• Applied Chemistry for Engineering
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• v.21 no.1
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• pp.18-23
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• 2010

This work investigated the catalytic reaction characteristics of $H_2$ SCR applied at low temperature ($80{\sim}150^{\circ}C$) using Pt catalyst supported on $TiO_2$. The experiments were performed in terms of $H_2O$, $O_2$ in reaction gas, calcination temperature of the Pt catalyst, $H_2$/NOx mole ratio, space velocity. $H_2O$ was an inhibitor of reaction on $H_2$ SCR using Pt catalyst, catalytic performance increased as $O_2$ concentration decreased. Nevertheless, $NH_3$ slip generated by the reaction between NOx and $H_2$ in the absence of $O_2$. While it was effective to calcine less than $600^{\circ}C$ by phase transition and the catalytic performance increased as $H_2$/NOx mole ratio increased. However, $H_2$ slip was not observed at that increase mole ratio by $H_2$ oxidation to $H_2O$.

• Tunnel and Underground Space
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• v.22 no.2
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• pp.77-85
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• 2012

In a material, micro-cracks can be progressively occurred, propagated and finally lead to failure when it is subjected to cyclic or periodic loading less than its ultimate strength. This phenomenon, fatigue, is usually considered in a metal, alloy and structures under repeated loading conditions. In underground structures, a static creep behavior rather than a dynamic fatigue behavior is mostly considered. However, when compressed air is stored in a rock cavern, an inner pressure is periodically changed due to repeated in- and-out process of compressed air. Therefore mechanical properties of surrounding rock mass and an inner lining system under cyclic loading/unloading conditions should be investigated. In this study, considering an underground lined rock cavern for compressed air energy storage (CAES), the mechanical properties of a lining system, that is, concrete lining and plug under periodic loading/unloading conditions were characterized through cyclic bending tests and shear tests. From these tests, the stability of the plug was evaluated and the S-N line of the concrete lining was obtained.

• Journal of the Korean Chemical Society
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• v.63 no.6
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• pp.453-458
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• 2019

Synthesis of ZnCo₂O₃ oxide is performed by sol-gel method via nitrate-citrate route. Powder X-ray diffraction (XRD) study shows monoclinic unit cell having lattice parameters: a = 5.721(1) Å, b = 8.073(2) Å, c = 5.670(1) Å, β = 93.221(8)°, space group P_2/m and Z = 4. Average crystallite sizes determined by Scherrer equation are the range ~14-32 nm, whereas SEM micrographs show nano-micro meter size particles formed in ZnCo₂O₃. Endothermic peak at ~798 K in the Differential scanning calorimetric (DSC) trace without weight loss could be due to structural transformation and the endothermic peak ~1143 K with weight loss is due to reversible loss of O₂ in air atmosphere. Energy Dispersive X-ray (EDX) analysis profile shows the presence of elements Zn, Co and O which indicates the purity of the sample. Magnetic measurements in the range of +12 kOe to -12 kOe at 10 K, 77 K, 120 K and at 300 K by PPMS-II Physical Property Measurement System (PPMS) shows hysteresis loops having very low values of the coercivity and retentivity which indicates the weakly ferromagnetic nature of the oxide. Observed X-band EPR isotropic lineshapes at 300 K and 77 K show positive g-shift at g_iso ~2.230 and g_iso ~2.217, respectively which is in agreement with the presence of paramagnetic site Co²⁺(3d⁷) in the oxide. DC conductivity value of 2.875 ×10^-8 S/cm indicates very weakly semiconducting nature of ZnCo₂O₃ at 300 K. DRS absorption bands ~357 nm, ~572 nm, ~619 nm and ~654 nm are due to the d-d transitions ⁴T_1g(⁴F)→²E_g(²G), ⁴T_1g(⁴F)→⁴T_1g(⁴P), ⁴T_1g(⁴F)→⁴A_2g(⁴F), ⁴T_1g(⁴F)→⁴T_2g(⁴F), respectively in octahedral ligand field around Co²⁺ ions. Direct band gap energy, E_g~ 1.5 eV in the oxide is obtained by extrapolating the linear part of the Tauc plot to the energy axis indicates fairly strong semiconducting nature of ZnCo₂O₃.

• Journal of Hydrogen and New Energy
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• v.31 no.1
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• pp.57-64
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• 2020

The water-gas shift reaction for the compact reformer was carried out at a gas hourly space velocity of 72,152 h^-1 over the Cu-Nb-CeO₂ catalysts prepared by co-precipitation method. In order to investigate the effect of Nb₂O₅ promotion over a Cu-CeO₂ catalyst, the Nb₂O₅ loading amount was systematically changed from 0 to 5 wt.%. Among the prepared catalysts, the Cu-Nb-CeO₂ (1%) catalyst showed the highest catalytic activity (CO conversion=61% at 400℃) as well as 100% CO₂ selectivity. The high activity and stability of Cu-Nb-CeO₂ (1%) catalyst are correlated to high Brunauer-Emmett-Teller surface area, small metallic Cu crystallite size, and enhanced redox property.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.36 no.3
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• pp.257-265
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• 2000

Brushless DC(BLDC) motors are widely used as AC servo motors in factory automation fields because of their quick instantaneous mobility, good energy saving efficiency and easiness of design for control system comparing with induction motors. Recently, a Two-Degree-of-Freedom(2DOF) PI control law has been adopted to some application parts to accomplish an advanced speed control of BLDC motors. The method can treat the two conflicting performances, minimum tracking errors versus reference inputs without large overshoot and rejection of some disturbances including modeling errors, independently. However, the method can not design the optimal system which is able to minimize tracking errors and energy consumption simultaneously. In this paper, a 2DOF integral type optimal servo control method is investigated to promote the speed control performances of BLDC motors considering energy consumption. In order to applicate the method to the speed servo system of the BLDC motor, the motor is modeled in the state space using the vector control and decoupling technique. To verify the validity of the suggested method, some simulations and experiments are performed.

