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Case Study of Hydrochemical Contamination by Antimony Waste Disposal in Korea (국내 안티몬폐기물에 의한 수질화학적 오염 사례연구)

  • Jeong, Chan-Ho
    • The Journal of Engineering Geology
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    • v.18 no.4
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    • pp.471-482
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    • 2008
  • This study was carried out to investigate the contamination characteristics of surface water, soil water and groundwater around and in antimony waste landfill site in Wonsung-ri, Yeonki-kun, Chungnam. The waste disposed in the study was excavated and transported to the other site in several years ago. For this study, we collected 35 water samples including groundwater, soil water and surface in the study site and also collected 2 groundwater samples from a comparison site. The data of chemical analysis of soil water samples show the antimony concentration of $48.75{\sim}74.81\;ppb$, which is much higher than groundwater in a comparison site and is highly excess than regulation level for a drinking water of some advanced countries. A relatively high antimony concentration was detected in three stream water samples nearby landfill site and two groundwater samples. Fe and Mn contents in soil water and stream water were measured as maxium 6.5 mg/L and 7.3 mg/L, respectively. Although other heavy metals of water samples in the study site are higher concentration than water sample of comparison site, their absolute levels are lower than regulation level for a drinking water. The chemical data of water samples are plotted widely from Ca - $HCO_3$ type to Ca - ($Cl +SO_4+NO_3$) type. Some groundwater show high contents of potassium and nitrate, which would come from fertilizer and sewage. Conclusively, some heavy metals including antimony have been still remained under the soil surface of the landfill site in the past. These metals have leaked out into nearby stream and groundwater system, and threaten the ecology, crops and the health of residents in this site. Therefore, the government have to prepare the strategy to prevent the diffusion of heavy metals into aquatic environment and have to process the reclamation work for contaminated site. It is also necessary to make a regulation level of the antimony concentration for a drinking water and soil environment in Korea.

Development of Non-Contact Penetration Measuring Device for Pile Driving Workers (항타 시공 작업자를 위한 비접촉식 관입량 측정기 개발)

  • Kim, J.K.;Kong, Y.K.;Choi, K.H.;Cho, M.U.;Kim, S.Y.;Kim, M.J.;Lee, J.H.;Park, Chae Won
    • Journal of the Korean Society of Safety
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    • v.35 no.3
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    • pp.58-63
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    • 2020
  • At the construction site of the driving site, the pile rebound and penetration measurements are performed manually to determine the end point of the driving operation, thereby causing the measurer to be exposed to a death accident. In this study, in order to eliminate the risk of this work, a non-contact penetration measuring device was developed and usability evaluation was conducted. The penetration measuring device is manufactured based on the ultrasonic sensor, and can be combined with the pile to deliver the data in real time, and the delivered data can be output in real time on the portable PC and the final penetration can be calculated. Usability evaluation on the device was conducted by comparison with manual work. Usability evaluation was largely evaluated on measured values, subjective comfort, and body parts comfort. The result of the measured value tended to overestimate the value measured manually by the measuring device, which is similar to the previous research. In terms of subjective comfort and body part comfort, overall satisfaction was higher than the manual method when using the measuring device. Taken together, these results indicate that it is possible to use the rudder measuring device in place of manual work in the construction site, and it is judged that the worker's comfort is greatly increased by using the measuring machine. The results of this study suggest that the use of non-contact measuring device in the field can be used as basic data to support them.

Improvement in the Catalytic Activity of ${\beta}$-Agarase AgaA from Zobellia galactanivorans by Site-Directed Mutagenesis

  • Lee, Seung-Woo;Lee, Dong-Geun;Jang, Min-Kyung;Jeon, Myong-Je;Jang, Hye-Ji;Lee, Sang-Hyeon
    • Journal of Microbiology and Biotechnology
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    • v.21 no.11
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    • pp.1116-1122
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    • 2011
  • In this study, site-directed mutagenesis was performed on the ${\beta}$-agarase AgaA gene from Zobellia galactanivorans to improve its catalytic activity and thermostability. The activities of three mutant enzymes, S63K, C253I, and S63K-C253I, were 126% (1,757.78 U/mg), 2.4% (33.47 U/mg), and 0.57% (8.01 U/mg), respectively, relative to the wild-type ${\beta}$-agarase AgaA (1,392.61 U/mg) at $40^{\circ}C$. The stability of the mutant S63K enzyme was 125% of the wild-type up to $45^{\circ}C$, where agar is in a sol state. The mutant S63K enzyme produced 166%, 257%, and 220% more neoagarohexaose, and 230%, 427%, and 350% more neoagarotetraose than the wild-type in sol, gel, and nonmelted powder agar, respectively, at $45^{\circ}C$ over 24 h. The mutant S63K enzyme produced 50% more neoagarooligosaccharides from agar than the wild-type ${\beta}$-agarase AgaA from agarose under the same conditions. Thus, mutant S63K ${\beta}$-agarase AgaA may be useful for the production of functional neoagarooligosaccharides.

