• Title/Summary/Keyword: environmental fates

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Bisphenol A and other alkylphenols in the environment - occurrence, fate, health effects and analytical techniques

  • Zhu, Zhuo;Zuo, Yuegang
    • Advances in environmental research
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    • v.2 no.3
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    • pp.179-202
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    • 2013
  • Bisphenol A and other alkylphenols are widely used in plastic and other industrial consumer products. Release of these compounds into the aquatic environment during their manufacture, use and disposal has been a great scientific and public concern due to their toxicity at high concentrations and endocrine disrupting effects at low concentration on aquatic wildlife and human beings. This paper reviews the published data and researches on the environmental occurrence, distribution, health effects and analytical techniques of bisphenol A and alkylphenols. The aim is to provide an overview of the current understanding about bisphenol A and alkylphenols in the environment and the difficulties faced today in order to establish standard and systematic environmental analysis and assessment process for these endocrine disruptor compounds.

Evaluation on the effects of pesticide residues to agroecosystem in Korea (농업 생태계에 대한 잔류농약의 영향 평가)

  • Lee, Kyu-Seung
    • Korean Journal of Environmental Agriculture
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    • v.16 no.1
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    • pp.80-93
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    • 1997
  • Pesticide residues in soil could be affected to the growth of micro organisms and the activity of enzymes directly, and successively to the soil properties as pH, Eh and nitrogen metabolism. However, residues are diminished by degradation of soil microorganisms, run-off, leaching, volatilization, photodecomposition and uptake through crops. In this paper research results published in Korea were summarized about translocation of soil residues into crops, fates of residues in soil, effects to the activity of soil microorganisms and metabolic pathways of some pesticides. Generally speaking, pesticide residues in soil were not much affected to the agro-ecosystem except few chemicals. So it should be needed more further researches in this field, continuously.

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Microcosm Studies of Nanomaterials in Water and Soil Ecosystems (수생태 및 토양생태계에서 나노물질의 마이크로코즘 연구)

  • Yoon, Sung-Ji;An, Youn-Joo
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.4
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    • pp.288-294
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    • 2012
  • The current growth of nano-industries has resulted in released nanoparticles entering into water and soil ecosystems via various direct or indirect routes. Physicochemical properties of nanoparticles differ from bulk materials, and nanomaterials influence the fates of nanoparticles and the interactions of living or non-living things in the environment. Microcosm analysis is a research methodology for revealing natural phenomena by mimicking part of an ecosystem under controlled conditions. Microcosm study allows for the integrated analysis of toxic effects and fates of nanoparticles in the ecosystem. Ecotoxicity studies of nanomaterials are steadily increasing, and microcosm studies of nanomaterials are currently beginning to surface. In this study, microcosm studies of nanomaterials in water and soil ecosystems were extensively investigated based on SCI(E) papers. We found that the microcosm studies have been reported in 12 instances, and mesocosm studies have been reported in only once until now. Advanced research was mostly evaluated at the microorganism level. But integrated analysis of nanotoxicity is required to research the interactions based of various species. Thus, our studies analysed the trend of microcosm studies on nanomaterials in water and soil ecosystems and suggested future directions of microcosm research of nanomaterials.

Comparative Quantification of LacZ (β-galactosidase) Gene from a Pure Cultured Escherichia coli K-12

  • Han, Ji-Sun;Kim, Chang-Gyun
    • Environmental Engineering Research
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    • v.14 no.1
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    • pp.63-67
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    • 2009
  • Escherichia coli K-12 (E. coli K-12) is a representative indicator globally used for distinguishing and monitoring dynamic fates of pathogenic microorganisms in the environment. This study investigated how to most critically quantify lacZ ($\beta$-galactosidase) gene in E. coli K-12 by two different real-time polymerase chain reaction (real-time PCR) in association with three different DNA extraction practices. Three DNA extractions, i.e., sodium dodecyl sulfate (SDS)/proteinase K, magnetic beads and guanidium thiocyanate (GTC)/silica matrix were each compared for extracting total genomic DNA from E. coli K-12. Among them, GTC/silica matrix and magnetic beads beating similarly worked out to have the highest (22-23 ng/${\mu}L$) concentration of DNA extracted, but employing SDS/proteinase K had the lowest (10 ng/${\mu}L$) concentration of DNA retrieved. There were no significant differences in the quantification of the copy numbers of lacZ gene between SYBR Green I qPCR and QProbe-qPCR. However, SYBR Green I qPCR obtained somewhat higher copy number as $1{\times}10^8$ copies. It was decided that GTC/silica matrix extraction or magnetic beads beating in combination with SYBR Green I qPCR can be preferably applied for more effectively quantifying specific gene from a pure culture of microorganism.

