• Title/Summary/Keyword: enthalpy method

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A Product Inhibition Study on Adenosine Deaminase by Spectroscopy and Calorimetry

  • Saboury, Ali Akbar;Divsalar, Adeleh;Jafari, Ghasem Ataie;Moosavi-Movahedi, Ali Akbar;Housaindokht, Mohammad Reza;Hakimelahi, Hosain
    • BMB Reports
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    • v.35 no.3
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    • pp.302-305
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    • 2002
  • Kinetic and thermodynamic studies have been made on the effect of the inosine product on the activity of adenosine deaminase in a 50 mM sodium phosphate buffer, pH 7.5, at $27^{\circ}C$ using UV spectrophotometry and isothermal titration calorimetry (ITC). A competitive inhibition was observed for inosine as a product of the enzymatic reaction. A graphical-fitting method was used for determination of the binding constant and enthalpy of inhibitor binding by using isothermal titration microcalorimetry data. The dissociation-binding constant is equal to $140\;{\mu}M$ by the microcalorimetry method, which agrees well with the value of $143\;{\mu}M$ for the inhibition constant that was obtained from the spectroscopy method.

Analysis of the $CO_2$ emission amount and characteristics of combined heat and power plants in industrial complex by using the fuel analysis method (연료분석 방법을 적용한 산업단지 열병합발전소 이산화탄소 배출량 및 배출특성분석)

  • Kang, Seok-Hun;Chung, Dae-Hun
    • Proceedings of the SAREK Conference
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    • 2008.06a
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    • pp.1243-1248
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    • 2008
  • $CO_2$ emission amount and characteristics of combined heat and power (CHP) plant in industrial complex of Korea is evaluated by using the fuel analysis method. Fuel analysis methods of several foreign countries and developed one which is developed considering the operation characteristics of the surveyed CHP plants are used. The operation data is surveyed for all of the CHP plants in industrial complex and is composed of fuel consumption amount, generation, sale and efficiency of heat and electricity, condensed steam enthalpy, and etc of the each CHP.

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Thermodynamic Modeling of Finned Tube Evaporator for Dehumidification and Air Conditioning (제조공조용 핀-관형 증발기의 열성능 모델링)

  • 박병규;이태환
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.12 no.11
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    • pp.1020-1030
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    • 2000
  • A crossflow finned tube evaporator has been investigated using tube-by-tube method. The refrigerant flows inside tubes while the air passes outside the finned tue. R134a for a refrigerant and wet air were used in this analysis. Three refrigerant circuitries, complex or simple, were compared. The effects of refrigerant circuitry and airside condensation on thermal performance such as heat transfer rate, enthalpy of refrigerant, temperature of refrigerant and air, pressure of refrigerant and average condensate layer thickness were investigated. It was found that this method could be applied to the analysis of finned tube evaporator for dehumidification and air conditioning.

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용탕유동과 응고를 고려한 주조공정의 유한요소해석

  • 윤석일;김용환
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1995.04a
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    • pp.620-625
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    • 1995
  • Finite element analysis tool was developed to analyze the casting process. Generally, casting processes consists of mold filling and solifification. In order to investigate the effects of process variables and to predict the defects, both filling and solidiffication process were simulated simultaneously. At filling process, especiallywe consider thermal coupling to investigate thermal history of material during the filling stage. And thermal condition at the final stage of filling is used as the initial conditions in a solidification process for the exact simulation of the actual casting processes. At mold filling process, Lagrangian-type finite element method with automatic remashing scheme was used to find the material flow. To avoid numerical instability in low viscous fluid, a perturbation method with artificial viscosity is adopted. At solififfication process, enthalpy-based finite element method was used to solve the heat transfer problem with phase change. And elastic stress analysis has been performed to predict the thermal residual stress. Through the FE analysis, solidiffication time, position of solidus line, liquidus line and thermal residual stress are studied. Finite element tools developed in this study will be used process design of casting process and maybe basic structure for total CAE system of castigs which will be constructed afterward.

Safety assessment of biological nanofood products via intelligent computer simulation

  • Zhao, Yunfeng;Zhang, Le
    • Advances in nano research
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    • v.13 no.2
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    • pp.121-134
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    • 2022
  • Emerge of nanotechnology impacts all aspects of humans' life. One of important aspects of the nanotechnology and nanoparticles (NPs) is in the food production industry. The safety of such foods is not well recognized and producing safe foods using nanoparticles involves delicate experiments. In this study, we aim to incorporate intelligent computer simulation in predicting safety degree of nanofoods. In this regard, the safety concerns on the nano-foods are addressed considering cytotoxicity levels in metal oxides nanoparticles using adaptive neuro-fuzzy inference system (ANFIS) and response surface method (RSM). Three descriptors including chemical bond length, lattice energy and enthalpy of formation gaseous cation of 15 selected NPs are examined to find their influence on the cytotoxicity of NPs. The most effective descriptor is selected using RSM method and dependency of the toxicity of these NPs on the descriptors are presented in 2D and 3D graphs obtained using ANFIS technique. A comprehensive parameters study is conducted to observe effects of different descriptors on cytotoxicity of NPs. The results indicated that combinations of descriptors have the most effects on the cytotoxicity.