Developing a Safety Scaffold Monitoring System Using Wireless Sensor Network Technology

  • Tserng, H. Ping;Huang, Hung-Jui;Li, Xin-Yan;Huang, Han-Tang
    • International conference on construction engineering and project management
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    • 2015.10a
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    • pp.324-327
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    • 2015
  • Scaffold is the most commonly used equipment in various types of construction works. Since various types of construction works use the same scaffold equipment, it becomes more difficult to be controlled and managed, thus resulting hazard frequently. According to the information announced in July 2012 by Council of Labor Affairs Executive Yan, the site collapse or incomplete anti-falling protection has led the site to accident frequently, and this is the main reason that causes construction industry occupational disasters. The labor death occupational hazard ratio rises up to 13% in scaffold activity, and the Council of Labor Affairs Executive Yan has showed that the death ratio is higher when using the scaffold in construction site, the total number of death has reached to 139 from 2005 to 2010. In order to ensure the safety of scaffold user, this study tends to build a wireless sensor monitoring system to detect the reliability and safety of the scaffold. The wireless sensor technique applies in this study is different with the traditional monitoring technique which is limited with wired monitoring. Wireless sensor technique does not need wire, it just needs to consider the power supply for establishing the network and receiving stable information, and it can become a monitoring system. In addition, this study also integrates strain gauge technique in this scaffold monitoring system, to develop a real-time monitoring data transfer mechanism and replace the traditional wired single project monitoring equipment. This study hopes to build a scaffold collapse monitoring system to effectively monitor the safety of the scaffold as well as provide the timesaving installation, low-cost and portable features.

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Estimation of site amplification and S-wave velocity profiles in metropolitan Manila, the Philippines, from earthquake ground motion records (지진 관측 기록을 이용한 필리핀 마닐라의 현장 증폭 특성 및 S파 속도구조 추정)

  • Yamanaka, Hiroaki;Ohtawara, Kaoru;Grutas, Rhommel;Tiglao, Robert B.;Lasala, Melchor;Narag, Ishmael C.;Bautista, Bartlome C.
    • Geophysics and Geophysical Exploration
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    • v.14 no.1
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    • pp.69-79
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    • 2011
  • In this study, empirical site amplifications and S-wave velocity profiles for shallow and deep soils are estimated using earthquake ground motion records in metropolitan Manila, the Philippines. We first apply a spectral inversion technique to the earthquake records to estimate effects of source, path, and local site amplification. The earthquake data used were obtained during 36 moderate earthquakes at 10 strong-motion stations of an earthquake observation network in Manila. The estimated Q value of the propagation path is modelled as $54.6f^{1.1}$. Most of the source spectra can be approximated with the omega-square model. The site amplifications show characteristic features according to surface geological conditions. The amplifications at the sites in the coastal lowland and Marikina Valley shows predominant peaks at frequencies from 1 to 5 Hz, while those in the central plateau are characterised by no dominant peaks. These site amplifications are inverted to subsurface S-wave velocity. We, next, discuss the relationship between the amplifications and average S-wave velocity in the top 30m of the S-wave velocity profiles. The amplifications at low frequencies are well correlated with the averaged S-wave velocity. However, high-frequency amplifications cannot be sufficiently explained by the averaged S-wave velocity in the top 30 m. They are correlated more with the average of S-wave velocity over depths less than 30 m.

Impact Assessment of Sewage Effluent on Freshwater Crucian Carp Carassius auratus using Biochemical and Histopathological Biomarkers (생화학적 및 조직병리학적 생체지표를 이용한 하수처리장 방류수의 담수 붕어(Carassius auratus) 영향 평가)

