• Bulletin of the Korean Chemical Society
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• v.35 no.10
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• pp.2911-2916
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• 2014

The gas phase structures, energetics, and interconversion pathways of five lowest energy conformers of acetylcholine were examined employing the B3LYP, MP2, and CCSD(T) methods in conjunction with diverse basis sets including the correlation consistent aug-cc-pVDZ and aug-cc-pVTZ basis sets. It is found that use of adequate basis set containing proper polarization and diffuse functions capable of describing the floppy potential energy surface of acetylcholine is important in correctly predicting the relative stability of these conformers. The interconversion pathways and barrier heights between these conformers were elucidated by examining the potential energy surface for torsional motion, which also manifested the presence of chiral conformations of acetylcholine corresponding to the original conformations. On the basis of high level electronic energy calculations and thermal contribution analysis, four lowest energy conformers appear to be populated in the energy range of less than 1 kcal/mol at room temperature.

• Nuclear Engineering and Technology
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• v.40 no.7
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• pp.533-538
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• 2008

In some situations, for example at very low doses, in microbeam irradiation experiments, or around high energy heavy ion tracks, use of the absorbed dose to describe the energy transferred to the irradiated target can be misleading. Since absorbed dose is the expected value of energy per mass it takes into account all of the targets which do not have any energy deposition. In many situations that results in numerical values, in Joules per kg, which are much less than the energy deposited in targets that have been crossed by a charged particle track. This can lead to confusion about the biochemical processes that lead to the consequences of irradiation. There are a few alternative approaches to describing radiation that avoid this potential confusion. Examples of specific situations that can lead to confusion are given. It is concluded that using the particle radiance spectrum and the exposure time, instead of absorbed dose, to describe these irradiations minimizes the potential for confusion about the actual nature of the energy deposition.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2018.05a
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• pp.51-52
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• 2018

Selective oxidation of RE elements from the U/RE metal ingot was studied in this paper using electrochemical process. Constant potential of -1.7V was applied between anode and cathode, where the potential value corresponds to standard potentials between actinide and rare earth materials. When the current values approached to nearly 0 mA, the reaction was finished. It is confirmed from the EPMA analysis that only U part of the U/RE ingot was remained. The metal recovered to the zinc cathode was obtained through the distillation process and it is being chemically analyzed in the KAERI analytical laboratory.

• Rapid Communication in Photoscience
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• v.4 no.4
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• pp.82-85
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• 2015

Photoelectrochemical cell (PEC) is one of the attractive ways to produce clean and renewable energy. However, solar to hydrogen production via PEC system generally requires high external bias, because of material's innate electronic band potential relative to hydrogen reduction potential and/or charge separation issue. For spontaneous photo-water splitting, here, we design dye-sensitized solar cell (DSSC) and their monolithic tandem cell incorporated with a $BiVO_4$ photoanode. $BiVO_4$ has high conduction band edge potential and suitable band gap (2.4eV) to absorb visible light. To achieve efficient $BiVO_4$ photoanode system, electron and hole mobility should be improved, and we demonstrate a tandem cell in which $BiVO_4/WO_3$ film is connected to cobalt complex based DSSC.

• Structural Engineering and Mechanics
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• v.31 no.6
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• pp.625-638
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• 2009

Applications of membrane mechanisms are widely found in nano-devices and nano-sensor technologies nowadays. An alternative approach for large deflection analysis of the orthotropic, elliptic membranes - subject to gravitational, uniform pressures often found in nano-sensors - is described in this paper. The material properties of membranes are assumed to be orthogonally isotropic and linearly elastic, while the principal directions of elasticity are parallel to the coordinate axes. Formulating the potential energy functional of the orthotropic, elliptic membranes involves the strain energy that is attributed to inplane stress resultant and the potential energy due to applied pressures. In the solution method, Rayleigh-Ritz method can be used successfully to minimize the resulting total potential energy generated. The set of equilibrium equations was solved subsequently by Newton-Raphson. The unparalleled model formulation capable of analyzing the large deflections of both circular and elliptic membranes is verified by making numerical comparisons with existing results of circular membranes as well as finite element solutions. The results are found in excellent agreements at all cases. Then, the parametric investigations are given to delineate the impacts of the aspect ratios and orthotropic elasticity on large static tensions and deformations of the orthotropic, elliptic membranes.

