• Title/Summary/Keyword: environmental fate

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Estimated Bioaccumulation properties of Acetanilide using BCFWIN (BCF WIN을 이용한 Acetanilide의 생물농축특성 평가)

  • Kwon, Min-Jeong;Choi, Yoon-Ho;Song, Sang-Hwan;Park, Hye-Youn;Koo, Hyun-Ju;Park, Kwang-Sik
    • Environmental Analysis Health and Toxicology
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    • v.16 no.4
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    • pp.223-226
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    • 2001
  • Acetanilide is a High Production Volume Chemical, which is produced about 2,300 tons/year in Korea as of 1998 survey. Most is used as an intermediate for synthesis of pharmaceuticals and dyes. The chemical is one of seven chemicals, which are under the frame of OECD SIDS program sponsored by National Institute of Environmental Research of Korea. Regarding the information on the environmental fate. bioconcentration is one of important factor to estimate the environmental tranfer. However, measurement of bioconcentration needs high expense and time. For this reason, OECD recommends to use BCFWIN model to estimate bioconcentration of organic chemicals, BCFWIN estimates the bioconcentration factor (BCF) of an organic compound using the log octanol-water partition coefficient (Kow) of the compound. Structures are entered into BCFWIN through SMITES (Simplified Molecular Input Line Entry System) notations. The BCFWIN method classifies a compound as either ionic or non-ionic. ionic compounds include carboxylic acids, sulfonic acids and salts of sulfonic acids, and charged nitrogen compounds (nitrogen with a + 5 valence such as quaternary ammonium compounds). All other compounds are classified as non-ionic. In this study, bioaccumulation of acetanilide was estimated using BCFWIN model based on SMIIES notation, chemical name data and partition coefficient as one of environmental fate/distribution of the chemical elements.

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Fate and mass balance of pharmaceuticals of unit processes in a sewage treatment plant (하수처리시설 단위공정별 잔류의약물질 거동 및 물질수지 분석)

  • Park, Junwon;Kim, Changsoo;Lee, Wonseok;Lee, Soo-Hyung;Chung, Hyenmi;Jeong, Dong-Hwan
    • Journal of Korean Society of Water and Wastewater
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    • v.33 no.5
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    • pp.367-377
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    • 2019
  • In this study, the fate and removal of 15 pharmaceuticals (including stimulants, non-steroidal anti-inflammatory drugs, antibiotics, etc.) in unit processes of a sewage treatment plant (STP) were investigated. Mass loads of pharmaceuticals were 2,598 g/d in the influent, 2,745 g/d in the primary effluent, 143 g/d in the secondary effluent, and 134 g/d in the effluent. The mass loads were reduced by 95% in the biological treatment process, but total phosphorous treatment did not show a significant effect on the removal of most pharmaceuticals. Also, mass balance analysis was performed to evaluate removal characteristics of pharmaceuticals in the biological treatment process. Acetaminophen, caffeine, acetylsalicylic acid, cefradine, and naproxen were efficiently removed in the biological treatment process mainly due to biodegradation. Removal efficiencies of gemfibrozil, ofloxacin, and ciprofloxacin were not high, but their removal was related to sorption onto sludge. This study provides useful information on understanding removal characteristics of pharmaceuticals in unit processes in the STP.

Development of National Scale Environmental & Geographical Information System for Supporting Exposure Assessment (노출평가를 위한 전국규모의 환경지리지형정보 시스템 개발)

  • Kim, Jong-Ho;Kim, Mi-Sug;Kwak, Byeong-Kyu;Yoo, Hong-Suk;Shin, Chi-Bum;Yi, Jong-Heop
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.10
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    • pp.1082-1089
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    • 2006
  • This study describes a methodology to develop a environmental and geographical information system for managing a national scale which is supports the environmental fate modeling. This system was developed via the integration of environmental and geographical information database(DB) and the DB usage software. For the sound environmental management, the DB were constructed by extracting the geometrical figures-such as points, polylines, and/or polygons-based on the geographical information previously developed in Korea. Then it was connected with the environmental information. Based on the Visual Basic Complier, the software can be a useful tool for visualizing the DB, for searching the environmental & geographical information, and supporting the environmental fate modeling.

Applicability Analysis of Chemical Fate Model Considering Climate Change Impact in Municipal and Industrial Areas in Korea (기후변화를 고려한 화학물질거동모형의 도시·산단지역 적용성 연구)

  • Ryu, Sun-Nyeo;Lee, Woo-Kyun
    • Journal of Climate Change Research
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    • v.6 no.2
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    • pp.121-131
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    • 2015
  • As the temperature has changed by climate change, changes in its own characteristic values of the chemical substance or the movement and distribution of chemicals take place in accordance with the changes of hydrological and meteorological phenomena. Depending on the impact of climate change on the chemical behavior, it is necessary to understand and predict quantitative changes in the dynamics of the environment of pollutants due to climate change in order to predict in advance the occurrence of environmental disasters, and minimize the impact on the life and the environment after the incident. In this study, we have analysed and compared chemical fate models validated by previous studies in terms of model configuration, application size and input/output factors. The potential models applicable to municipal and industrial areas were selected on the basis of characteristic of each model, availability of input parameters and consideration for climate change, identified the problems, and then presented an approach to improve applicability.