• Tunnel and Underground Space
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• v.22 no.3
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• pp.173-180
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• 2012

In this study, diagonal ventilation circuits that are advantageous in air flow direction control were studied. Based on the results of the study, it could be seen that air volumes in diagonal ventilation circuits could also be calculated using numerical formulas or programs if the air volumes and air flow directions to be infused into diagonal branches are determined in advance as with other serial/parallel circuits. To apply the results, design plans for high level radioactive waste repositories applied with diagonal ventilation circuits and parallel ventilation circuits. To compared the each design plans and obtain expected operation results, ventilation network simulations were conducted through the Ventsim program which is a ventilation networking program. Based on the results, in the case of diagonal repositories that was expected to cause great increases in resistance, fan pressure was 1570 pa, total flux was 84 $m^3/s$, fan efficiency was 76.4%, fan power consumption was 181.2 kW and annual fan operating costs were 178,710,838 and thus maximum around 8% differences were shown in pressure and flux values and a difference of around 1.5% was shown in terms of operating costs.

• Tunnel and Underground Space
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• v.28 no.2
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• pp.156-169
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• 2018

The relationship between the mechanical and textural properties of sedimentary rocks has been studied for decades. However, inconsistencies in the results have arisen from both the inhomogeneity of natural rocks and the difficulties encountered in controlling just one textural factor of interest in each experiment. This work produced artificial sedimentary rocks to enable control of every independent parameter at all times. Their homogeneity lowered the deviation of the results, and thus they produced clearer correlations than for natural rocks. The samples were made by mixing bassanite powder with water and silica sand, which produced rocks consisting of sand and gypsum cement. The effect of grain content and size on mechanical properties such as uniaxial compressive strength, Young's modulus, and seismic velocity was estimated. Increasing grain content lowered the compressive strength but raised Young's modulus and seismic velocity. Overall, grain size did not linearly affect the mechanical properties of the samples, but affected them in some way. In future, these results can be compared and integrated with similar experiments using different cement or grain types. This should allow comparison of the effects of the rock constituents themselves and their interactions, with applicability to all kinds of sedimentary rocks.

• Korean Journal of Soil Science and Fertilizer
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• v.23 no.2
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• pp.94-99
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• 1990

A field experiment was conducted to study seasonal evapotranspiration above soybean canopy and its relationship with dry matter production by the Bowen ratio-energy balance method. The soybean "Paldalkong" was sown with the space of $47{\times}10cm$ at Suwon on May 27, 1988. The daily net radiation ranged from 59 to 76 percents of the total shortwave radiation under cloudless conditions, which was lower than cloud overcast condition with recorded 63 to 83 percents. The latent heat flux under overcast condition was sometimes larger than the sum of net radiation, implying transportation of energy by advection of ambient air. The linear relationship was obtained between daily or daytime net radiation and evapotranspiration. The evapotranspiration calculated by Bowen ratio-energy balance method was about 150 percent of class A pan evaporation during the growing season. The total solar radiation from June 20 to August 27 was $1043MJm^{-2}$. The 85 percent of the total shortwave radiation was used for evaporative heat. The dry matter production within the period was $836gm^{-2}$ and the water use efficiency was $2.31gDM\;kg^{-1}\;H_2O$.

• Tunnel and Underground Space
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• v.24 no.3
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• pp.201-211
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• 2014

In the present study, the thermal performance of multiple rock caverns for large-scale thermal energy storage (TES) was numerically investigated for different separation distances between the caverns through heat transfer analysis using a computational fluid dynamics code, FLUENT. The thermal performance of multiple caverns was assessed in terms of the thermal stratification within the caverns and the heat loss to the surroundings, and the heating characteristics of the rock around the caverns were investigated. The results of numerical simulation showed that there was little difference in thermal performance between multiple TES caverns with different separation distances when the surrounding rock was less heated and it reached thermal steady-state, which represent the thermal states of the surrounding rock at the early and long-term operational stages of the TES caverns, respectively. However, as the separation distance decreased, the rock between the caverns reached thermal steady-state more quickly, and thus the heat loss from the caverns tended to converge rapidly to the value of heat loss occurred under thermal steady-state conditions in the surrounding rock. This result implies that the operating cost of heating the surrounding rock (i.e., rock heating) can be reduced with a reduction in the separation distance between multiple caverns, and suggests that the separation distance should be determined by considering the operating cost of rock heating as well as the construction cost of the caverns.

• Korean Chemical Engineering Research
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• v.47 no.4
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• pp.481-487
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• 2009

In this of study, effects of input air velocity(0.05~0.22 m/sec) and molten carbonate salt temperature ($870{\sim}970^{\circ}C$) on flow regime transition have been studied by adopting a drift-flux model of air holdup and a stochastic analysis of differential pressure fluctuations in an air-molten sodium carbonate salt two-phase system(molten salt oxidation process). Air holdup where the flow regime transition begins was determined by air holdup-drift flux plot. The air holdup value which the flow regime transition begins was increased with increasing molten carbonate salt temperature due to the decrease of viscosity and surface tension of molten carbonate salt. To characterize the flow regime transition more quantitatively, differential pressure fluctuation signals have been analyzed by adopting the stochastic method such as phase space portraits and Kolmogorov entropy, The Kolmogorov entropy decreased with an increasing of molten carbonate salt temperature but increased gradually with an increase in an air velocity, however, it exhibited different tendency with the flow regime and the air velocity value which flow regime transition begins was same to the results of drift-flux analysis.