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Formation Condition and Ferroelectric Properties of Niobate Tetragonal Tungsten Bronze (TTB) Type Ferroelectrics

  • Naoki Wakiya;Wang, Ju-Kai;Kazuo Shinozaki;Nobuyasu Mizutani
    • The Korean Journal of Ceramics
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    • v.6 no.4
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    • pp.380-384
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    • 2000
  • Crystal structure of $Ba_5-5X$Y$_10/3$Nb$_10$O$_30$ was tried to determine by Rietveld analysis using powder X-ray diffraction data. This compound has tetragonal tungsten bronze (TTB) structure with general formula, (Al)$_2$(A2)$_4$(B1)$_2$(B2)$_8$(O1)$_8$(O2)$_8$(O3)$_4$(O4)$_2$(O5)$_4$(O6)$_4$. However, it was difficult to determine the distribution of Ba and Y in Al and A2 sites by the analysis only. Combination of Rietveld analysis and site potentials calculation as well as lattice energy calculations helped to determine the distribution. As the result, it was clarified that $Ba^2+$ cations occupy A2 (pentagonal tunnel site) and $Y^3+$ cations occupy Al (cubic site). The distribution of cations at each site coincides with the distribution estimated by the difference of ionic radii. This supports the formation condition of TTB which was proposed in our previous report. $Ba_5-5X$Y$_10X/3$Nb$_10$O$_30$ shows ferroelectric characteristics. In this compound, remanent polarization decreases slightly with the composition X. On the other hand, the result of crystal structure determination reveals that atomic positions along c-axis for A1, A2, B1 and B2 cations are also decreased with the composition X. This would suggest that the dependence of remanent polarization on composition X is derived by the dependence of atomic coordinates on composition X.

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Spatially variable effects on seismic response of the cable-stayed bridges considering local soil site conditions

  • Tonyali, Zeliha;Ates, Sevket;Adanur, Suleyman
    • Structural Engineering and Mechanics
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    • v.70 no.2
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    • pp.143-152
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    • 2019
  • In this study, stochastic responses of a cable-stayed bridge subjected to the spatially varying earthquake ground motion are investigated for variable local soil cases and wave velocities. Quincy Bay-view cable-stayed bridge built on the Mississippi River in Illinois, USA selected as a numerical example. The bridge is composed of two H-shaped concrete towers, double plane fan type cables and a composite concrete-steel girder deck. The spatial variability of the ground motion is considered with the coherency function, which is represented by the components of incoherence, wave-passage and site-response effects. The incoherence effect is investigated by considering Harichandran and Vanmarcke model, the site-response effect is outlined by using hard, medium and soft soil types, and the wave-passage effect is taken into account by using 1000, 600 and 200 m/s wave velocities for the hard, medium and soft soils, respectively. Mean of maximum response values obtained from the analyses are compared with those of the specific cases of the ground motion model. It is concluded that the obtained results from the bridge model increase as the differences between local soil conditions cases of the bridge supports change from firm to soft. Moreover, the variation of the wave velocity has important effects on the responses of the deck and towers as compared with those of the travelling constant wave velocity case. In addition, the variability of the ground motions should be considered in the analysis of long span cable-stayed bridges to obtain more accurate results in calculating the bridge responses.

Investigation of the LPG Gas Explosion of a Welding And Cutting Torch at a Construction Site

  • Lee, Su-kyung;Lee, Jung-hoon;Song, Dong-woo
    • Korean Chemical Engineering Research
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    • v.56 no.6
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    • pp.811-818
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    • 2018
  • A fire and explosion accident caused by a liquefied petroleum gas (LPG) welding and cutting torch gas leak occurred 10 m underground at the site of reinforcement work for bridge columns, killing four people and seriously injuring ten. We conducted a comprehensive investigation into the accident to identify the fundamental causes of the explosion by analyzing the structure of the construction site and the properties of propane, which was the main component of LPG welding and cutting work used at the site. The range between the lower and upper explosion limits of leaking LPG for welding and cutting work was examined using Le Chatelier's formula; the behavior of LPG concentration change, which included dispersion and concentration change, was analyzed using the fire dynamic simulator (FDS). We concluded that the primary cause of the accident was combustible LPG that leaked from a welding and cutting torch and formed a explosion range between the lower and upper limits. When the LPG contacted the flame of the welding and cutting torch, LPG explosion occurred. The LPG explosion power calculation was verified by the blast effect computation program developed by the Department of Defense Explosive Safety Board (DDESB). According to the fire simulation results, we concluded that the welding and cutting torch LPG leak caused the gas explosion. This study is useful for safety management to prevent accidents caused by LPG welding and cutting work at construction sites.

