• Title/Summary/Keyword: engineering education in secondary education

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Kinetic Study on the Oxidation Reaction of Alcohols by Cr(VI)-Quinoline Compound (크롬(VI)-퀴놀린 화합물에 의한 알코올류의 산화반응에 대한 반응속도론적 연구)

  • Park, Young-Cho;Kim, Soo-Jong
    • Journal of Convergence for Information Technology
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    • v.11 no.9
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    • pp.109-114
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    • 2021
  • Cr(VI)-quinoline compound[(C9H7NH)2Cr2O7] was synthesized by the reaction between of quinoline and chromium(VI) trioxide, and structure was FT-IR, elemental analysis. The oxidation ability of benzyl alcohol greatly depends upon the dielectric constant of the used organic solvent, where carbon tetrachloride was worst and N,N'-dimethylformamide was best solvent. Noticeably, in N,N'-dimethylformamide solvent, Cr(VI)-quinoline compound oxidized substituted benzyl alcohols. The Hammett reaction constant(ρ)=-0.69(303K). As a resuit, Cr(VI)-quinoline compound was found as efficicent oxidizing agent that converted benzyl alcohol, allyl alcohol, primary alcohol and secondary alcohols to the corresponding aldehydes or ketones. Cr(VI)-quinoline compound was selective oxidizing agent of benzyl alcohol, allyl alcohol and primary alcohol in the presence of secondary alcohol ones.

Shifting Cultivation and Environmental Problems of Nam Khane Watershed, Laos (라오스 남칸(Nam Khane)유역분지(流域盆地)의 이동식화전농업(移動式火田農業)과 환경문제(環境問題))

  • Jo, Myung-Hee;Jo, Hwa-Ryong
    • Journal of the Korean association of regional geographers
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    • v.1 no.1
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    • pp.93-101
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    • 1995
  • Nam Khane watershed, in the Northern Laos, consists of limestone plateau surrounded with steep slope(above 1000m), wide piedmont hill land(300-700m) and narrow alluvial plain. Opium on the plateau and up-land rice on the hill-side are cultivated for each, but its shifting agricultural activity, which degrades the forest and soil, has caused the serious environmental problems. MOS-1 satellite image and 40 points of soil samples are analyzed to identify the distribution of the shifting cultivation and to evaluate the environmental problems for Nam Khane watershed. The land use classification map is presented on the photo 2, and the value of each land use area by elevation level and soil property are showed on the table 2 and 3, respectively. Excessive agricultural activity of shifting cultivation in the Nam Khane watershed not only decreased the forest area, but also changed the primary forest of tree into secondary woodland of shrub. On the phase of soil property, it accelerated the soil and gully erosion, and acidification. To solve these environmental problems, the most important step is to settle the agriculture from shifting cultivation to permanent cropping.

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