of fertilizer used for strawberry cultivation. Spatial variation of ion concentration is smaller in August than April because of low agricultural activity and heavy rainfall. Geochemical type of groundwater shows that the center of island has the characteristics of recharge zone but the rim area corresponds to a mixing zone between groundwater and stream water. According to the analysis of saturation index for Fe and Mn ions, hematite, goethite, and rhodochrosite under supersaturation have a possibility of additional mineral deposition, and siderite, $Fe(OH)_3$, manganite, pyrolusite, and pyrochroite under unsaturation may exist as a type of dissolved ion.