• The Korean Journal of Ceramics
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• v.2 no.3
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• pp.131-136
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• 1996

The electrical conductivity of polycrystalline TiO2 samples was measured over the temperature range 1000°-1400℃ and from 0.21 to 10-16 atm of oxygen. Based on the excellent fit observed between the theoretically derived relatin σ3=(Aσ+B)Po2-1/2+D'σ2 and the experimental conductivity data, the nonstoichimetric defect structure of TiO2 was rationalized in terms of a defect model involving quasi-free electrons and both singly and doubly ionized oxygen vacancies. The standard enthalpy of formation for the following defect reactions in TiO2. (a) OO={{{{ { 1} over {2 } }}O2(g)+VO+e'; Δ{{{{ { H}`_{o } ^{a } }}=5.15(eV) (b) OO={{{{ { 1} over {2 } }}O2(g)+VO+2e'; Δ{{{{ { H}`_{0 } ^{ a} }}=6.30(eV) (c) VO=VO+e'; Δ{{{{ { H}`_{0 } ^{a } }}=1.15(eV) were determined from the temperature dependence of A and B obtained from the above relation and from the experimental expression between the electron mobility and temperature. The electrical conductivity of TiO2 in air below approximately 950℃ appears, on the basis of this investigation, to be impurity controlled due to the presence of aluminum rather than intrinsic conduction.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.12 no.4
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• pp.261-271
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• 2002

The fluid-elastic instability analysis of the U-tube bundle inside the steam generator is very important not only for detailed design stage of the SG but also for the change of operating condition of the nuclear powerplant. However the calculation procedure for the fluid-elastic instability was so complicated that the consolidated computer program has not been developed until now. In this study, the numerical calculation procedure and the computer program to obtain the stability ratio were developed. The thermal-hydraulic data in the region of secondary side of steam generator was obtained from executing the ATHOS3 code. The distribution of the fluid density can be calculated by using the void fraction, enthalpy, and operating pressure. The effective mass distribution along the U-tube was required to calculate natural frequency and dynamic mode shape using the ANSYS ver. 5.6 code. Finally, stability ratios for selected tubes of the CE type steam generator were computed. We considered the YGN 3.4 nuclear powerplant as the model plant, and stability ratios were investigated at the flow exit region of the U-tube. From our results, stability ratios at the central and the outside region of the tube bundle are much higher than those of other region.

• Environmental Engineering Research
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• v.17 no.3
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• pp.125-132
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• 2012

The removal of Cd(II) and Cu(II) from aqueous solution by an agricultural solid waste biomass prepared from Moringa oleifera bark (MOB) was investigated. The biosorbent was characterized by Fourier transform infrared spectroscopy and elemental analysis. Furthermore, the effect of initial pH, contact time, biosorbent dosage, initial metal ion concentration and temperature on the biosorption of Cd(II) and Cu(II) were studied using the batch sorption technique. Kinetic studies indicated that the biosorption process of the metal ions followed the pseudo-second order model. The biosorption data was analyzed by the Langmuir, Freundlich, Dubinin-Radushkevich, and Temkin isotherm models. Based on the Langmuir isotherm, the maximum biosorption capacities for Cd(II) and Cu(II) onto MOB were 39.41 and 36.59 mg/g at 323 K, respectively. The thermodynamic parameters, Gibbs free energy (${\Delta}G^o$), enthalpy (${\Delta}H^o$), and entropy (${\Delta}S^o$) changes, were also calculated, and the values indicated that the biosorption process was endothermic, spontaneous and feasible in the temperature range of 303-323 K. It was concluded that MOB powder can be used as an effective, low cost, and environmentally friendly biosorbent for the removal of Cd(II) and Cu(II) ions from aqueous solution.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.25 no.12
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• pp.74-81
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• 2011

A computational approach was developed to understand about the arc quenching process in a gas circuit breaker(GCB). This approach is a program to analyze the gas flow in the breaker. The arc is processed at the same time. The program was used the so-called FLIC method for gas analysis techniques. It was referenced that the arc is interpreted the 'a Simplified Enthalpy Flow Arc Model'. In order to validate about the results of the program, a Auto Puffer GCB was chosen as the test subject. Because, the breaker is the one that arc current is interrupted by using the arc heating. And also, the current interrupting capability can be obtained only owing to the positive utilization(auto puffer) of the clogging phenomenon, without other puffer actions. In this paper, it has been realized that the entire arc quenching process is computerized, which is based on the self-flow current interruption by the auto puffer action. This program, which was verified through experiments, produced good results.

• Journal of the Korean Society for Aviation and Aeronautics
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• v.23 no.3
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• pp.8-17
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• 2015

In this research, low fidelity air/heat load analysis was conducted for the intake of high speed vehicle. For air/heat load calculations, aerodynamic properties at the surface and the boundary layer edge were estimated using Taylor-Maccoll equation for conical flow, shockwave relation and Prandtl-Meyer expansion equation for internal and external flow. Couette flow assumption and Reynolds analogy were used in order to calculate convective heat transfer coefficient. In order to calculate skin friction coefficient for heat transfer coefficient analysis, Van Driest method II and Reference Enthalpy method were considered. An axis symmetric SCRAMJET model was selected as a reference configuration for verifying the proper implementation of the present method. Comparison of the results using the present method and Computational Fluid Dynamic analysis showed that the present method is valuable for efficiently providing pressure and heat loads for air-intake structure design of the high speed air vehicle.

