• Economic and Environmental Geology
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• v.53 no.1
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• pp.11-21
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• 2020

One-dimensional analytical solutions were used for forward and back diffusion of trichloroethylene (TCE) and tetrachloroethylene (PCE) in a single system with high- and low-permeability layers. Concentration profiles in a low-permeability layer, diffusive fluxes at the interface between the high- and low-permeability layers, and contaminant persistence in the high-permeability layer due to back diffusion were simulated with a comparison of semi-infinite and finite analytical solutions. In order to validate the analytical solutions used in this study, the results of one-dimensional analytical solutions developed by Yang et al. (2015) were compared with Nash-Sutcliffe model efficiency coefficient (NSE). When compared with Yang et al. (2015), the analytical solutions used in this study showed good agreements (NSE = 0.99). When compared with semi-infinite analytical solutions, TCE and PCE concentration profiles in the low-permeability layer, the diffusive fluxes, and the contaminant tailings of the high-permeability layer were underestimated. In order to determine the appropriate analytical solutions based on the effective diffusion coefficient, the thickness of the low-permeability layer, and the diffusion time in the TCE and PCE contaminated site, a term of dimensionless diffusion length (Z_d) was used. If the Z_d is less than 0.7, the semi-infinite solutions can be used to simulate accurate concentration profiles in low-permeability layers. If the Z_d is greater than 0.7, the reliability of simulations may be improved by using the finite solutions.

• Computers and Concrete
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• v.22 no.3
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• pp.261-267
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• 2018

Long-term deformation of a steel-reinforced concrete (SRC) column is different from that of a reinforced concrete (RC) column due to the different moisture distribution. Wide-flange steel in an SRC column obstructs diffusion and makes long-term deformation slower. Previous studies analyzed the characteristics of long-term deformation of SRC columns. In this study, an additional experiment is conducted to more precisely investigate the effect of wide-flange steel on the long-term deformation of SRC columns. Long-term deformation, especially creep of SRC columns with various types of wide-flange steel, is tested. Wide-flange steel for the experiment is made of thin acrylic panels that can block diffusion but does not have strength, because the main purpose of this study is to exclusively demonstrate the long-term deformation of concrete caused by moisture diffusion, not by the reinforcement ratio. Experimental results show that the long-term deformation of a SRC column develops slower than that in a RC column, and it is slower as the wide-flange steel hinders diffusion more. These experimental results can be used for analytical prediction of long-term deformation of various SRC columns. An example of the analytical prediction is provided. According to the experimental and analytical results, it is clear that a new prediction model for long-term deformation of SRC columns should be developed in further studies.

• Proceedings of the Korean Operations and Management Science Society Conference
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• 2003.11a
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• pp.43-46
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• 2003

Based on the innovation literature, this study has identified nine variables under three categories (technological, environmental, and organizational contexts) and evaluated their influence on e-marketplace adoption and diffusion within organizations. We have also assessed whether level of e-marketplace diffusion is related to the procurement performance of the purchasing organizations.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2002.09a
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• pp.327-330
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• 2002

In this study, analyses of contaminant transport are peformed to evaluate the diffusion effect of A sewage tunnel. First, Crank's analytical method is used to measure the concentration change of contaminant with time and space. Two dimensional numerical analysis is performed to measure concentration distribution of contaminant. Both methods show that the diffusion effect is little even after 500 years. This means that when flow converges into the tunnel, the environmental effect of contaminant in tunnel is not serious because there is no advection occurs.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 1996.11a
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• pp.58-62
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• 1996

To check the variability of the effective diffusion coefficient in the unsaturated porous soil media. a Monte Carlo simulation was done for the equation suggested by Millington and Quirk(1961). The results shows that the probability density function of D$_{c}$/D$_{o}$ is positively skewed. It means the chance of having less effective diffusion coefficient values in the soil media than mean value is high. Also, the distribution types of D$_{c}$/D$_{o}$ are about same regardless of assumed distribution types of input parameters.ers.ers.

• Computers and Concrete
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• v.10 no.1
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• pp.79-93
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• 2012

This paper estimates theoretically the diffusion-reaction behaviour of sulfate ion in concrete caused by environmental sulfate attack. Based on Fick's second law and chemical reaction kinetics, a nonlinear and nonsteady diffusion-reaction equation of sulfate ion in concrete, in which the variable diffusion coefficient and the chemical reactions depleting sulfate ion concentration in concrete are considered, is proposed. The finite difference method is utilized to solve the diffusion-reaction equation of sulfate ion in concrete, and then it is used to simulate the diffusion-reaction process and the concentration distribution of sulfate ion in concrete. Afterwards, the experiments for measuring the sulfate ion concentration in concrete are carried out by using EDTA method to verify the proposal model, and results show that the proposed model is basically in agreement with the experimental results. Finally, Numerical example has been completed to investigate the diffusion-reaction behavior of sulfate ion in the concrete plate specimen immersed into sulfate solution.

• Economic and Environmental Geology
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• v.26 no.3
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• pp.421-429
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• 1993

Dissolution reactions of chemical grade zinc sulfide and natural sphalerite were studied in ferric chloride solution as an oxidant. To enhance the leaching reaction, ultrasonic technique was employed in this investigation. For the reaction with pure zinc sulfide, chemical reaction was the rate limiting step in the range of low conversion irrespective of applying ultrasonic wave. And the diffusion through liquid film instead of diffusion through product layer of free sulfur was the rate determining step because ultrasonic vibration removes the product from reaction zone. In the case of sphalerite with the ultrasonic vibrator, it was found that inert mineral layer diffusion was the rate determining step, in which the elemental sulfurs formed were removed by the ultrasonic action. Experimental results showed that the ultrasonic technique proved to be the methods which can significants improve the leaching performance.

• Journal of Environmental Science International
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• v.10 no.5
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• pp.343-350
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• 2001

To investigate air quality away from the coastal urban source region, we used a hybrid Eulerian - Lagrangian method which can describe the formation, transport, transform and deposition processes in complex terrain, with inclusion of shipping sources that were considered to be important emission in the coastal urban region. The result of the Eulerian advection - diffusion prediction was quite similar to that of the Lagrangian particle diffusion prediction. It showed that pollutants emitted from Sasang and Janglim industrial complexes can affect Hwamyeong and the coastal, respectively. During the daytime the concentration was low due to large deposition flux and terrain effect.

• Journal of Environmental Science International
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• v.11 no.12
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• pp.1321-1326
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• 2002

A numerical model is investigated to predict a behavior of the gaseous volatile organic compounds and a subsurface contamination caused by them in the unsaturated zone. Two dimensional advective-dispersion equation caused by a density difference and two dimensional diffusion equation are computed by a finite difference method in the numerical model. A laboratory experiment is also carried out to compare the results of the numerical model. The dimensions of the experimental plume are 1.2m in length, 0.5m in height, and 0.05m in thickness. In comparing the result of 2 methods used in the numerical model with the one of the experiment respectively, the one of the advective-dispersion equation shows better than the one the diffusion equation.

• Proceedings of the Korean Society of Toxicology Conference
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• 2005.05a
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• pp.122-122
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• 2005