• Journal of Biomedical Engineering Research
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• v.29 no.5
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• pp.408-413
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• 2008

Human body has a complete left and right symmetry structure, and the left and right balance by Yin and Yang. When the balance is broken, the left and right Meridian becomes abnormal condition. Acupuncture is a kind of therapy to recover from energy unbalance of the left and right Meridian to a new balance condition. In the study, we observed the electric potential along the stomach meridian (ST) in order to verify the energy consensus phenomenon by transportation of bio-energy between operator and subject during acupuncture. The acupuncture effects on opposite meridian site were investigated by comparing the electric potentials between the right and left ST sites. Meridian electrical potentials (MEPs) between operator and subject were simultaneously generated during the acupuncture and the polarity of MEPs was opposite. The results might imply the bio-energy transportation between operator and subject. In addition, we observed three different patterns of MEPs on both ST sites which might represent the condition of the related meridians because meridians in the body are organically interconnected.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2005.11b
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• pp.39-50
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• 2005

Electrolytic reduction of uranium oxide to uranium metal was studied in a $LiCl-Li_{2}O$ molten salt system. The reduction mechanism of the uranium oxide to a uranium metal has been studied by means of a cyclic voltammetry. Effects of the layer thickness of the uranium oxide and the thickness of the MgO on the overpotential of the cathode and the anode were investigated by means of a chronopotentiometry. From the cyclic voltamograms, the decomposition potentials of the metal oxides are the determining factors for the mechanism of the reduction of the uranium oxide in a $LiCl-3\;wt{\%} Li_{2}O$ molten salt and the two mechanisms of the electrolytic reduction were considered with regards to the applied cathode potential. In the chronopotentiograms, the exchange current and the transfer coefficient based on the Tafel behavior were obtained with regard to the layer thickness of the uranium oxide which is loaded into the porous MgO membrane and the thickness of the porous MgO membrane. The maximum allowable currents for the changes of the layer thickness of the uranium oxide and the thickness of the MgO membrane were also obtained from the limiting potential which is the decomposition potential of LiCl.

• 한국신재생에너지학회:학술대회논문집
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• 2011.11a
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• pp.59.2-59.2
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• 2011

This study presents a new method for coupling ArcGIS (popular GIS software) with TRaNsient SYstems Simulation (TRNSYS, reference software for researchers and engineers around the world) to use capabilities of the 4 and 5-parameter PV array performance models within the ArcGIS environment. Using the validated and industry-proven solar energy simulation models implemented in TRNSYS and other built-in ArcGIS functionalities, dynamic characteristics of distributed PV potential in terms of hourly, daily or monthly power outputs can be investigated with considerations of diverse options in selecting and mounting PV panels. In addition, the proposed method allows users to complete entire procedures in a single framework (i.e., a preliminary site survey using 3D building models, shading analyses to investigate usable rooftop areas with considerations of different sizes and shapes of buildings, dynamic energy simulation to examine the performances of various PV systems, visualization of the simulation results to understand spatially and temporally distributed patterns of PV potential). Therefore tedious tasks for data conversion among multiple softwares can be significantly reduced or eliminated. While the programming environment of TRNSYS is proprietary, the redistributable executable, simulation kernel and simulation engine of TRNSYS can be freely distributed to end-users. Therefore, GIS users who do not have a license of TRNSYS can also use the functionalities of solar energy simulation models within ArcGIS.

• 한국태양에너지학회:학술대회논문집
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• 2011.04a
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• pp.235-240
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• 2011

Small hydropower resources for five major river systems have been studied. The model, which can predict flow duration characteristic of stream, was developed to analyze the variation of inflow caused from rainfall condition. And another model to predict hydrologic performance for small hydropower(SHP) plants is established. Monthly inflow data measured at Andong dam were analyzed. The predicted results from the developed models in this study showed that the data were in good agreement with measured results of long term inflow at Andong darn. It was found that the models developed in this study can be used to predict the available potential and technical potential of SHP sites effectively. Based on the models developed in this study, the hydrologic performance for small hydropower sites located in river systems have been analyzed. The results show that the hydrologic performance characteristics of SHP sites have some difference between the river systems. Especially, the specific design flowrate and specific output of SHP sites located on North Han river and Nakdong river systems have large difference compared with other river systems.

• Journal of the Korean Electrochemical Society
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• v.7 no.4
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• pp.211-219
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• 2004

A classical Lippmann equation valid for liquid electrodes can not describe the interfacial properties of solid electrodes due to the elastic surface strain on solid electrodes. Although there have been many attempts to derive the thermodynamic equations for solid electrodes Outing the past few decades, their validity has been still questioned by many researchers. In practice, although there are various experimental techniques to measure surface energy of solid electrodes, the results obtained by each technique are rather inconsistent due to the complexity of the surface strain on solid electrodes. This article covers these controversial issues in surface energy of solid electrodes. After giving brief summaries of the definition of the important thermodynamic parameters and the derivation of the thermodynamic equations for solid electrodes, the several experimental methods were introduced for the measurement of surface energy of solid electrodes. And then we discussed in detail the inconsistent results in the measurement of the potential of zero charge (pac) and the potential of electrocapillary maximum (ecm).