• Clean Technology
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• v.30 no.3
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• pp.188-194
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• 2024

This study investigates the impact of reduction temperature on the structure and performance of cobalt-manganese (CM) based catalysts in the direct hydrogenation reaction of carbon dioxide (CO₂). It was observed that at a reduction temperature of 350 ℃, these catalysts could successfully facilitate the conversion of CO₂ into long-chain hydrocarbons. This efficiency is attributed to the optimal conditions provided by the core-shell structure of the catalysts, which effectively catalyzes both the reverse water-gas shift (RWGS) and Fischer-Tropsch (FT) reactions. However, as the reduction temperature increased to 600 ℃, the effectiveness of the reaction process was hindered, and there was a shift in selectivity towards methane. This shift is due to the excessive reduction of the catalyst's outer shell, which reduces the number of RWGS sites and subsequently suppresses the production of CO. These findings highlight the importance of carefully controlling the reduction temperature in the design and optimization of cobalt-based catalysts. Maintaining a balance between the RWGS and FT reactions is crucial. This emphasizes that the reduction temperature is a key factor in efficiently generating long-chain hydrocarbons from CO₂.

• Advances in nano research
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• v.17 no.4
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• pp.369-383
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• 2024

Annular nano-electromechanical systems (NEMS) in intelligent prosthetic hands enhance precision by serving as highly sensitive sensors for detecting pressure, vibrations, and deformations. This improves feedback and control, enabling users to modulate grip strength and tactile interaction with objects more effectively, enhancing prosthetic functionality. This research focuses on the electro-thermal buckling behavior of multi-directional poroelastic annular NEMS used as temperature sensors in airplanes. In the present study, thermal buckling performance of nano-scale annular functionally graded plate structures integrated with piezoelectric layers under electrical and extreme thermal loadings is investigated. In this regard, piezoelectric layers are placed on a disk made of metal matrix composite with graded properties in three radials, thickness and circumferential directions. The grading properties obey the power-law distribution. The whole structure is embedded in thermal environment. To model the mechanical behavior of the structure, a novel four-variable refined quasi-3D sinusoidal shear deformation theory (RQ-3DSSDT) is engaged in obtaining displacement field in the whole structure. The validity of the results is examined by comparing to a similar problem published in literature. The results of the buckling behavior of the structure in different boundary conditions are presented based on the critical temperature rise and critical external voltage. It is demonstrated that increase in the nonlocal and gradient length scale factor have contradicting effects on the critical temperature rise. On the other hand, increase in the applied external voltage cause increase in the critical temperature. Effects of other parameters like geometrical parameters and grading indices are presented and discussed in details.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.28 no.2
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• pp.145-152
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• 2015

In the study, the effects of damping devices on damping ratio increase and wind-load reduction were investigated based on the computational platform, which is one of the parametric modeling methods. The computational platform helps the designers or engineers to evaluate the efficacy of the numerous alternative structural systems for irregular Super-Tall building, which is crucial in determining the capacity and the number of the supplemental damping devices for adding the required damping ratios to the building. The inherent damping ratio was estimated based on the related domestic and foreign researches conducted by using real wind-load records. Two types of damping devices were considered: One is inter-story installation type passive control devices and the other is mass type active control devices. The supplemental damping ratio due to the damping devices was calculated by means of equivalent static analysis using an equation suggested by FEMA. The optimal design of the damping devices was conducted by using the computational platform. The structural element quantity reduction effect resulting from the installation of the damping devices could be simply assessed by proposing a wind-load reduction factor, and the effectiveness of the proposed method was verified by a numerical example of a 455m high-rise building. The comparison between roof displacement and the story shear forces by the nonlinear time history analysis and the proposed method indicated that the proposed method could simply but approximately estimate the effects of the supplemental damping devices on the roof displacement and the member force reduction.

• Journal of Microbiology and Biotechnology
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• v.23 no.9
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• pp.1308-1321
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• 2013

The emergence of microcarrier technology has brought a renewed interest in anchorage-dependent cell culture for high-yield processes. Well-known in vaccine production, microcarrier culture also has potential for application in other fields. In this work, two types of microcarriers were evaluated for small-scale monoclonal antibody (mAb) production by CHO-K1 cells. Cultures (5 ml) of microporous Cytodex 3 and macroporous CultiSpher-S carriers were performed in vented conical tubes and subsequently scaled-up (20 ml) to shake-flasks, testing combinations of different culture conditions (cell concentration, microcarrier concentration, rocking methodology, rocking speed, and initial culture volume). Culture performance was evaluated by considering the mAb production and cell growth at the phases of initial adhesion and proliferation. The best culture performances were obtained with Cytodex 3, regarding cell proliferation (average $1.85{\pm}0.11{\times}10^6$ cells/ml against $0.60{\pm}0.08{\times}10^6$ cells/ml for CultiSpher-S), mAb production ($2.04{\pm}0.41{\mu}g/ml$ against $0.99{\pm}0.35{\mu}g/ml$ for CultiSpher-S), and culture longevity (30 days against 10-15 days for CultiSpher-S), probably due to the collagen-coated dextran matrix that potentiates adhesion and prevents detachment. The culture conditions of greater influence were rocking mechanism (Cytodex 3, pulse followed by continuous) and initial cell concentration (CultiSpher-S, $4{\times}10^5$ cells/ml). Microcarriers proved to be a viable and favorable alternative to standard adherent and suspended cultures for mAb production by CHO-K1 cells, with simple operation, easy scale-up, and significantly higher levels of mAb production. However, variations of microcarrier culture performance in different vessels reiterate the need for optimization at each step of the scale-up process.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.21 no.2
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• pp.179-187
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• 2010

The use of high frequency band, broad band and MIMO antenna is expected in the next generation mobile communication system. By the rapid increase of demand for wireless communications and the explosive increase of the mobile communication services, researches for optimization of next-generation mobile communication system are required. In the existing MIMO channel models, propagation-environments are commonly classified into urban, suburban, rural area, etc. However such approaches can have drawbacks in that many different morphologies may exist even in the urban area, for example. In this paper, we introduced path morphology concept, and proposed the method of morphology classification considering the building height, density, etc. Delay spread(DS), angular spread(AS) of AoD and AoA analyzed for each environment using the ray tracing technique. Based on the analysis, a MIMO channel model appropriate in domestic environment was suggested.