Site response analysis using true coupled constitutive models for liquefaction triggering

  • Cristhian C. Mendoza-Bolanos;Andres Salas-Montoya;Oscar H. Moreno-Torres;Arturo I. Villegas-Andrade
    • Earthquakes and Structures
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    • v.25 no.1
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    • pp.27-41
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    • 2023
  • This study focused on nonlinear effective stress site response analysis using two coupled constitutive models, that is, the DM model (Dafalias and Manzari 2004), which incorporated a simple plasticity sand model accounting for fabric change effects, and the PMDY03 model (Khosravifar et al. 2018), that is, a 3D model for earthquake-induced liquefaction triggering and postliquefaction response. A detailed parametric study was conducted to validate the effectiveness of nonlinear site response analysis and porewater pressure (PWP) generation through a true coupled formulation for assessing the initiation of liquefaction at ground level. The coupled models demonstrated accurate prediction of liquefaction triggering, which was in line with established empirical liquefaction triggering relations in published databases. Several limitations were identified in the evaluation of liquefaction using the cyclic stress method, despite its widespread implementation for calculating liquefaction triggering. Variations in shear stiffness, represented by changes in shear wave velocity (Vs1), exerted the most significant influence on site response. The study further indicated that substantial differences in response spectra between nonlinear total stress and nonlinear effective stress analyses primarily occurred when liquefaction was triggered or on the verge of being triggered, as shown by excess PWP ratios approaching unity. These differences diminished when liquefaction occurred towards the later stages of intense shaking. The soil response was predominantly influenced by the higher stiffness values present prior to liquefaction. A key contribution of this study was to validate the criteria used to assess the triggering of level-ground liquefaction using true coupled effective-stress constitutive models, while also confirming the reliability of numerical approximations including the PDMY03 and DM models. These models effectively captured the principal characteristics of liquefaction observed in field tests and laboratory experiments.

AUTOMATIC DATA COLLECTION TO IMPROVE READY-MIXED CONCRETE DELIVERY PERFORMANCE

  • Pan Hao;Sangwon Han
    • International conference on construction engineering and project management
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    • 2011.02a
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    • pp.187-194
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    • 2011
  • Optimizing truck dispatching-intervals is imperative in ready mixed concrete (RMC) delivery process. Intervals shorter than optimal may induce queuing of idle trucks at a construction site, resulting in a long delivery cycle time. On the other hand, intervals longer than optimal can trigger work discontinuity due to a lack of available trucks where required. Therefore, the RMC delivery process should be systematically scheduled in order to minimize the occurrence of waiting trucks as well as guarantee work continuity. However, it is challenging to find optimal intervals, particularly in urban areas, due to variations in both traffic conditions and concrete placement rates at the site. Truck dispatching intervals are usually determined based on the concrete plant managers' intuitive judgments, without sufficient and reliable information regarding traffic and site conditions. Accordingly, the RMC delivery process often experiences inefficiency and/or work discontinuity. Automatic data collection (ADC) techniques (e.g., RFID or GPS) can be effective tools to assist plant managers in finding optimal dispatching intervals, thereby enhancing delivery performance. However, quantitative evidence of the extent of performance improvement has rarely been reported to data, and this is a central reason for a general reluctance within the industry to embrace these techniques, despite their potential benefits. To address this issue, this research reports on the development of a discrete event simulation model and its application to a large-scale building project in Abu Dhabi. The simulation results indicate that ADC techniques can reduce the truck idle time at site by 57% and also enhance the pouring continuity in the RMC delivery process.

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A Study on Information Collection and Idea Creation Using Drones (드론을 활용한 정보수집 및 아이디어 창출에 관한 연구)

  • Jo, Hwani;Yoo, Jaewon;Choi, Hyun
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.44 no.1
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    • pp.117-124
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    • 2024
  • The objective of Value Engineering (VE) is to derive the optimal value at the most efficient life cycle cost, comprising three stages: Pre-Study, Study, and Post-Study. In this study, we propose a method for information collection and analysis during planned site visit surveys in the preparation stage of VE. The 3D spatial model, created using a drone, facilitated observation and analysis of the study area from various angles, both from the center and the outside. Additionally, through the utilization of drones, we conducted on-site investigations of the research area's 3D spatial model, enabling a macroscopic perspective previously only feasible through a microscopic viewpoint during planned site visits in the pre-study phase. Furthermore, the utilization of actual spatial data obtained from observations allowed for real-time information verification during Design VE workshops, enhancing the efficiency and reliability of the VE project.

