• 제목/요약/키워드: enthalpy model

검색결과 182건 처리시간 0.027초

활성탄에 의한 난분해성 염료인 Eosin Y의 흡착 (Adsorption of Non-degradable Eosin Y by Activated Carbon)

  • 이민규;감상규;서근학
    • 한국환경과학회지
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    • 제21권5호
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    • pp.623-631
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    • 2012
  • The adsorption behavior of Eosin Y on activated carbon (AC) in batch system was investigated. The adsorption isotherm could be well fitted by the Langmuir adsorption equation. The kinetics of adsorption followed the pseudo-second-order model. The temperature variation was used to evaluate the values of free energy (${\Delta}G^{\circ}$), enthalpy (${\Delta}H^{\circ}$) and entropy (${\Delta}S^{\circ}$). The positive value of enthalpy change ${\Delta}H^{\circ}$ for the process confirms the endothermic nature of the process and more favourable at higher temperature, the positive entropy of adsorption ${\Delta}S^{\circ}$ reflects the affinity of the AC material toward Eosin Y and the negative free energy values ${\Delta}G^{\circ}$ indicate that the adsorption process is spontaneous. With the increase of the amount of AC, removal efficiency of Eosin Y was increased, but adsorption capacity was decreased. And adsorption capacity was increased with the decrease of particle size. With the increase of the amount of AC, removal efficiency of Eosin Y was increased, but adsorption capacity was decreased. And adsorption capacity was increased with the decrease of particle size.

상온 및 상압하에서 3성분계 {1,2-dichloropropane + 1,3-dioxolne + 1,4-dioxane}의 과잉 몰엔탈피 예측 (Excess Molar Enthalpies for the Ternary System {1,2-dichloropropane + 1,3-dioxolne + 1,4-dioxane} at T=298.15 K and p=101.3 kPa)

  • 이영세;김문갑
    • 한국산업융합학회 논문집
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    • 제14권1호
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    • pp.9-14
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    • 2011
  • The excess molar enthalpies $H_m^E$ at T=298.15 K and p=101.3 kPa of ternary system {1,2-dichloropropane (1,2-DCP) + 1,3-dioxolane+ 1,4-dioxane} were predicted by using the binary contribution model of $Radojkovi{\check{c}}$ with correlated sub-binary Redlich-Kister parameters. Excess partial molar enthalpies ${\bar{H}}_i^E$ were also calculated for the binary systems {1,2-dichloropropane + 1,3-dioxolane}, {1,2-dichloropropane + 1,4-dioxane} and {1,3-dioxolane + 1,4-dioxane} using adjustable parameters of Redlich-Kister equation. By extrapolation of excess partial molar enthalpies to infinite dilution, limiting excess partial molar enthalpies ${\bar{H}}_i^{E,{\infty}}$ of each component were also obtained. The ternary excess molar enthalpies excess partial molar enthalpies of these sub-binary systems have been calculated by using our previously reported results.

Numerical Study on Laser-driven In-Tube Accelerator (LITA) Performance using a Plasma Size Modeling

  • Kim, Sukyum;Toshiro Ohtani;Akihiro Sasoh;Jeung, In-Seuck;Park, Jeong--Yeol
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2004년도 제22회 춘계학술대회논문집
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    • pp.320-324
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    • 2004
  • Laser Propulsion is a device that generates thrust using laser energy. Laser-driven In-Tube Accelerator (LITA) has been developed at Tohoku University. LITA is a laser propulsion system that accelerates an object not in an open air but in a tube. Experiments of vertical launching and pressure measurement on the tube wall were carried out and in order to observe the initial state of plasma and blast wave, the visualization experiment was carried out using the shadowgraph method. In this study, the time variation of pressure on the tube wall is numerically simulated solving Euler equation. In order to model the laser energy, heat source function added to the frozen flow Euler equation. Plasma size from the shadowgraph images was used for the initial condition of laser energy input. For verification of the modeling, these results were compared with the previous experimental and numerical results. From these verifications, an analysis of LITA performance will be investigated.

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연료전지 자동차의 물탱크 해빙과정에 대한 수치해석적 연구 (Numerical analysis of melting process in a water tank for fuel-cell vehicles)

  • 김학구;정시영;허남건;임태원;박용선
    • 대한설비공학회:학술대회논문집
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    • 대한설비공학회 2006년도 하계학술발표대회 논문집
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    • pp.74-79
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    • 2006
  • Good cold start characteristics are essential for satisfactory operation of fuel cell vehicles. In this study, the melting process has been numerically investigated for a water tank frozen in cold weather The 2-D model of the tank containing ice and plate heaters was assumed and the unsteady melting process of the ice was calculated. The enthalpy method was used for the description of the melting process, and a FVM code was used to solve the problem. The feasibility study compared with other experiment showed that the developed program was able to describe the melting process well. From the numerical analysis carried out for different wall temperatures of the pate heaters, some important design factors could be found such as local overheating and pressurization in the tank.

