• The Journal of the Petrological Society of Korea
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• v.27 no.3
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• pp.121-138
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• 2018

We have examined the petrotectonic setting and magmatic evolution from petrochemical characteristics of major and trace elements for the Cretaceous volcanic rocks in and around the Mireukdo Island. The volcanic rocks, can be devided into Jusasan, Unmunsa, Yokji and Saryang subgroups on the ascending order, are classified as basalt, basaltic andesite, andesite, dacite and rhyolite on TAS diagram. Petrochemical data show that the rocks are calc-alkaline series, and suggest that erupted earlier medium-K series and later high-K series. The volcanic rocks provide a case in which the calc-alkaline magma are formed, not only from separate protoliths, but following separate paths from source to surface. Earlier and later subgroups take different paths to the surface respectively, and are emplaced in the shallow crust as a series of discrete magma chambers through the volcanic processes. After emplacement, each chamber evolves indepently through fractional crystallization with a little assimilation of wall rock. The volcanic rocks have close petrotectonic affinities with orogenic suite and subduction-related volcanic arc. The rhyolitic magma can be derived from calc-alkaline andesitic magma by fractional crystallization with crustal assimilation, which may be derived from a partial melt of peridotite in the upper mantle.

• Environmental Mutagens and Carcinogens
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• v.23 no.3
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• pp.85-93
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• 2003

Welders working in a confined space, like in the shipbuilding industry, are at risk of being exposed to high concentrations of welding fumes and developing pneumoconiosis or other welding-fume exposure related diseases. Among such diseases, manganism resulting from welding-fume exposure remains a controversial issue, as the movement of manganese into specific brain regions has not been clearly established. Accordingly, to investigate the distribution of manganese in the brain after welding-fume exposure, male Sprague Dawley rats were exposed to welding fumes generated from manual metal arc stainless steel (MMA-SS) at concentrations of $63.6{\pm}4.1$ $mg/m^3$ (low dose, containing 1.6 $mg/m^3$ Mn) and $107.1{\pm}6.3$ $mg/m^3$ (high dose, containing 3.5 $mg/m^3$ Mn) total suspended particulates for 2 hrs per day, in an inhalation chamber over a 60-day period. Blood, brain, lungs and liver samples were collected after 2 hr, 15, 30, and 60 days of exposure and the tissues analyzed for their manganese concentrations using an atomic absorption spectrophotometer. Although dose- and time-dependent increases in the manganese concentrations were found in the lungs and livers of the rats exposed for 60 days, only slight manganese increases were observed in the blood during this period. Major statistically significant increases in the brain manganese concentrations were detected in the cerebellum after 15 days of exposure and up until 60 days. Slight increases in the manganese concentrations were also found in the substantia nigra, basal ganglia (caudate nucleus, putamen, and globus pallidus), temporal cortex, and frontal cortex, thereby indicating that the pharmacokinetics and distribution of manganese inhaled from welding fumes would appear to be different from those resulting from manganese-only exposure.

• Journal of the Korean GEO-environmental Society
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• v.14 no.12
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• pp.23-30
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• 2013

Bearing capacity of pile is governed by only skin friction in frozen ground condition, while it is generally governed both by skin friction and end bearing capacity in typically unfrozen ground condition. Skin friction force, which arises from the interaction between pile and frozen soils, is defined as adfreeze bond strength, and adfreeze bond strength is one of the most important key parameters for design of pile in frozen soils. Many studies have been carried out in order to analyze adfreeze bond strength characteristics over the last fifty years. However, many studies for adfreeze bond strength have been conducted with limited circumstances, since adfreeze bond strength is sensitively affected by various influence factors such as intrinsic material properties, pile surface roughness, and externally imposed testing conditions. In this study, direct shear test is carried out inside of large-scaled freezing chamber in order to analyze the adfreeze bond strength characteristics with varying freezing temperature and normal stress. Also, the relationship between adfreeze bond strength and shear strength of the frozen soil obtained from previous study was analyzed. The coefficient of adfreeze bond strength was evaluated in order to predict adfreeze bond strength based on shear strength, and coefficients suggested from this and previous studies were compared.