  • Samanta, Palas;Im, Hyungjoon;Lee, Hwanggoo;Hwang, Soon-Jin;Kim, Wonky;Ghosh, Apurba Ratan;Jung, Jinho
    • Journal of Korean Society on Water Environment
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    • v.32 no.5
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    • pp.419-432
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    • 2016
  • The aim of this study is to assess the influence of effluent discharge from a sewage treatment plant by evaluating oxidative stress and histopathological alterations in freshwater crucian carp Carassius auratus collected from the Eungcheon stream, located in Korea. Catalase activity in the gills, liver, and kidneys of C. auratus was collected from mixing zones; the downstream site was notably higher of fish than that of the upstream site. In addition, the activity of glutathione-S-transferase in the gills and liver was significantly higher in samples from the mixing zone than in those from the upstream site (p < 0.05). In addition, significantly elevated lipid peroxidation levels were observed in fish livers sampled from the mixing zone than in those from the upstream site (p < 0.05). Significant histopathological alternations were also observed in C. auratus, with the order of magnitude changes being liver > kidney > gills. These findings suggest that the liver is most affected by effluent discharge. The degree of tissue changes (DTC) indicate that the highest level occurred in samples from the mixing zone (30.98 ± 5.40) followed by those from the downstream site (19.28 ± 4.31) and was the lowest in samples from the upstream site (4.83 ± 2.67). These findings indicate that fish collected from the mixing zone are most affected by effluent discharge and both oxidative stress and histopathological indices are useful tools for monitoring contaminated rivers and streams.

Building Information Modeling of Caves (CaveBIM) in Jeju Island at a Specific Site below a Road at Jaeamcheon Lava Tube and at a Broader Scale for Hallim Town (제주도 한림 재암천굴과 도로 교차구간의 CaveBIM 구축)

  • An, Joon-Sang;Kim, Wooram;Baek, Yong;Kim, Jin-Hwan;Lee, Jong-Hyun
    • The Journal of Engineering Geology
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    • v.32 no.4
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    • pp.449-466
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    • 2022
  • The establishment of a complete geological model that includes information about all the various components at a site (such as underground structures and the compositions of rock and soil underground space) is difficult, and geological modeling is a developing field. This study uses commercial software for the relatively easy composition of geological models. Our digital modeling process integrates a model of Jeju Island's 3D geological information, models of cave shapes, and information on the state of a road at the site's upper surface. Among the numerous natural caves that exist in Jeju Island, we studied the Jaeamcheon lava tube near Hallim town, and the selected site lies below a road. We developed a digital model by applying the principles of building information modeling (BIM) to the cave (CaveBIM). The digital model was compiled through gathering and integrating specific data: relevant processes include modeling the cave's shape using a laser scanner, 3D geological modeling using geological information and geophysical exploration data, and modeling the surrounding area using drones. This study developed a global-scale model of the Hallim region and a local-scale model of the Jaeamcheon cave. Cross-validation was performed when constructing the LSM, and the results were compared and analyzed.

Mapping Submarine Bathymetry and Geological Structure Using the Lineament Analysis Method

  • Kwon, O-Il;Baek, Yong;Kim, Jinhwan
    • The Journal of Engineering Geology
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    • v.24 no.4
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    • pp.455-461
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    • 2014
  • The Honam-Jeju, Korea-Japan, and Korea-China subsea tunnel construction projects have drawn significant attention since the early 2000s. These subsea tunnels are much deeper than most existing natural shallow sea tunnels linking coastal areas. Thus, the need for developing new technologies for the site selection and construction of deep subsea tunnels has recently emerged, with the launch of a research project titled "Development of Key Subsea Tunnelling Technology" in 2013. A component of this research, an analysis of deep subsea geological structure, is currently underway. A ground investigation, such as a borehole or geophysical investigation, is generally carried out for tunnel design. However, when investigating a potential site for a deep subsea tunnel, borehole drilling requires equipment at the scale of offshore oil drilling. The huge cost of such an undertaking has raised the urgent need for methods to indirectly assess the local geological structure as much as possible to limit the need for repeated borehole investigations. This study introduces an indirect approach for assessing the geological structure of the seafloor through a submarine bathymetry analysis. The ultimate goal here is to develop an automated approach to the analysis of submarine geological structures, which may prove useful in the selection of future deep subsea tunnel sites.

1,8-Naphthyridine Modified Naphthalimide Derivative: Ratiometric and Selective Sensor for Hg2+ in Organic Aqueous Solution

  • Shi, Yong Gang;Duan, Yu Lian;Chen, Jian Hua;Wu, Xiang Hua;Zhou, Ying;Zhang, Jun Feng
    • Bulletin of the Korean Chemical Society
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    • v.34 no.1
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    • pp.63-67
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    • 2013
  • A bottom-modified (4-position) naphthalimide derivative 1 with 1,8-naphthyridine as binding site has been designed and synthesized. Compound 1 is the first 1,8-naphthyridine-modified naphthalimide-based sensor that can detect $Hg^{2+}$ selectively with respect to ratiometric fluorescent change and blue shift in organic aqueous solution. The Job's plot and FAB mass indicate that 1 formed a 1:1 complex with $Hg^{2+}$. A top-modified naphthalimide derivative 2 with 1,8-naphthyridin as binding site has also been synthesized for comparison.