Analysis of Active Center in Hyperthermophilic Cellulase from Pyrococcus horikoshii

  • Kang, Hee-Jin;Ishikawa, Kazuhiko
    • Journal of Microbiology and Biotechnology
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    • v.17 no.8
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    • pp.1249-1253
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    • 2007
  • A hyperthermostable endoglucanase from Pyrococcus horikoshii with the capability of hydrolyzing crystalline cellulose was analyzed. A protein engineering study was carried out to obtain a reduced-size mutant. Five amino acid residues at both the N- and C-terminus were found to be removable without any loss of activity or thermal stability. Site-directed mutagenesis was also performed on R102, N200, E201, H297, Y299, E342, and W377, residues possibly involved in the active center or in the recognition and binding of a cellulose substrate. The activity of the resulting mutants was considerably decreased, confirming that the mutated residues were all important for activity. A reduced-size enzyme, as active as the wild-type endoglucanase, was successfully obtained, plus the residues critical for its activity and specificity were confirmed. Consequently, an engineered enzyme with a reduced size was obtained, and the amino acids essential for activity were confirmed by site-directed mutagenesis and comparison with a known three-dimensional structure.

A Method for Identifying Splice Sites and Translation Start Sites in Human Genomic Sequences

  • Kim, Ki-Bong;Park, Kie-Jung;Kong, Eun-Bae
    • BMB Reports
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    • v.35 no.5
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    • pp.513-517
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    • 2002
  • We describe a new method for identifying the sequences that signal the start of translation, and the boundaries between exons and introns (donor and acceptor sites) in human mRNA. According to the mandatory keyword, ORGANISM, and feature key, CDS, a large set of standard data for each signal site was extracted from the ASCII flat file, gbpri.seq, in the GenBank release 108.0. This was used to generate the scoring matrices, which summarize the sequence information for each signal site. The scoring matrices take into account the independent nucleotide frequencies between adjacent bases in each position within the signal site regions, and the relative weight on each nucleotide in proportion to their probabilities in the known signal sites. Using a scoring scheme that is based on the nucleotide scoring matrices, the method has great sensitivity and specificity when used to locate signals in uncharacterized human genomic DNA. These matrices are especially effective at distinguishing true and false sites.

A Study on the Research & Analysis of the Health and Safety Managing's Understanding on the Applied Construction Work Site Risk Assessment - Focus on Site Manager & Manager - (건설업 위험성평가 적용사업장 종사자 안전보건 인식도 조사 연구 -사업장책임자 및 관리감독자를 중심으로-)

  • Choi, Soo-Hwan;Kim, Chi-Kyung
    • Journal of the Korean Society of Safety
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    • v.27 no.4
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    • pp.62-67
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    • 2012
  • Risk Assessment, a basis of health and safety management system, is an calamity prevention activity which regularly measure the level of a risk to passively improve potential hazard. A problem, the assessment not being improved to be applied to the construction work site where requires diversity and complexity, causes the assessment to be inefficient to bring quality results. A study on the investigates and compares the surveyed degree of recognitions of workers who works in companies executing the risk assessment By the investigation and comparison, it is expected to bring the better solution for early and efficient application for those companies which are not taking the risk assessment.

A Case Study of Caisson Typed Bridge-Foundation Fabrication and Installation in Ul-san Newport Breakwater Project (케이슨식 교량기초 제작 및 거치 시공사례 -울산 신항 방파제현장 시공 사례를 중심으로-)

  • JANG BYUNG-SOO;SIN SUNG-GWEN;KIM DUCK-HO
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2004.11a
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    • pp.45-50
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    • 2004
  • The method of caisson typed bridge-foundation fabrication and installation applied in Ul-san newport breakwater project is throughly carried out to compact QRR mound vibro-hammer step by step to minimize settlement through stability check. Floating Dock was mobilized for caisson fabrication due to limited site area. fabricated caisson on the Floating Dock was towed to the deeper area of 8m water depth to be launched, and Floating Crane assisted launching and installation work of the caisson. finally water filling was done followed by surveying work to permanent installation.

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