• Title/Summary/Keyword: energy composition

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Phase diagrams adn stable structures of stranski-krastanov structure mode for III-V ternary quantum dots

  • Nakajima, Kazuo;Ujihara, Toru;Miyashita, Satoru;Sazaki, Gen
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.4
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    • pp.387-395
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    • 1999
  • The strain, surface and interfacial energies of III-V ternary systems were calculated for three kinds of structure modes: the Frank-van der Merwe(FM) mode, the Stanski-Krastanov(SK) mode and the Volmer-Weber(VW) mode. The free energy for each mode was estimated as functions of thickness and composition or lattice misfit. Through comparison of the free energy of each mode, it was found that the thickness-composition phase diagrams of III-V ternary systems can be determined only by considering the balance of the free energy and three kinds of structure modes appear in the phase diagrams. The SK mode appears only when the lattice misfit is large and/or the lattice layer is thick. The most stable structure of the SK mode is a cluster with four lattice layers or minimum thickness on a wetting layer of increasing lattice layers. The VW mode appears when the lattice misfit is large and the lattice layer is thin and only in the INPSb/InP and GaPSb/GaP system which have the largest lattice misfit of III-V ternary systems. The stable region of the SK mode in the GaPSb/GaP and InPSb/InP phase diagrams is largest of all because the composition dependence of the strain energy of these systems is stronger than that of the other systems. The critical number of lattice layers below which two-dimensional(2D) layers precede the three-dimensional(3D) nucleation in the SK mode at x=1.0 depends on the lattice misfit.

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Study on Optical Properties and Phase Transition of $TlGa_xIn_{1-x}Se_2$ Solid Solutions ($TlGa_xIn_{1-x}Se_2$ Solid Solution의 광학적 특성 및 상전이에 관한 연구)

  • Yoon, Chang-Sun;Kim, Byong-Ho;Cha, Duk-Joon
    • Journal of the Korean Vacuum Society
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    • v.2 no.2
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    • pp.220-226
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    • 1993
  • An investigation was made of the dependences of the lattice constants and the energy gap on the composition of $TlGa_xIn_{1-x}Se_2$ single cystals grown by Bridgman method. It was found that a discontinuity in $TlGa_xIn_{1-x}Se_2$ solid solutions occurred in the composition range 0.25$0.0{\leq}X{\leq}0.25$) to the monoclinic structure ($0.65{\leq}X{\leq}1.0$) was observed in this composition range. The temperature dependences of the energy gap and the dielectric constant in $TlGaSe_2$ single crystal have shown that the anomalies appeared at 107 K and 120 K corresponding to first-order and second-order phase transitions, respectively.

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PARTITIONING RATIO OF DEPLETED URANIUM DURING A MELT DECONTAMINATION BY ARC MELTING

  • Min, Byeong-Yeon;Choi, Wang-Kyu;Oh, Won-Zin;Jung, Chong-Hun
    • Nuclear Engineering and Technology
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    • v.40 no.6
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    • pp.497-504
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    • 2008
  • In a study of the optimum operational condition for a melting decontamination, the effects of the basicity, slag type and slag composition on the distribution of depleted uranium were investigated for radioactively contaminated metallic wastes of iron-based metals such as stainless steel (SUS 304L) in a direct current graphite arc furnace. Most of the depleted uranium was easily moved into the slag from the radioactive metal waste. The partitioning ratio of the depleted uranium was influenced by the amount of added slag former and the slag basicity. The composition of the slag former used to capture contaminants such as depleted uranium during the melt decontamination process generally consists of silica ($SiO_2$), calcium oxide (CaO) and aluminum oxide ($Al_2O_3$). Furthermore, calcium fluoride ($CaF_2$), magnesium oxide (MgO), and ferric oxide ($Fe_2O_3$) were added to increase the slag fluidity and oxidative potential. The partitioning ratio of the depleted uranium was increased as the amount of slag former was increased. Up to 97% of the depleted uranium was captured between the ingot phase and the slag phase. The partitioning ratio of the uranium was considerably dependent on the basicity and composition of the slag. The optimum condition for the removal of the depleted uranium was a basicity level of about 1.5. The partitioning ratio of uranium was high, exceeding $5.5{\times}10^3$. The slag formers containing calcium fluoride ($CaF_2$) and a high amount of silica proved to be more effective for a melt decontamination of stainless steel wastes contaminated with depleted uranium.