• Korean Journal of Soil Science and Fertilizer
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• v.47 no.1
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• pp.59-65
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• 2014

Generally, nitrogen (N) fertilization higher than the recommended dose is applied during vegetable cultivation for increasing in productivity. However, excessive N application rate beyond plant requirement could cause adverse environmental impact such as nitrate leaching and nitrous oxide emission. In this experiment, the impacts of N fertilization was studied on nitrous oxide ($N_2O$) emission to standardize the optimum fertilization level for minimizing of $N_2O$ emission as well as most of the crop productivity. Herein, we assessed the $N_2O$ emission in the flat upland soil which was cultivated with different N application rates on red pepper for 3 years (2010~2012). $N_2O$ emission was measured in chemical N fertilizer amounts 0 (N 0), 95 (N 0.5), 190 (N 1.0), $380(N_2.0)kgha^{-1}$ by using the abnormal shape chamber closed repeating three times. In average for 3 years, the total $N_2O$ emissions of each treatment in field of soybean were 2.110 (N 0), 3.165 (N 0.5), 5.039 (N 1.0), and $7.228(N_2.0)kgN_2Oha^{-1}yr^{-1}$, respectively. And then the primary regression between nitrogen fertilizer amount and the total $N_2O$ emission was showed as y = 0.0138x + 2.0942 ($r^2=0.9885$), and an average of the emission factor was $EF_1$ 0.0148(0.0118~0.0191) $N_2O-NkgN^{-1}kg^{-1}$ from 2010 to 2012. The result was a little higher than the emission default of the IPCC 1996 Guideline ($EF_1$ 0.0125) when the results are converted into $N_2O$ emission factor.

• Journal of Korean Tunnelling and Underground Space Association
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• v.18 no.3
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• pp.257-272
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• 2016

It is usually not an easy task to counter-measure on time and appropriately when confronting with troubles in mechanized tunnelling job-sites because of the limitation of available spaces to perform those actions with the existence of disk cutter, cutter head, chamber and other various apparatus in Tunnel Boring Machine (TBM). So, it is important to predict the ground condition ahead of a tunnel face during tunnel excavation. Efforts have been made to utilize geophysical methods such as elastic wave survey, electromagnetic wave survey, electrical resistivity survey, etc for predicting the ground condition ahead of the TBM tunnel face. Each prediction method among these geophysical methods has its own advantage and disadvantage. Therefore, it might be needed to apply several geophysical methods rather than just one to predict the ground condition ahead of the tunnel face in the complex and/or mixed grounds since those methods will compensate among others. The problem is that each prediction method will give us different answer on the predicted ground condition; how to combine different solutions into a most reasonable and representative predicted value might be important. Therefore, in this study, we proposed a methodology how to systematically combine each prediction method utilizing probabilistic analysis as well as analytic hierarchy process. The proposed methods is applied to a virtual job site to confirm the applicability of the model to predict the ground condition ahead of the tunnel face in the mechanized tunnelling.

• Analytical Science and Technology
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• v.14 no.5
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• pp.451-457
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• 2001

Because liquids with high molecular weight such as mineral oil have low vapor pressure at room temperature, it is generally thought to be difficult to lose them to evaporation. However, when they are dispersed into air in small droplets during application in machining processes, their surface area becomes considerably higher. To determine the potential for metalworking fluids (MWF) filter losses, MWF mist was generated and collected on polyvinyl chloride (PVC) filters in test chamber. After collected MWF was exposed to clean air during designated period (range 10~240 minutes) and the filters were desiccated, losses were evaluated. As duration of clean air passing through PVC filter increased, loss of MWF gradually increased. MWF lost after 10 minutes ranged form 12.4 % to 21.8 % of the original loading mass, on average 53.3 % of the total loss. These results indicate that significant mass of MWF collected on PVC filters can be lost at the beginning of air sampling. Loss of MWF collected on PVC filter also occurred during desiccation without active airflow. In multiple regression to identify which factors influence the loss of MWF collected on PVC filter, both duration of air passing through PVC filter and MWF age (fresh vs. used) were significant predictor (p=0.0001). Therefore, workers' exposure to MWF measured method 0500, may underestimate true concentration. Further study is needed to develop a new method to quantify the workers' exposure to airborne MWF mist accurately.

• Journal of Korean Society of Environmental Engineers
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• v.28 no.2
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• pp.191-196
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• 2006

The injection of ozone, produced by dielectric barrier discharge, into the exhaust gas gives rise to a rapid oxidation of NO that is the main component of nitrogen oxides($NO_x$) in most practical exhaust gases. Once NO is converted into $NO_2$, it on readily be reduced to $N_2$ in the next step by a reducing agent such as sodium sulfide and sodium sulfite. The reducing agents used ca also remove $SO_2$ effectively, which makes it possible to treat $NO_x\;and\;SO_2$ simultaneously. The present two-step process made up of an ozonizing chamber and an absorber containing a reducing agent solution was able to remove about 95% of the $NO_x$ and 100% of the $SO_2$, initially contained in the simulated exhaust gas. The formation of $H_2S$ from sodium sulfide was prevented by using a strong basic reagent(NaOH) together with the reducing agent. The removal of $NO_x$\;and\;SO_2$ was more effective for $Na_2S$ than $Na_2SO_3$.

