• Title/Summary/Keyword: energy gap

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Effect of Processing Parameters on the Microstructure and Band Gap Energy of 1D-Na2Ti6O13 (1D-Na2Ti6O13 합성 변수에 따른 미세구조 및 밴드 갭 에너지 변화)

  • Yun, Kang-Seop;Ku, Hye-Kyung;Kang, Woo-Seung;Kim, Sun-Jae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.8
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    • pp.664-669
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    • 2012
  • Nano-structured one-dimensional $Na_2Ti_6O_{13}$ particles were synthesized by a molten salt process. Effects of processing parameters on the microstructure and band gap energy of the $Na_2Ti_6O_{13}$ powder were studied in this paper. For the synthesis of the $Na_2Ti_6O_{13}$ particles, two different raw materials of tubular shaped Na-titanate (Na-TiNT) and spherical shaped $TiO_2$ were utilized. Synthesizing with the raw material of Na-TiNT, around 70nm thick 1D-$Na_2Ti_6O_{13}$ with the bandgap energy of 3.5 eV was obtained at $810^{\circ}C$. Below $810^{\circ}C$ or without the presence of NaCl, 1D-$Na_2Ti_6O_{13}$ was in a relatively short in length and agglomerated state. With the processing temperature increased, the thickness of the 1D-$Na_2Ti_6O_{13}$ was also observed to be increased. On the other hand, when $TiO_2$ was employed as a raw material, the mixed amount of $Na_2CO_3$ played an important role in transforming the morphology and phase of the raw material, affecting the bandgap energy of the synthesized product. Specific surface area of the synthesized 1D-$Na_2Ti_6O_{13}$ was significantly affected by the raw and mixed materials as well as processing temperature. When Na-TiNT was processed at $810^{\circ}C$ with NaCl, the specific surface area of the 1D-$Na_2Ti_6O_{13}$ showed the best value of 30.63 $m^2/g$.

Optical Properties of Photoferroelectic Semiconductors IV.(Optical Properties of SbSI:V, SbSeI:V, BiSI:V, BiSeI:V, SbSI:Cr, SbSeI:Cr, BiSI:Cr, BiSeI:Cr, SbSI:Ni, SbSeI:Ni, BiSI:Ni and BiSeI:Ni Single Crystals) (Photoferroelectric 반도체의 광학적 특성 연구 IV. (SbSI:V, SbSeI:V, BiSI:V, BiSeI:V, SbSI:Cr, SbSeI:Cr, BiSI:Cr, BiSeI:Cr, SbSI:Ni, SbSeI:Ni, BiSI:Ni 및 BiSeI:Ni 단결정의 광학적 특성에 관한 연구))

  • Oh, Seok-Kyun;Hyun, Seung-Cheol;Yun, Sang-Hyun;Kim, Wha-Tek;Kim, Hyung-Gon;Choe, Sung-Hyu;Yoon, Chang-Sun;Kwun, Sook-Il
    • Journal of the Korean Vacuum Society
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    • v.2 no.2
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    • pp.236-245
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    • 1993
  • Single crystals, SbSI : V, SbSeI : V, BiSI : V, BiSeI : V, SbSI : Cr, SbSeI : Cr, BiSI : Cr, BiSeI : Cr, SbSI : Ni, SbSeI : Ni, BiSI : Ni, and BiSeI : Ni were grown by the vertical Bridgman method. It is found that the grown single crystals have an orthorhombic structure and the indirect optical transitions. The temperature dependence of energy gap shows the two reflection point related with the phase transitions and is well fitted with Varshni equation in the continuous region. The optical absorption peaks due to the doped impurities (V, Cr and Ni) are respectively attributed to the electron transitions between the split energy levels of $V^{+2}$, $Cr^{+2}$ and $Ni^{+2}$ ions sited at $T_d$ symmetry of the host lattice.