Isomeric Effects on Volatilization of 1,3-Dichloropropene Fumigant in Soil

  • Kim, Jung-Ho;Mallavarapu, Megharaj
    • Journal of Environmental Science International
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    • v.18 no.12
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    • pp.1325-1330
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    • 2009
  • The fumigant 1,3-dichloropropene (1,3-D) was recently proposed as a direct replacement for methyl bromide ($CH_3Br$) in soil fumigation. This study was conducted to better understand behavior phase partitioning, diffusion and volatilization of 1,3-D as affected by isomer. The Henry's law constant(KH) of cis-1,3-D and trans-1,3-D was 0.058 and 0.037 at $20^{\circ}C$, respectively. $K_H$ of cis form of 1,3-D was higher than that of trans form of 1,3-D. To compare with volatilization of 1,3-D isomer, soil column [70 cm (length)${\times}$12 cm (i.d.)] included a shank injection at 30 cm with 300 kg $ha^{-1}$. Maximum cis-1,3-D and trans-1,3-D concentration reached 57 mg $L^{-1}$ and 39 mg $L^{-1}$ at 30 cm depth at 1h after application. Cumulatively, after 10 days, 51.8% and 43.57% of applied cis-1,3-D and trans-1,3-D was emitted via volatilization, respectively. The total losses of cis-1,3-D were significantly greater than that of trans-1,3-D. Finally, cis-1,3-D and trans-1,3-D, such as isomer are dominant of 1,3-D fates in soil.

Air Monitoring of Persistent Organic Pollutants Using Passive Air Samplers (Passive Air Sampler를 이용한 잔류성 유기오염물질의 대기 모니터링)

  • Choi, Sung-Deuk;Chang, Yoon-Seok
    • Journal of Korean Society for Atmospheric Environment
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    • v.21 no.5
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    • pp.481-494
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    • 2005
  • The monitoring of persistent organic pollutants (POPs) in the atmosphere is a basis for the study of the fate of POPs in multimedia environments. Recently, passive air samplers (PASs) for POPs have been developed. In this paper, we deal with the principle, properties, and applications of the PAS. The principle of PAS, which has no pump, is physical sorption of semi-volatile organic chemicals on various sorbent materials. The PAS is much smaller than a high-volume air sampler and does not need electricity. These properties of the PAS make it possible to conduct various-scaled environmental monitoring all over the world including the Arctic and Antarctic, but the major disadvantage of PAS is its long sampling periods up to 2 years. To date, four kinds of PAS have been developed: polyurethane foam (PUF), polymer-coated glass (POG), semi-permeable membrane devices (SPMDs), and XAD resin-based PAS. Among them, SPMDs have been commercialized and are most widely used now. Meanwhile, the POPs emitted from China have a large potential to influence the levels and fates of POPs in Korea. Since characteristics of PAS are quite useful to monitor long-range transport of POPs, the use of PAS is highly recommended.

A Single Cell Multimedia Fate Model for Endocrine Disrupting Chemicals

  • Park, Kyunghee;Junheon Youn;Daeil Kang;Lee, Choong;Lee, Dongsoo;Jaeryoung Oh;Sunghwan Jeon;Jingyun Na
    • Proceedings of the Korea Society of Environmental Toocicology Conference
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    • 2003.05a
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    • pp.149-149
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    • 2003
  • To understand environmental paths of the transport and accumulation of endocrine disrupting chemicals (EDCs), a single cell multimedia fate model has been constructed and evaluated. The EDCs of concern were PAHs, Organochlorine Pesticides (OCPs), PCBs, Alkyl phenols, and phthalates. An evaluation model was designed for the multimedia distribution, including air, water, soil, sediment and vegetation. This model was verified using reported values and via monitoring data. Based on collected data, the distribution trends of EDCs with respect to environmental media were analyzed. Those results have applied to the model for the prediction of the spatial and temporal distribution of EDCs in Seoul. Especially, phenol compound, phthalates, PAHs, PCBs and organochlorine pesticides were estimated and the model was verified. This model was successfully conducted to environmental media, such as air (vapor and suspended particles), soils (forest soil, bare soil, and cement-concrete covered soil), water (dissolved and suspended solids), sediment, trees (deciduous and coniferous). The discrepancies between the model prediction and the measured data are approximately within or near a factor of 10 for the PAHs of three rings through that of six rings, implying that multimedia distribution of the PAHs could be predicted with a factor of 10. Concerning about the air equilibrium may be assumed, a fugacity at steady state is similar in all environmental media. Considering the uncertainties of this model, the use of equilibrium models may be sufficient for assessing chemical fates. In this study, a suggestion was made that modeling and estimation of chemicals in environmental multimedia be rigorously evaluated using the measured flux data. In addition, these data should be obtained, for example, from the precise and standardized inventory of the target chemicals. The model (EDC Seoul) will be refined in an on-going research effort and will be used to support decision-making concerning the management of EDCs.