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Nucleation kinetics and technology design for crystal growth from aqueous solution

  • Kidyarov, B.I.
    • 한국결정성장학회지
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    • 제13권2호
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    • pp.51-55
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    • 2003
  • The interrelation into nucleation and thermodynamic parameters of solutions has been established by plotting of various dependencies: the enthalpy of dissolution, solubility product and super-solubility on ionic salt radii and also the extent of deviation from an ideal Debye -Huckel model of electrolyte solution on solubility product. The possible methods of perfect crystal growth from aqueous solution have been found a priori by separating of known set of pair values of solubility and super-solubility into no less than six-nine characteristic and distinctive sub-sets.

Simplified Technique for 3-Dimensional Core T/H Model in CANDU6 Transient Simulation

  • Lim, J.C.
    • 한국에너지공학회:학술대회논문집
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    • 한국에너지공학회 1995년도 춘계학술발표회 초록집
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    • pp.113-116
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    • 1995
  • Simplified approach has been adopted for the prediction of the thermal behavior of CANDU reactor core during power transients. Based on the assumption that the ratio of mass flow rate for each core channel does not vary during the transient, quasy-steady state analysis technique is applied with predicted core inlet boundary conditions(total mass flow rate and specific enthalpy). For restricted transient case, the presented method shows functionally reasonable estimation of core thermal behavior which could be implemented in the fast running reactor simulation program.

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회전익 채널내 후류장에 의한 비정상 유동특성에 관한 연구 (Unsteady Flow Fields in a Rotor Blade Passage by Wake Passing)

  • 김윤제;전용렬
    • 한국유체기계학회 논문집
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    • 제2권4호
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    • pp.16-23
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    • 1999
  • The characteristic of unsteady flowfields on gas turbine, particularly on a rotor blade surface has been numerically investigated. The unsteady flow in a rotor blade passage as a result of wake/blade interaction is modeled by the inviscid flow approach, and solved by Euler equations using a time accurate marching scheme. Unsteady flow in the blade passage is induced by periodically moving a wake model across the passage inlet. The wake model used in this study is the Gaussian wate model in which the wake flow is assumed to be parallel with uniform static pressure and uniform relative total enthalpy. Numerical results show that for the case of Ps/Pr=1.5, the velocity and pressure distribution on the blade surfaces have much more complex profiles than for the case of Ps/Pr=1.0.

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Reduction of the Wet Surface Heat Transfer Coefficients from Experimental Data

  • Kim, Nae-Hyun;Sim, Yong-Sub
    • International Journal of Air-Conditioning and Refrigeration
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    • 제12권1호
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    • pp.37-49
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    • 2004
  • Four different data reduction methods for the heat transfer coefficients from experimental data under dehumidifying conditions are compared. The four methods consist of two heat and mass transfer models and two fin efficiency models. Data are obtained from two heat exchanger samples having plain fins or wave fins. Comparison of the reduced heat transfer coefficients revealed that the single potential heat and mass transfer model yielded the humidity-independent heat transfer coefficients. Two fin efficiency models-enthalpy model and humidity model-yielded approximately the same fin efficiencies, and accordingly approximately the same heat transfer coefficients. The heat transfer coefficients under wet conditions were approximately the same as those of the dry conditions for the plain fin configuration. For the wave fin configuration, however, wet surface heat transfer coefficients were approximately 12% higher. The pressure drops of the wet surface were 10% to 45% larger than those of the dry surface.

코르크 삭마를 고려한 비행체 1D 온도해석 도구 개발 (A Development of One-dimensional Thermal Analysis Tool for Flight Vehicle with Cork Insulation)

  • 정태빈
    • 한국군사과학기술학회지
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    • 제21권4호
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    • pp.464-470
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    • 2018
  • A development of one-dimensional thermal analysis tool is performed to estimate the thickness of cork insulation for flight vehicle. In the calculation of cork temperature, the cork density model, heat of ablation and pyrolysis gas enthalpy model were applied. The calculation for the two-layer model of cork and metal was performed by the tool and compared with the experimental data. The results for the two aerodynamic heating conditions were 17 % and -12 % different from the experimental data, respectively. The effect of mechanical ablation not included in the calculation can be expected as the cause of the difference. The temperature-density curve of cork which adjusted by experimental data was also presented.

비예혼합 수소-공기 난류제트화염내의 NOx 생성특성 예측 (Prediction of NOx Formation Characteristics in Turbulent Nonpremixed Hydrogen-Air Jet Flames)

  • 김성구;김용모;안국영;오군섭
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 1998년도 제17회 KOSCI SYMPOSIUM 논문집
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    • pp.165-170
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    • 1998
  • Turbulent nonpremixed $H_2$-air jet flames are numerically investigated using the joint PDF model. The reaction progress variable is derived by assuming the radicals 0, H, and OH to be in partial equilibrium and additional species $HO_2$ and $H_2O_2$ in steady state. The model is extended to npnadiabatic flame by introducing additional variable for the transport of enthalpy and radiative source term is calculated using a local, geometry independent model. In terms of flame structure and NO formation, the predicted results are favorably agreed with experimental data. The effects of nonequilibrium chemistry and radiative heat loss on the thermal NO formation are discussed in detail.

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