The Pollution Potential of Animal Production Systems : Origin and Atmospheric Cycling of Their Pollutants (축산환경의 오염 잠재력 : 축산오염 물질의 발생과 대기환경계 순환)

  • 김기현;김동균;윤종만
    • Journal of Animal Environmental Science
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    • v.1 no.2
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    • pp.155-164
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    • 1995
  • Despite considerable progresses made in our understanding of environmental fate of pollutants stemming from animal production systems, relatively little is known about the processes and mechanisms regulating their dispersement (via emission) into and deposition from the earth's atmospheric system. Here we present and summarize up-to-date knowledge on this topic with a main emphasis on their origin, physico-chemical characteristics, and geochemical distribution behavior.

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Polychlorinated Biphenyls (PCBs) in the Bio-geochemistry of Oceans

  • Kannan, Narayanan
    • Journal of Marine Bioscience and Biotechnology
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    • v.2 no.4
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    • pp.201-208
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    • 2007
  • Polychlorinated biphenyls (PCBs) are anthropogenic contaminants found globally in water, ice, soil, air and sediment. Modern analytical techniques allow us to determine these chemicals in environmental matrices at parts per trillion levels or lower. Environmental forensic on PCBs opens up new avenues of investigation such as transport and fate of water masses in oceans, sedimentation, onset of primary production, migration of marine mammals, their population distribution and pharmacokinetics of drugs inside organisms. By virtue of persistence, bioaccumulation, bioconcentration and structure-activity relationship PCBs emerge as unconventional chemical tracers of new sort.

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Oil Spill Spreading of Continuous Spills

  • Lee, Jung-Lyul;Chu, Jin-Kyu
    • Proceedings of the Korean Society of Coastal and Ocean Engineers Conference
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    • 1998.09a
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    • pp.40-44
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    • 1998
  • Since oil spills discharged by offshore oil production platforms, ship accidents etc., cause many environmental problems, forecasts of drift and spreading of the spilled oil are requested as a basis for oil spill combat management. The numerical approach has been thought as the most effective methods of such forecast. In general, the oil spill model takes into account the trajectory and fate of oil, including drifting, spreading, evaporation, dispersion, emulsification, shoreline standing, and so on. (omitted)

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Fate and Transport of Viruses in Soil and Groundwater Environments (토양.지하수 환경에서 바이러스의 거동)

  • Park, Jeong-Ahn;Yoon, Seo-Young;Kim, Song-Bae
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.7
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    • pp.504-515
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    • 2012
  • Groundwater is widely used as drinking water supplies around the world. However, microbial contamination of groundwater is a serious environmental problem that degrades drinking water quality and poses a great threat to human health. Among the pathogenic microorganisms such as viruses, bacteria, and protozoa, viruses are not readily removed during transport through soils, having high mobility in groundwater environment due to their smaller size compared to bacteria and protozoa. Studies regarding the fate and transport of viruses in soils and aquifers are necessary to determine the vulnerability of groundwater to microbial contamination and to secure safe drinking water sources. Also, these studies provide important information to establish the regulations and policies related to public health. This review paper presented the field and laboratory studies conducted for the fate and transport of viruses in subsurface environments. Also, the paper provided the factors affecting the fate and transport of viruses, the characteristics of bacteriophages used for virus studies, and virus transport model/colloid filtration theory. Based on this review work, future researches should be performed actively to set up the viral protection zone for the protection of groundwater from viral contamination sources. Especially, the researches should be focused on the development of mathematical models to calculate the setback distance and travel time for the viral protection zone along with the accumulation of information related to the model parameters.

Analysis of Contaminant Transport in the Ground using the Lattice-Boltzmann Method (격자 볼츠만 방법에 의한 지반 내 오염물질의 거동 분석)

  • Kang, Dong Hun;Yun, Tae Sup
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.32 no.6C
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    • pp.267-274
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    • 2012
  • The conventional approach to evaluate the contaminant transport in soils adopts the macro-scale implementation while the pore configuration and network is a dominant factor to determine the fate of contaminant. However, the observation of fate and transport at pore scale may not be readily approachable because of the computational expenses to solve Navier-Stokes equation. We herein present the 2D Lattice-Boltzmann method that enables to assess the local fluid velocity and density efficiently for the case of single phase and multi-components. The solute fate spatio-temperal space is explicitly determined by the advection of fluid flow. Two different types of idealized pore space provides the path of fluid. Also, solute transport, the velocity field and average concentration of solute are computed in steady state. Results show that the pore geometry such as tortuosity mainly affect the solute fate. It highlights the significance of the pore configuration and shape in granular soils and rock discontinuity in spite of the equivalent porosity.

Properties and fate of nitrogen in a reclaimed tidal soil (국내 간척지의 토양 특성과 질소 동태)

  • Kim, Hye-JIn;Kim, Gi-Rim;Woo, Hyun-Nyung;Park, Suk-Hyun;Shin, Ji-Hoon;Choi, Yoon-Chul;Chung, Doug-Young
    • Korean Journal of Agricultural Science
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    • v.38 no.2
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    • pp.301-307
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    • 2011
  • In this article, we reviewed properties of reclaimed tidal soil and fate of nitrogen in its soil. The results were summarized as followings. Most of the soil derived from the fluvio-marine deposit were silly textured soils. The EC of the Saemanguem soil were ranged from 14.7 to 33.9 dS $m^{-1}$, pH was 7.7. The organic matter content was low with 1.5 g $kg^{-1}$. The cation exchange capacity was 7.2 cmol $kg^{-1}$ and exchangeable sodium percent was high with range 45.1 % to 56.2%. High sodium concentration caused poor drainage. The salinity significantly affects efficiency of N fertilizer in reclaimed tidal soil.