• 제목/요약/키워드: environmental diffusion

검색결과 919건 처리시간 0.025초

콘크리트의 염소이온 확산특성에 미치는 시멘트 종류의 영향 (Influence of Cement Type on the Diffusion Characteristics of Chloride Ion in Concrete)

  • 박재임;배수호;이광명;김지상;차수원
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2006년도 추계 학술발표회 논문집
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    • pp.573-576
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    • 2006
  • To predict service life of concrete structures exposed to chloride attack, surface chloride concentration, diffusion coefficient of chloride ion, and chloride corrosion threshold value in concrete, are used as important factors. of these, as the diffusion coefficient of chloride ion for concrete is strongly influenced by concrete quality and environmental conditions of structures and may significantly change the service life of structures, it is considered as the most important factor for service life prediction. The qualitative factors affecting the penetration and diffusion of chloride ion into concrete are water-binder(W/B) ratio, age, cement type and constituents, chloride ion concentration of given environment, wet and dry conditions, etc. In this paper the influence of cement type on the diffusion characteristics of chloride ion in concrete was investigated through the chloride ion diffusion test. For this purpose, the diffusion characteristics in concrete with cement type such as ordinary portland cement(OPC), binary blended cement(BBC), and ternary blended cement(TBC) were estimated for the concrete with W/B ratios of 32% and 38%, respectively. It was observed from the test that the difussion characteristics of BBC containing OPC and ground granulated blast-furnace slag was found to be most excellent of the cement type used in this study.

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CALPUFF 모델을 이용한 기후변화에 따른 일산화탄소의 대기오염 영향 분석 (Analysis about CO Diffusion Change Caused by Climate Change Using CALPUFF)

  • 하민진;이태경;이임학;전의찬
    • 한국기후변화학회지
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    • 제8권2호
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    • pp.81-89
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    • 2017
  • In this study CALPUFF was used to estimate the influence of temperature rise, according to the observation value of temperature rise based RCP scenario, on meteorological elements (wind direction, wind speed, mixing height) and the change of pollutant diffusion. According to the result. applying estimated value of year 2050 temperature rise, the mixing height is increased as per the temperature rise, so the range of atmospheric diffusion is widened. In summer case, by applying temperature rise of $4^{\circ}C$ and comparing with before applying temperature rise, there was change of diffusion range as per the change of temperature between 10 AM to 11 PM. And the range of diffusion was wider than that of before temperature rise. In winter case, by applying estimated value of temperature rise, $2.3^{\circ}C$, diffusion range has been changed between 8 AM to 4 PM, showing different diffusion aspect from summer. Also, according to the result of air pollution level assessment with temperature rise, it was proved that the ratio of area with increasing air pollution level has been getting higher by increase of temperature.

하절기 천안 제 2산업단지의 대기오염확산 및 악취물질에 관한 연구 (Dispersion of Air Pollutants Dispersion and Odorous Materials in Cheon-an Second Industrial Complex)

  • 정진도;홍정희;김수영;김정태;최소진
    • 대한환경공학회지
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    • 제28권12호
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    • pp.1316-1322
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    • 2006
  • 본 연구는 천안 제 2산업단지에서 배출되는 대기오염물질과 악취물질을 분석하고 대기오염물질의 확산모델링을 수행하고자 함을 목적으로 한다. 측정은 12가지 지정 악취물질과 대기오염물질의 농도에 대하여 2005년 8월에 수행하였다. 악취물질은 주요 배출원을 중심으로 부지경계선에서 측정 및 분석을 실시하였으며, 대기오염물질은 ISCST3모델을 이용하여 대기오염확산 농도를 계산하였다. Air Master는 현재 국내 대기환경영향평가에 많이 사용되고 있고 U.S. EPA의 추천모델인 ISC3모델 중 ISCST3모델을 사용하였다. 따라서 천안 제 2산업단지를 대상으로 하절기 대기오염물질을 측정하여 모델링 하고 악취물질은 시료채취 후 분석을 실시하여 주변 지역에 영향을 끼치는 대기오염물질과 악취발생물질의 종류와 발생 원인을 규명하고자 한다.