• 한국태양에너지학회:학술대회논문집
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• 2008.04a
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• pp.111-116
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• 2008

The objective of this paper was to show the possibility of demand-controlled ventilation (DCV) using the current Korean ventilation standard for multi-purposed facilites. Two attractive DCV approaches; $CO_2$-DCV and RFID-DCV were applied to DCV simulations for a theoretical public assembly space served by a dedicated outdoor air system (DOAS) with enthalpy recovery device. A numerical model for predicting realtime occupant number, ventilation rate, and $CO_2$ concentration under given conditions was developed using a commercial equation solver program. It was found that the current ventilation standard causes unstable ventilation system control in DCV applications, especially under $CO_2$-DCV. It is because the ventilation rate (per person) used in Korea is the sum of the outdoor air required to remove or dilute air contaminants generated by both occupant and building itself, and not a pure function of occupant numbers. Finally, it makes DCV control unstable when ventilation flow is regulated only by the number of occupants. In order for solving this problem, current Korean ventilation standard was modified as a form of ASHRAE Standard 62.1-2007 showing good applicability to various DCV approaches. It was found that this modification enhances applicability of the current ventilation standard to DCV significantly.

• 한국전산유체공학회:학술대회논문집
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• 2010.05a
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• pp.283-288
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• 2010

The characteristics of a condenser dryer and a vented dryer that are common types of domestic clothes dryers for home use are predicted and compared in an effort to improve the efficiency and to overcome economical and environmental problems due to its inefficient power consumption. In the present study, a drying system is simplified by assuming the mechanism is composed of several elements such as heater and drum and mathematical models using the mass and energy conservation of moisture and air through each element are defined. Based on this mathematical model, the computational tool is developed to predict temperature, humidity and enthalpy of moisture and air in a drum and remained moisture contents (RMC) in drying materials. The computational results are verified by comparing with experimental results from existing studies. In addition, the efficiency of a dryer is calculated using these predicted results for a given condition and the drying characteristics of a condenser dryer and a vented dryer are compared and analyzed.

• Proceedings of the KSME Conference
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• 2003.04a
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• pp.1572-1577
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• 2003

High-power pulsed laser ablation under atmospheric pressure is studied utilizing numerical and experimental methods with emphasis on recondensation ratio, and the dynamics of the laser induced vapor flow. In the numerical calculation, the temperature pressure, density and vaporization flux on a solid substrate are first obtained by a heat-transfer computation code based on the enthalpy method, and then the plume dynamics is calculated by using a commercial CFD package. To confirm the computation results, the probe beam deflection technique was utilized for measuring the propagation of a laser induced shock wave. Discontinuities of properties and velocity over the Knudsen layer were investigated. Related with the analysis of the jump condition, the effect of the recondesation ratio on the plume dynamics was examined by comparing the pressure, density, and mass fraction of ablated aluminum vapor. To consider the effect of mass transfer between the ablation plume and air, unlike the most previous investigations, the equation of species conservation is simultaneously solved with the Euler equations. Therefore the numerical model computes not only the propagation of the shock front but also the distribution of the aluminum vapor. To our knowledge, this is the first work that employed a commercial CFD code in the calculation of pulsed ablation phenomena.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.23 no.10
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• pp.1254-1264
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• 1999

A three-dimensional coupled turbulent fluid flow and solidification process were analyzed in a continuous casting process of a steel slab with Electromagnetic Brake(EMBR). A revised low-Reynolds number $k-{\varepsilon}$ turbulence model was used to consider the turbulent effects. The enthalpy-porosity relation was employed to suppress the velocity within a mushy region. The electromagnetic field was described by Maxwell equations. Tile application of EMBR to the mold region results in the decrease of the transfer of superheat to the narrow face, the increase of temperature in free surface region and most liquid of submold region, and the higher temperature gradient near the solidifying shell. The increasing magnetic flux density effects mainly to the surface temperature of the solidifying shell of narrow face, hardly to the one of wide face. It is seen that in the presence of EMBR a thicker solidifying shell is obtained at the narrow face of the slab.

• Journal of the Korean Chemical Society
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• v.56 no.4
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• pp.416-423
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• 2012

Using time domain reflectometry, the complex dielectric spectra between 10 MHz to 20 GHz has been measured in the whole composition range at 10, 20, 30 and $40^{\circ}C$ for the binary mixtures of ethylene glycol and dimethyl sulfoxide. For all the mixtures, only one dielectric loss peak was observed in this frequency range. The relaxation in these mixtures can be described by a single relaxation time using the Debye model. A systematic variation is observed in dielectric constant (${\varepsilon}_0$) and relaxation time (${\tau}$). The excess permittivity (${\varepsilon}^E$), excess inverse relaxation time $(1/{\tau})^E$, Kirkwood correlation factor (g) and thermodynamic parameters viz. enthalpy of activation (${\Delta}H$) and Gibbs free energy of activation (${\Delta}G$) have been determined, to confirm the formation of hydrogen bonded homogeneous and heterogeneous cooperative domains, the dynamics of solute - solute interaction and the hindrance to molecular rotation in the hydrogen bonded glass forming ethylene glycol - dimethyl sulphoxide system.