Experimental Study on Performance Evaluation of System A/C using PWM or Inverter Method (Heating Characteristics at Low Temperature Conditions) (PWM 방식과 인버터 방식을 사용한 시스템 에어컨의 성능평가에 대한 실험적 연구(난방저온 특성))

  • 김대훈;전용호;권영철;이윤수;문제명;홍주태
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.15 no.7
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    • pp.551-556
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    • 2003
  • The present study concerns an experiment on the heating characteristics of a system air-conditioner (A/C) using PWM method or inverter method at low temperature con-ditions. The compressors used are digital scroll type and BLDC inverter type. Under the low outside temperature condition, -5$^{\circ}C$, -1$0^{\circ}C$, -15$^{\circ}C$, heating capacities and COPs are mea-sured by the psychometric calorimeter using air enthalpy method. Also, outlet air temperatures at heating operation mode are measured at -5$^{\circ}C$, -1$0^{\circ}C$ and -15$^{\circ}C$. Experimental results show that COPs of the system A/C using a PWM method are more effective than those of the inverter method at heating operation mode. Although the heater is on, COPs of PWM method are similar to those of BLDC inverter method. Moreover, the heating capacities of PWM method at -5$^{\circ}C$, -1$0^{\circ}C$ and -15$^{\circ}C$ are larger about 10~20% and outlet air tempe-rature at -15$^{\circ}C$ is larger about 10%, compared to the inverter method.

A Study on the impact and solidification of the liquid metal droplet in the thermal spray deposition (용사 공정에서 용융 금속 액적의 충돌현상과 응고 과정 해석)

  • Ha, Eung-Ji;Kim, Woo-Seung
    • Proceedings of the KSME Conference
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    • 2001.06d
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    • pp.214-219
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    • 2001
  • In this study, numerical investigation has been performed on the spreading and solidification of a droplet impacting onto a solid substrate in the thermal spray process. The finite difference method with volume-of-fluid approach is used to analyze the free surface flow and the source-based enthalpy method is employed to model the latent heat release during the solidification. In this work, the numerical model is validated through the comparison of the present numerical result with experimental data available for the flat substrate.

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A Study of Aero-thermodynamic Ablation Characteristics for Rocket Nozzle (로켓노즐내부의 공기 열역학적 삭마특성에 관한 연구)

  • Seo, J.I.;Jeong, J.H.;Kim, Y.I.;Kim, J.H.;Song, D.J.;Bai, C.H.
    • Proceedings of the KSME Conference
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    • 2001.06e
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    • pp.282-287
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    • 2001
  • The CSCM Upwind method and Material Transport Analysis (MTA) have been used to predict the thermal response and ablation rate for non-charring material to be used as thermal protection material (TPM) in KSR-III test rocket nozzle. The thermal boundary conditions such as cold wall heat-transfer rate and recovery enthalpy for MTA code are obtained from the upwind Navier-Stokes solution procedure. The heat transfer rate and temperature variations at rocket nozzle wall were studied with shape change of the nozzle surface as time goes by. The surface recession was severely occurred at nozzle throat and this affected nozzle performance such as thrust coefficient substantially.

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Computations of Supersonic Flow with Ristorcelli′s Compressible Turbulence Model (Ristorcelli의 압축성 난류 모형을 이용한 초음속 유동의 계산)

  • Park C. H;Park S. O
    • Journal of computational fluids engineering
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    • v.8 no.3
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    • pp.1-6
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    • 2003
  • Three-dimensional endwall flow within a linear cascade passage of high performance turbine blade is simulated with a 3-D Wavier-Stokes CFD code (MOSA3D), which is based on body-fitted coordinate system, pressure-correction and finite volume method. the endwall flow characteristics, including the development and generation of horseshoe vortex, passage vortex, etc. are clearly simulated, consistent with the generally known tendency The effects of both turbulence model and convective differencing scheme on the Prediction performance of endwall flow are systematically analyzed in the present paper. The convective scheme is found to have stronger effect than the turbulence modei on the prediction performance of endwall flow. The present simulation result also indicates that the suction leg of the horseshoe vortex continues on the suction side until it reaches the trailing edge.

A Study on the Performance Analysis of Automotive Air Conditioning System (자동차용 에어컨 시스템의 성능해석에 관한 연구)

  • 이대웅;유성연
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.14 no.4
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    • pp.304-314
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    • 2002
  • Performance analysis of the automotive air-conditioning system is conducted by using computer simulation, and performance tests are carried out by using the climate wind tunnel in order to verify simulation. Evaporator and condenser were modeled by using empirical correlation which was obtained from calorimeter data, and compressor was modeled by using map based method. The steady state thermodynamic conditions of refrigerant satisfying mass and energy balance were assumed in the simulation program for automotive airconditioning system. The system performance was analyzed by finite difference method until differential air enthalpy between evaporator inlet and outlet becomes converged. Simulation results are in good agreement with experimental results at most operating conditions. Variation of discharge temperature and pressure of compressor, outlet temperature of evaporator, cooling capacity, and COP were investigated in term of air volume flow rate for evaporator, compressor capacity, compressor speed, superheat of thermostatic expansion valve, and diameter of suction line.