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A STUDY OF A NUCLEAR HYDROGEN PRODUCTION DEMONSTRATION PLANT

  • Chang, Jong-Hwa;Kim, Yong-Wan;Lee, Ki-Young;Lee, Young-Woo;Lee, Won-Jae;Noh, Jae-Man;Kim, Min-Hwan;Lim, Hong-Sik;Shin, Young-Joon;Bae, Ki-Kwang;Jung, Kwang-Deog
    • Nuclear Engineering and Technology
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    • v.39 no.2
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    • pp.111-122
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    • 2007
  • The current energy supply system is burdened by environmental and supply problems. The concept of a hydrogen economy has been actively discussed worldwide. KAERI has set up a plan to demonstrate massive production of hydrogen using a VHTR by the early 2020s. The technological gap to meet this goal was identified during the past few years. The hydrogen production process, a process heat exchanger, the efficiency of an I/S thermochemical cycle, the manufacturing of components, the analysis tools of VHTR, and a coated particle fuel are key areas that require urgent development. Candidate NHDD plant designs based on a 200 MWth VHTR core and I/S thermochemical process have been studied and some of analysis results are presented in this paper.

Accurate Wind Speed Prediction Using Effective Markov Transition Matrix and Comparison with Other MCP Models (Effective markov transition matrix를 이용한 풍속예측 및 MCP 모델과 비교)

  • Kang, Minsang;Son, Eunkuk;Lee, Jinjae;Kang, Seungjin
    • New & Renewable Energy
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    • v.18 no.1
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    • pp.17-28
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    • 2022
  • This paper presents an effective Markov transition matrix (EMTM), which will be used to calculate the wind speed at the target site in a wind farm to accurately predict wind energy production. The existing MTS prediction method using a Markov transition matrix (MTM) exhibits a limitation where significant prediction variations are observed owing to random selection errors and its bin width. The proposed method selects the effective states of the MTM and refines its bin width to reduce the error of random selection during a gap filling procedure in MTS. The EMTM reduces the level of variation in the repeated prediction of wind speed by using the coefficient of variations and range of variations. In a case study, MTS exhibited better performance than other MCP models when EMTM was applied to estimate a one-day wind speed, by using mean relative and root mean square errors.

A study on the exhaust gas recirculation in a MILD combustion furnace by using a Venturi nozzle (MILD 이용한 배기가스 재순환에 관한 연구)

  • Ha, Ji Soo;Shim, Sung Hoon
    • Journal of Energy Engineering
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    • v.22 no.4
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    • pp.413-419
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    • 2013
  • The present study used the MILD combustor, which has coaxial cylindrical tube. The outside tube of the MILD combustor corresponds to the exhaust gas passage and the inner side tube is the furnace passage. A numerical analysis was accomplished to elucidate the characteristics of exhaust gas entrainment toward the inner furnace with the changes of venturi nozzle geometrical parameters, nozzle position, nozzle gap between high pressure air nozzle and venturi nozzle, and with the change of high pressure nozzle inlet velocity. The entrainment flow rate for the case with the high pressure air nozzle attached at the exhaust gas wall has relatively small change with the change of nozzle gap. That for the case with the high pressure air nozzle exposed to the exhaust gas has monotonically increase with the change of nozzle gap. The flow rate ratio of entrainment flow rate has considerably increase tendency with relatively lower air inlet velocity, on the other hand, that with relatively higher air inlet velocity could be seen relatively small increase.

A Study on the Design of the Flywheel Energy Storage Device to Store the Regenerative Energy (회생에너지 저장용 플라이휠 에너지 저장 장치 설계에 관한 연구)

  • Lee, Jun-Ho;Park, Chan-Bae;Lee, Byeong-Song
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.62 no.7
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    • pp.1045-1052
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    • 2013
  • In this study we deal with design procedures for the flywheel energy storage system that has the capacity to store the regenerative energy produced from the railway vehicles. The flywheel energy storage system (FESS) stores the regenerative electrical energy into the high speed rotational flywheel, by conversion the electrical energy into the mechanical rotational energy. Thus the FESS is composed of the energy conversion components, such as the motor and generator, mechanical support components, such as the rotational rotor, the magnetic bearings to support the rotor, and the digital controller to control the air gap between the rotor and the magnetic bearings. In this paper the design procedures for the rotor operating at the rigid mode and the magnetic bearings to support the rotational rotor without contact are presented.