Performance Comparison of Integrated Reactor with Steam Reforming and Catalytic Combustion using Anode Off-Gas for High Temperature Fuel Cells (고온용 연료전지 미반응 가스를 이용한 촉매연소-개질 통합 반응기의 성능 비교)

  • Ghang, Tae-Gyu;Sung, Hae-Jung;Lee, Sang-Min;Ahn, Kook-Young;Kim, Yong-Mo
    • Journal of Hydrogen and New Energy
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    • v.22 no.6
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    • pp.800-809
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    • 2011
  • The reaction characteristics of an integrated reactor with steam reformer and catalytic combustor using anode offgas for high temperature fuel cells such as MCFC and SOFC have been experimentally investigated in the present study. The coupled reactor had a coaxial cylindrical shape, and the inner and the outer tube was packed with combustion catalysts and reforming catalysts, respectively. Thus, the endothermic steam reforming could proceed by absorbing heat from catalytic combustion of anode offgas. Results show that increasing inlet temperature and decreasing excess air ratio increased the reformer temperature, which led to the increase in $H_2$ yield. The reforming performance for SOFC conditions was better than that for MCFC conditions since the composition of flammable components became smaller for MCFC cases. Measured reformate composition under various test conditions correlated well with thermal equilibrium composition.

Assessment of Physical Activity Pattern, Activity Coefficient, Basal Metabolic Rate and Daily Energy Expenditure in Female University Students (일부 여대생의 활동에너지 소비패턴, 활동계수, 기초대사량 및 에너지 소비량 평가)

  • Park, Yoonji;Kim, Jung Hee
    • Korean Journal of Community Nutrition
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    • v.18 no.1
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    • pp.45-54
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    • 2013
  • This study was conducted to investigate the physical activity pattern, activity coefficient, basal metabolic rate and energy expenditure of female university students. One-day activity diaries were collected from 95 female university students in Seoul. Body composition was measured by Inbody 720. Subjects spent 7 hr 8min on sleeping, 6 hr 31min on studying, 2 hr 50min on physiological activity, 2 hr 3min on leisure, 2 hr 2min on walking and jogging, 1 hr 58 min on commuting and 22min on house chores. The activity coefficient of these subjects was 1.58. The comparison of body composition of subjects according to PAL showed that body weight, body fat mass, arm circumference and arm muscle circumference of physically active group were significantly higher than those of the sedentary group. BMR calculated by Harris-Benedict (H-B) formula and DRI formula and BMR measured by Inbody 720 was 1375 kcal, 1306 kcal and 1209 kcal, respectively. Total energy expenditure (TEE) examined by one-day activity diaries and calculated by H-B formula and estimated energy requirement (EER) formula in DRI was 2102.1 kcal, 2184.4 kcal, and 2164.5 kcal, respectively. The Pearson correlation coefficient between TEE examined by one-day activity diaries and H-B TEE was 0.795 (p < 0.001) while that between TEE examined and DRI EER was 0.604 (p < 0.001). Overall data indicated that female university students seemed to be less active. Therefore it is recommended that universities develop good exercise programs for their students. Further studies are needed to generate more meaningful results with a larger sample size and using machine attached to the body, which are able to detect physical activity more accurately.

A Study on Nutrition Composition Labeling and Nutrition Claim Practices for the Processed Foods (시판 가공식품의 영양성분 및 영양강조 표시 실태에 대한 연구)

  • 오세인;장영애
    • Korean journal of food and cookery science
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    • v.20 no.1
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    • pp.100-111
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    • 2004
  • The purpose of this study was to investigate the status of current nutrition labeling on the packaging of the processed foods that provide consumers with a reliable and consistent source of information, which has been considered as a useful aid for food selection and a potent educational tool for nutrition in daily life. The 2,160 processed foods purchased at the supermarket on September, 2002, were divided by food category issued from the 2002 food codes and assessed in the terms of the nutrition composition labeling and nutrition claims. Nutrition composition labeling was found on 356 of the 2160 processed foods items. Milk and dairy products had 49.7% of nutrition composition labeling, which was the largest number among the food category. Tables were most frequently used as the type of nutrition composition labeling (79.8%). Nutrition composition including many different ways of expression, such as a table of nutrition composition, indication of nutrition composition, analysis table of nutrition composition and comparative table of nutrition composition, made frequent use of nutrition composition labeling titles (78.7%). The various unit of measures were use in the nutrition labeling of the processed foods, per l00g or 100$m\ell$ was the highest (44.6%) under the currently practiced nutrition labeling. The correct labeling standard with nutrient content and % RDA except energy, was used on 47.8% of labels, and those with only liability indication nutrient and liability indication nutrients plus discretion indication nutrients were 25.3 and 22.5% respectively. The processed foods with nutrition claims were 8.0% (172 items). Nutrition claims were divided in two ways: nutrient content claims and nutrient comparative claims. The most frequently used claims were contained in the former (44.4%) and more or plus in the latter case (16.3%). Ca was the most popular item as a nutrition claim nutrient (50.6%).