• Microbiology and Biotechnology Letters
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• v.45 no.3
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• pp.257-264
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• 2017

Mixed substrate oil cakes are known to emit sulfides, ammonia, and amines. Microorganisms capable of removing odorous gases related to these sulfur compounds were isolated from colonies enriched in vials containing oil cakes and water. Activity tests for hydrogen sulfide and methyl mercaptan reduction were performed to measure the sulfide reduction ratio of the isolates. Control groups were prepared with 0.25 g oil cakes and 10 ml water in a 100-ml vial without inoculation. The experimental groups were prepared similarly, albeit with an inoculum. Hydrogen sulfide removal efficiency of >90% was observed for an isolate, which was identified as Brevundimonas diminuta by 16S rDNA sequence analysis. The sequence was deposited in the Korean Collection for Type Cultures under the accession number KCTC11724BP. B. diminuta could remove up to 200 ppmv standard hydrogen sulfide in 24 hours and demonstrated a maximum hydrogen sulfide and methyl mercaptan removal efficiency of 100% at 453 ppmv and 98 ppmv, respectively, in vial tests. Furthermore, B. diminuta cells in 20% (v/w) medium showed removal efficiency of >85% for sulfur compounds in an odor emission chamber for swine manure.

• The Journal of the Petrological Society of Korea
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• v.18 no.4
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• pp.337-348
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• 2009

Clear and homogeneous glass inclusions are well preserved at the rim of the quartz phenocrysts of tuff from Sunshin epithermal Au deposit, Haenam, although the host rocks experienced extensive silicification and argillic alteration. Glass inclusion vary in size from $5\;{\mu}m$ to larger than $200\;{\mu}m$ consisting of glass(60~80 vol%) + vapor bubble(15~30 vol%) $\pm$ daughter crystals(<10 vol%). Most of glass inclusions are cubic to rectangular in shape, indicating that the host quartz grew in the stability field of $\beta$-quartz. All the glass inclusions appear to be primary. Glass inclusions are composed of highly evolved high-K calc-alkaline rhyolites, which can represent the final liquidus phase of the magma system. The $Au_2O_3$ concentration (<0.30 wt%) is trivial in the glass, indicating there was no enrichment in the final residual melt. Textural characteristics suggest that magma was water-saturated shortly before or during the eruption. $H_2O$ content of the glass (ca. 2-4 wt%) suggests a water saturation pressure($P_{H2O}$) of about 300-900 bars. This pressure implies a minimum depth of 0.8-2.5 km for the magma chamber.

• The Journal of the Petrological Society of Korea
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• v.25 no.4
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• pp.349-360
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• 2016

The Bunam Stock ($29.5km^2$ area) is an outcrop of plutonic complex classified four facies: coarse-grained granite, quartz monzodiorite, granodiorite and fine-grained granite. Three facies except the last one exhibit very irregular boundaries with gradational compositional variations between both facies and show concentric zoning from the central quartz monzodiorite through granodiorite to outer coarse-grained granite. Mafic microgranular enclaves (MME) commonly occur in granodiorite. Some MMEs, have very fine-grained chilled margins and indentedly crenulate contacts, and display horizontally circular and vertically elongate shapes. Their shape and granularity indicate coeval flow and mingling of partly crystalline felsic and mafic magmas. MMEs exhibit dark fine-grained margins giving them a ellipsoidal form that has been attributed to undercooling of a mafic magma as blobs intruded into a felsic magma. The observed relations in the Bunam Stock identify that two endmembers are coarse-grained granite from a felsic magma and quartz monzodiorite from a mafic magma, and hybrid is granodiorite including MMEs. So they exhibit concentric zoning that lays the center on the mafic endmember due to magma mixing at the contacts of two magmas, when mafic magma injected into felsic magma. Thus the quartz monzodiorite may probably represent an ancient conduit of mafic magma transport through a granitic magma chamber. Mafic magma would rise through the conduit in which favorable conditions for magma mixing occurred. All these features suggest that they formed from mixing processes of calc-alkaline magma in the Bunam Stock.