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Direct Conversion to Achieve Glial Cell Fates: Oligodendrocytes and Schwann Cells

  • Wonjin Yun;Yong Jun Kim;Gabsang Lee
    • International Journal of Stem Cells
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    • v.15 no.1
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    • pp.14-25
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    • 2022
  • Glia have been known for its pivotal roles in physiological and pathological conditions in the nervous system. To study glial biology, multiple approaches have been applied to utilize glial cells for research, including stem cell-based technologies. Human glial cells differentiated from pluripotent stem cells are now available, allowing us to study the structural and functional roles of glia in the nervous system, although the efficiency is still low. Direct conversion is an advanced strategy governing fate conversion of diverse cell types directly into the desired lineage. This novel strategy stands as a promising approach for preliminary research and regenerative medicine. Direct conversion employs genetic and environmental cues to change cell fate to that with the required functional cell properties while retaining maturity-related molecular features. As an alternative method, it is now possible to obtain a variety of mature cell populations that could not be obtained using conventional differentiation methods. This review summarizes current achievements in obtaining glia, particularly oligodendrocytes and Schwann cells.

Fates and Removals of Micropollutants in Drinking Water Treatment (정수처리 과정에서의 미량오염물질의 거동 및 제거 특성)

  • Nam, Seung-Woo;Zoh, Kyung-Duk
    • Journal of Environmental Health Sciences
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    • v.39 no.5
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    • pp.391-407
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    • 2013
  • Micropollutants emerge in surface water through untreated discharge from sewage and wastewater treatment plants (STPs and WWTPs). Most micropollutants resist the conventional systems in place at water treatment plants (WTPs) and survive the production of tap water. In particular, pharmaceuticals and endocrine disruptors (ECDs) are micropollutants frequently detected in drinking water. In this review, we summarized the distribution of micropollutants at WTPs and also scrutinized the effectiveness and mechanisms for their removal at each stage of drinking water production. Micropollutants demonstrated clear concentrations in the final effluents of WTPs. Although chronic exposure to micropollutants in drinking water has unclear adverse effects on humans, peer reviews have argued that continuous accumulation in water environments and inappropriate removal at WTPs has the potential to eventually affect human health. Among the available removal mechanisms for micropollutants at WTPs, coagulation alone is unlikely to eliminate the pollutants, but ionized compounds can be adsorbed to natural particles (e.g. clay and colloidal particles) and metal salts in coagulants. Hydrophobicities of micropollutants are a critical factor in adsorption removal using activated carbon. Disinfection can reduce contaminants through oxidation by disinfectants (e.g. ozone, chlorine and ultraviolet light), but unidentified toxic byproducts may result from such treatments. Overall, the persistence of micropollutants in a treatment system is based on the physico-chemical properties of chemicals and the operating conditions of the processes involved. Therefore, monitoring of WTPs and effective elimination process studies for pharmaceuticals and ECDs are required to control micropollutant contamination of drinking water.

Changing C-N Interactions in the Forest Floor under Chronic N Deposition: Implications for Forest C Sequestration

  • Park, Ji-Hyung
    • Journal of Ecology and Environment
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    • v.31 no.3
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    • pp.167-176
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    • 2008
  • Atmospheric N deposition has far-reaching impacts on forest ecosystems, including on-site impacts such as soil acidification, fertilization, and nutrient imbalances, and off-site environmental impacts such as nitrate leaching and nitrous oxide emission. Although chronic N deposition has been believed to lead to forest N saturation, recent evidence suggests that N retention capacity, particularly in the forest floor, can be surprisingly high even under high N deposition. This review aims to provide an overview of N retention processes in the forest floor and the implications of changing C-N interactions for C sequestration. The fate of available N in forest soils has been explained by the competitive balance between tree roots, soil heterotrophs, and nitrifiers. However, high rates of N retention have been observed in numerous N addition experiments without noticeable increases in tree growth and soil respiration. Alternative hypotheses have been proposed to explain the gap between the input and loss of N in N-enriched, C-limited systems, including abiotic immobilization and mycorrhizal assimilation, both of which do not require additional C sources to incorporate N in soil N pools. Different fates of N in the forest floor have different implications for C sequestration. N-induced tree growth can enhance C accumulation in tree biomass as observed across temperate regions. C loss from forests can amount to or outweigh C gain in N-saturated, declining forests, while another type of 'C-N decoupling' can have positive or neutral effects on soil C sequestration through hampered organic matter decomposition or abiotic N immobilization, respectively.