콘크리트의 염소이온 확산특성에 미치는 물-시멘트비 및 양생조건의 영향 (Influence of Water-Cement Ratios and Curing Conditions on the Diffusion Characteristics of Chloride Ion in Concrete)

  • 배수호;이광명;김지상;정상화
    • 대한토목학회논문집
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    • 제26권4A호
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    • pp.753-759
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    • 2006
  • 염해환경 하에 있는 콘크리트 구조물의 내구수명을 예측하기 위하여 콘크리트의 표면 염소이온 농도, 염소이온 확산계수 및 임계 염화물량 등이 주요 인자로 사용된다. 이들 중 염소이온 확산계수는 콘크리트 품질 및 주변 환경조건 등에 많은 영향을 받으며, 이에 따라 콘크리트 구조물의 내구수명이 크게 달라지기 때문에 내구수명을 예측하는 데 가장 중요한 인자로 평가되고 있다. 콘크리트 내의 염소이온 침투 확산에 영향을 미치는 정성적인 주요 인자로는 물-시멘트비, 재령, 양생조건, 주위 환경의 염소이온 농도 및 건습조건 등을 들 수 있는데, 본 연구에서는 염소이온 확산실험을 통해 물-시멘트비와 양생조건이 콘크리트의 염소이온 확산특성에 미치는 영향을 조사하였다. 전위차를 이용한 촉진시험법에 의하여 확산셀을 통과한 전위차를 측정한 후, Andrade의 모델에 의하여 전압강하량을 고려하여 3종류의 물-시멘트비를 갖는 콘크리트의 염소이온 확산계수를 구하였다. 또한, 양생조건별로 물-시멘트비 및 재령 효과를 고려한 회귀분석을 통하여 염소이온 확산계수 추정식을 제안하였다.

심층 지하에서의 육가 크롬 확산 (Diffusion of Cr(VI) in Porous Media)

  • 현재혁
    • 지질공학
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    • 제3권2호
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    • pp.203-214
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    • 1993
  • 액체 산업폐기물을 심층지하에 방출시, 폐기물의 이동은 지하매체의 낮은 투수율로 인하여 분자확산에 의해 좌우된다. 하편 확산에 의한 이동은 Fick의 제2법칙으로 예측할 수 있다. 본 연구에서는 실험을 통한 Cr(VI)의 확산 이동계수를 구하였다. 다공질내에서의 Cr(VI)이동을 추적하기 위해 방사성 동위원소인 $^{51}Cr$을 사용하였으며, Fick의 제2법칙에 대한 해석해를 구해 Cr(VI)의 확산계수를 결정하였다. 본 연구에서는 온도, $^{51}Cr$의 양, 염소 이온의 양, 매체의 건조밀도를 환경적 변화인자로 이용하였다.

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패각 폐기물을 이용한 황화반응 모델에 관한 연구 (A Study on the Model of Sulfidation Kinetics Using Seashell Wastes)

  • 김영식
    • 한국환경보건학회지
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    • 제30권5호
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    • pp.395-401
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    • 2004
  • In this study, lots of methods have been studing to utilize energy and decrease contaminated effluents. There has been great progress on IGCC (Integrated gasification combined cycle) to reduce thermal energy losses. The following results have been conducted from desulfurization experiments using waste shell to remove $H_{2}S$. Unreacted core model ior desulfuriration rate prediction of sorbent was indicated. These were linear relationship between time and conversion. So co-current diffusion resistance was conducted reaction rate controlling step. The sulfidation rate is likely to be controlled primarily by countercurrent diffusion through the product layer of calcium sulfide(CaS) formed. Maximum desulfurization capacity was observed at 0.631 mm for lime, oyster and hard-shelled mussel. The kinetics of the sorption of $H_{2}S$ by CaO is sensitive to the reaction temperature and particle size at $800^{\circ}C$, and the reaction rate of oyster was faster than the calcined limestone at $700^{\circ}C$.