Variation in Energy and Nutrient Composition of Oilseed Meals from Different Countries (수입 박류사료내 에너지 및 영양소 함량의 변이)

  • Son, Ah Reum
    • Korean Journal of Poultry Science
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    • v.47 no.2
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    • pp.107-114
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    • 2020
  • This study was conducted to investigate the variation in nutrient composition of oilseed meals and to develop prediction equations for amino acid concentrations. Energy and nutrient contents were determined in a total of 1,380 feed ingredient samples including copra byproducts, corn distillers, dried grains with solubles, palm kernel byproducts, and soybean meal. The ingredient samples were imported to the Republic of Korea between 2006 and 2015. Data were analyzed using the MIXED procedure of SAS. The regression procedure of SAS was used to generate the prediction equation for the lysine concentration using the crude protein (CP) concentration as an independent variable. The concentrations of moisture, gross energy, CP, ether extract, crude fiber, ash, calcium, phosphorus, lysine, methionine, cysteine, and threonine in tested oilseed meals differed (P<0.05) depending on producing countries. The prediction equations for amino acid concentrations (% as-is basis) in the oilseed meals are: lysine = -1.08 + 0.080 × CP (root mean square error = 0.244, R2 = 0.924, and P<0.001); threonine = -0.297 + 0.044 × CP (root mean square error = 0.099, R2 = 0.958, and P<0.001). In conclusion, energy and nutrient compositions vary in the oilseed meals depending on the producing countries. Moreover, the crude protein concentration can be used as a suitable independent variable for estimating lysine and threonine concentrations in the oilseed meals.

A Study on the Thermal Performance Analysis of Curtain Wall Office Building Considering the Thermal Bridges (열교부위를 고려한 커튼월 사무소 건물의 열성능 해석에 관한 연구)

  • Shin, U-Cheul;Kim, Seung-Chul;Yoon, Jong-Ho
    • Journal of the Korean Solar Energy Society
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    • v.31 no.3
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    • pp.95-100
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    • 2011
  • Currently, office buildings in Korea tend to adopt as their outer wall the curtain wall structure which can be easily constructed and has beautiful external appearance as well. However, the problem is that the curtain wall structure does not have a uniform composition unlike the wall of existing reinforced concrete structures and has a frame made of metal with high heat conduction. Therefore, it is expected that the structure will be highly influenced by the thermal bridge. Thereupon, this study analyzes how to set up the composition of the wall system and heat transmission rate in consideration of the thermal characteristics of the curtain wall structure and applies it in practice by simulation in order to propose a guideline for the energy simulation method of the curtain wall structure and analyze its differences from existing simulation methods.

Design of Metal Cored Wire for Erosion Resistant Overlay Welding

  • Kim, Jun-Ki;Kim, In-Ju;Kim, Ki-Nam;Kim, Ji-Hui;Kim, Seon-Jin
    • Proceedings of the KWS Conference
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    • 2009.11a
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    • pp.202-204
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    • 2009
  • Erosion is a common failure mode of materials frequently encountered in plant and power industry. Although the erosion resistance of Fe-base alloy has been inferior to the other expensive materials, it is expected that the strain-induced martensitic transformation can impart high erosion resistance to Fe-base alloy. The key technology to develop Fe-base metal cored welding wire for erosion resistant overlay welding may include the strain-induced metallurgy for hardening rate control and the welding flux metallurgy for dilution control. Sophisticated studies showed that the strain-induced martensitic transformation behavior was related to the critical strain energy which was dependent on the alloy composition. Dilution and bead shape of overlay weld were proved to be affected by metal transfer mode during gas tungsten arc welding and elements in welding fluxes. It was considered that the highly erosion resistant Fe-base overlay weld could be achieved by precise control of alloy composition to have proper level of critical strain energy for energy absorption and welding flux formulation to have small amount of deoxidizing metallic elements for dilution.

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Thermogravimetric Analysis of Rice Husk Flour for a New Raw Material of Lignocellulosic Fiber-Thermoplastic Polymer Composites

  • Kim, Hyun-Joong;Eom, Young-Guen
    • Journal of the Korean Wood Science and Technology
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    • v.29 no.3
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    • pp.59-67
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    • 2001
  • Rice husk flours were analyzed by chemical composition and thermogravimetric methods in nitrogen atmosphere to discuss its feasibility as a raw material for manufacturing agricultural lignocellulosic fiber-thermoplastic polymer composite. It was revealed in the chemical composition analysis that rice husk flour was composed of moisture, 5.0%; lignin, 21.6%; holocellulose, 60.8%; ash, 12.6%. In the thermogravimetric analysis (TGA), thermal decomposition behavior of rice husk flour from room temperature to $350^{\circ}C$ was similar to that of wood flour, but rice husk flour was more thermally stable from 350 to $800^{\circ}C$ than wood flour because of higher silica content in the rice husk flour and smaller particle size of rice husk flour. The activation energy of thermal decomposition was evaluated using Flynn & Wall expression. As the thermal decomposition proceeded in rice husk flour, the activation energy of thermal decomposition appeared almost constant up to ${\alpha}=0.25$, but thereafter increased. Activation energy of thermal decomposition in wood flour, however, decreased steeply up to ${\alpha}=0.3$, but thereafter remained almost constant. From the results, rice husk flour was thought be a substitute for wood flour in manufacturing agricultural lignocellulosic fiber-thermoplastic polymer composite in the aspect of thermal decomposition.

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