• Applied Chemistry for Engineering
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• v.19 no.6
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• pp.668-673
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• 2008

The objective of this study is to optimize the leaching conditions of sequential leaching and extracting processes for selective Ni recovery from spent Ni-Mo-based catalyst. The selective Ni recovery process consists of two processes of leaching and extracting process. In this 2-step process, Ni component is dissolved from solid spent Ni-Mo-based catalyst into leaching agent in leaching process and sequentially extracted to Ni complex with an extracting agent in the extracting process. The solutions of nitric acid ($HNO_3$), ammonium carbonate ($(NH_4)_2CO_3$) and sodium carbonate ($Na_2CO_3$) were used as a leaching agent in leaching process and oxalic acid was used as an extracting agent in extracting process. $HNO_3$ solution is the most efficient leaching agent among the various leaching agent. Also, the optimized leaching conditions for the efficient and selective Ni recovery were the leaching temperature of $90^{\circ}C,\;HNO_3$ concentration of 6.25 vol% and elapsed time of 3 h. As a result, Nickel oxalate having the highest yield of 88.7% and purity of 100% was obtained after sequentially leaching and extracting processes under the optimized leaching conditions.

• Journal of the Institute of Electronics and Information Engineers
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• v.49 no.10
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• pp.111-121
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• 2012

In this paper, a poly-Si thin film transistor with ${\sim}0.5{\mu}m$ gate length was fabricated and its electrical characteristics are optimized. From the results, it was verified that making active region with larger grain size using low temperature annealing is an efficient way to enhance the subthreshold swing, drain-induced barrier lowering and on-current characteristics. A SONOS flash memory was fabricated using this poly-Si channel process and its performances are analyzed. It was necessary to optimize O/N/O thickness for the reduction of electron back tunneling and the enhancement of its memory operation. The optimized device showed 2.24 V of threshold voltage memory windows which coincided with a well operating flash memory.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.22 no.7
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• pp.694-704
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• 2011

In this paper, we present a design of a 5th order Chebyshev interdigital band-pass filter using inverter and susceptance slope parameter values obtained from EM simulated multi-port Y-parameters. The shifted length of the resonator is determined when the frequency of the transmission zero is separated far away from the center frequency. For the initial dimensions of the interdigital filter, the filter is decomposed into the individual resonators, and the dimensions are obtained using EM Simulation of the decomposed resonators. However, the interdigital filter with the dimensions determined from the EM simulation of the decomposed resonators shows slightly distorted response from the desired frequency response due to the coupling between non-adjacent resonators. To obtain a EM simulation dataset, EM simulation for this filter is carried out by parameter sweep with constant ratio for the initial values. In this dataset, it is determined the final values for the filter by optimization. The fabricated filter by PCB shows an upper-shift of center frequency of about 70 MHz, which was caused by permittivity changed and tolerance of fabrication.

• Journal of Korea Water Resources Association
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• v.53 no.6
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• pp.395-408
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• 2020

This paper aims to develop and apply three different machine learning approaches (i.e., artificial neural networks (ANN), adaptive neuro-fuzzy inference systems (ANFIS), and wavelet-based neural networks (WNN)) combined with an evolutionary optimization algorithm and the k-fold cross validation for multi-step (days) streamflow forecasting at the catchment located in Algeria, North Africa. The ANN and ANFIS models yielded similar performances, based on four different statistical indices (i.e., root mean squared error (RMSE), Nash-Sutcliffe efficiency (NSE), correlation coefficient (R), and peak flow criteria (PFC)) for training and testing phases. The values of RMSE and PFC for the WNN model (e.g., RMSE = 8.590 ㎥/sec, PFC = 0.252 for (t+1) day, testing phase) were lower than those of ANN (e.g., RMSE = 19.120 ㎥/sec, PFC = 0.446 for (t+1) day, testing phase) and ANFIS (e.g., RMSE = 18.520 ㎥/sec, PFC = 0.444 for (t+1) day, testing phase) models, while the values of NSE and R for WNN model were higher than those of ANNs and ANFIS models. Therefore, the new approach can be a robust tool for multi-step (days) streamflow forecasting in the Seybous River, Algeria.

• Plant Journal
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• v.9 no.3
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• pp.38-42
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• 2013

Submarine gas fields have focused because of the increasing fuel cost, the environmental regulations, and the safety & NIMBY problems. LNG-FPSO which is available for acid gas removal, recovery of the condensate & LPG and Liquefaction in topside process is one of high technology offshore structures. On the other hands, it is necessary to verify the pre-treatment efficiency by the ship motion and to apply to the design for LNG-FPSO. This study is to develop the pre-treatment technology for LNG-FPSO as taking account to the process efficiency by ship motion effects and the area optimization. Based on the simulation results, it founds that hybrid process shows the low circulate rate, the low heat duty and the small size of column dimensions compared to typical amine process. It will be verified the process efficiency in the various conditions by sea states as performing the 6-DOF motion test and CFD simulation.