Optimum Sewage Discharge Strategy for Coastal Waters

  • Kang, Yun-Ho;Lee, Moon-Ock
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • 제10권S_3호
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    • pp.97-106
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    • 2001
  • To improve the water quality, particularly for sea bathers, the behaviour of wastewater from sewage outfalls in water adjacent to Swansea, UK, was studied using a mathematical model. The water quality in the sewage receiving basin was determined using factors like the outfall diffuser location(distance from land boundary), sewage treatment scheme, discharge time, and bacteria decay rate, etc. With respect to these factors, an optimal strategy for sewage discharge was then investigated to minimize bacteria levels along the bathing beaches. As water quality criteria, predicted faecal coliform levels were monitored along the coast adjacent to the outfall locations. The resultant values were compared with EC Mandatory(<2000, 95 % of 20 samples) and Guideline Standards(< 100, 80 % of 20 samples). For the advective-diffusion equation, the non linear advective terms were represented using the ULTIMATE algorithm and the third-order accurate QUICKEST scheme to avoid numerical diffusion. Details of the simulation results are then presented as an optimal policy for sewage discharge in the region.

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난방시 가압식 바닥취출 공조방식의 실내온열환경 평가 (An Estimation on Indoor Thermal Environment by Pressurized Plenum Under Floor Air Conditioning System in Heating)

  • 최은훈;이용호;권영철;황정하
    • 한국태양에너지학회 논문집
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    • 제30권4호
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    • pp.92-99
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    • 2010
  • The purpose of this study is to apply pressurized plenum under floor air conditioning system to office areas to understand characteristics of indoor thermal environment based on forms of diffusers. For doing this, the author conducted experiment of module measurement, and based on the results, analyzed indoor temperature distribution and velocity distribution based on direction of diffusion by using Computational Fluid Dynamics(CFD), and estimated the Predicted Mean Vote(PMV) of residents based on forms of diffusers to present the optimal air conditioning of the pressurized plenum under floor air conditioning system in heating. The results of this study are as follows. First, as for forms of diffusers, distributed diffusers rather than conical and grill diffusers were favorable in maintaining $24^{\circ}C$, the established temperature in heating, were active in velocity flowing, and were wide in a radius of diffusion. Second, as for position of pressurizing, the difference between upper and lower temperature was wider in center, lateral, and dispersed pressurizing (in order). As for velocity distribution, the velocity was more increased in lateral, center, and dispersed pressurizing(in order), indicating that dispersed pressurizing maintained uniform thermal environment. Third, as for diffusion direction, mixed direction showed less difference between upper and lower temperature and the difference in velocity between center and lateral part was 0.01m/1, indicating that it maintained uniform thermal environment. Fourth, as for the PMV of residents based on the forms of diffusers, the dispersed type showed(+) values above (0) when applied variably based on the position of diffuser, presenting thermal feeling of "being comfortable" to residents.

Franz Diffusion Cell을 이용한 문신용 염료 내 유해물질의 피부 투과특성 연구 (Permeation Characteristics of Hazardous Substances in Tattoo Dye using Franz Diffusion Cells)

  • 박교현;정세훈;신호상;김배환
    • 한국환경보건학회지
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    • 제42권1호
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    • pp.61-70
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    • 2016
  • Objectives: The purpose of this study is to determine the exposure risk to tattoo components by analyzing skin absorption using the in vitro method. Tattoos are commonly used for cosmetic purposes, and the skin of not only the operator but of the people who are undergoing the cosmetic procedure is continuously exposed to hazardous chemicals. Methods: Skin permeation risk determination was conducted by the in vitro Franz diffusion cell method according to the ingredient types of tattoo dyes, such as volatile organic compounds (VOCs), non-volatile organic compounds and heavy metals, using hairless mouse full skin and human cadaver epidermis. Results: The major components with good skin penetration for each type of tattoo dye ingredient were clarified. Among the tatto dye ingredients, 1,2-Dichlorobenzene, Zn, Al, Pb and Ti showed good skin penetration. Most of the skin transmission rates were higher in hairless mouse full skin than in human cadaver epidermis. Conclusion: A possible exposure risk to hazardous substances in tattoo dyes was confirmed from this study. These results are expected to provide a positive contribution to the establishment of management regulations for tattoo dyes.