• Title/Summary/Keyword: emulsion method

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Decontaminatin Techniques using Liquid/Supercritical $CO_2$ (액체 및 초임계 이산화탄소를 이용한 제염법)

  • 박광헌;김홍두;김학원;고문성;윤청현
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2003.11a
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    • pp.650-654
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    • 2003
  • A major problem of nuclear energy is the production of radioactive wastes. Needs for more environmentally favorable method to decontaminate radioactive contaminants make the use of liqui $d^ercritical $CO_2$ as a solvent medium. In removing radioactive metallic contaminants under $CO_2$ solvent, two methods - use of chelating ligands and that of water in $CO_2$ emulsion-are possible. In the chelating ligand method, a combination of ligands that can make synergistic effects seems important. We discuss about the properties of microemulsion formed by F-AOT and that by non-ionic surfactant. By adding acid in water core, decontamination of metallic parts, soils were possible. The rate of metal surface dissolution to the microemulsion solution was measured by QCM. The possibility of recovering the surfactants after use is also mentioned.ed.

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Thickness Control of Core Shell type Nano CoFe2O4@SiO2 Structure (두께 조절이 가능한 코어셸 형태의 SiO2 coated CoFe2O4 구조)

  • Yu, Ri;Kim, Yoo-Jin;Pee, Jae-Hwan;Kim, Kyung-Ja
    • Journal of Powder Materials
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    • v.17 no.3
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    • pp.230-234
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    • 2010
  • Homogenous silica-coated $CoFe_2O_4$ samples with controlled silica thickness were synthesized by the reverse microemulsion method. First, 7 nm size cobalt ferrite nanoparticles were prepared by thermal decomposition methods. Hydrophobic cobalt ferrites were coated with controlled $SiO_2$ using polyoxyethylene(5)nonylphenylether (Igepal) as a surfactant, $NH_4OH$ and tetraethyl orthosilicate (TEOS). The well controlled thickness of the silica shell was found to depend on the reaction time and the amount of surfactant used during production. Thick shell was prepared by increasing reaction time and small amount of surfactant.

The Variation of Offset Ink Properties According to Methyl Ester of Soy Oil and Resin Molecular Weight (대두유의 Methyl Ester와 수지 분자량에 따른 평판 잉크의 물성 변화에 관한 연구)

  • Park, Jung-Min;Kim, Sung-Bin
    • Journal of the Korean Graphic Arts Communication Society
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    • v.29 no.1
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    • pp.45-59
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    • 2011
  • According as gradually increasing the demand for Eco-friendly products it has been progressed fairly development at a field of printing and printing inks. The Inks are used by soy oil beginning of ink industry for preventing environment. Now it is possible to make Eco-friendly inks with vegetable ester. So it is not necessary to use petroleum-based solvents for preventing environment. But There is some problems if using vegetable ester to inks. Vegetable ester has high solubility, it causes misting and low viscosity of the Inks. So resin is required high performance. Thus, in this paper, I studied about the properties variation of the Varnish and inks According to using the phenolic modified rosin ester and Soy oil Methyl esters. The compared in order of average molecular weight by the GPC method, rheological properties were found by rotational rheometer, and emulsion behavior were compared by high speed emulsification tester.

Heat transfer coefficients for F.E analysis in warm forging processes (온간 단조 공정에서의 열전달 계수)

  • Kang J. H.;Ko B. H.;Jae J. S.;Kang S. S.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2005.05a
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    • pp.138-143
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    • 2005
  • Finite Element analysis is widely applied to elevated temperature forging processes and shows a lot of information of plastic deformation such as strain, stress, defects, damages and temperature distributions. In highly elevated temperature deformation processes, temperature of material and tool have significant influence on tool life, deformation conditions and productivities. To predict temperature related properties accurately, adequate coefficients of not only contact heat transfer between material and dies but also convection heat transfer due to coolants are required. In most F.E analysis, too higher value of contact heat transfer coefficient is usually applied to get acceptable temperature distribution of tool. For contact heat transfer coefficients between die and workpiece, accurate values were evaluated with different pressure and lubricants conditions. But convection heat transfer coefficients have not been investigated for forging lubricants. In this research, convection heat transfer coefficients for cooling by emulsion lubricants are suggested by experiment and Inverse method. To verify acquired convection and contact heat transfer coefficients, tool temperature was measured for the comparison between measured tool temperature and analysis results. To increase analysis accuracy, repeated analysis scheme was applied till temperature of the tool got to be in the steady-state conditions. Verification of heat transfer coefficients both contact and convection heat transfer coefficients was proven with good accordance between measurement and analysis.

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SPF Measurement and Cytotoxicity of Sunscreen Agents in Cosmetic (화장품에서 UV 차단제의 피부 자극성과 SPF 측정)

  • Kim, In-Young;Kang, Sam-Woo
    • Analytical Science and Technology
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    • v.11 no.2
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    • pp.79-87
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    • 1998
  • Consumers have recently preferred to purchase extensive UV intercepting products, which are waterproof and free from side effects on skin. During the testing of cytotoxicity (in-vitro) in neutral red (NR) method, cell survival ratio of UV-B interceptors decreased to just above 0.08 w/v%, and it was observed that the UV-A interceptors the ratio also decreased to just above 0.06 w/v%. In addition patch-tests of inorganic UV interceptors resulted in no skin irritation even below 10.0 and 11.25. In absorption curves, UV-B was most suitable for octyl methoxycinnamate (OMC) and UV-A for butyl methoxy dibenzoylmethane (BMDM). For this reason, $Nylonpoly^{TM}$ UVA/UVB the material of OMC and BMDM coated with Nylon & polyethylene, was used as the organic UV interceptor. Zinc oxide (ZnO) and titanium dioxide ($TiO_2$) was used as inorganic UV interceptors. The appropriate mixture ratio of ZnO and $TiO_2$ was 6 to 4:6% of ZnO, 4% of $TiO_2$ and 5% of $Nylonpoly^{TM}$ UVA/UVB were all combined and added to our sunscreen cream. The SPF value of in-vitro was 38.9. In practical application, each sun protection factor (SPF) duration of oil-in-water (O/W) emulsion and water-in-silicone (W/S) emulsion containing sunscreen cream of the same content showed that W/S type of sunscreen cream was 5 times as durable as the other. Therefore, this product is fit for use in swimming, climbing or skiing. This research is to minimize skin trouble caused by UV interceptors and to make one with proper softness, skin safety and UV intercepting efficiency.

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Analysis of Air Void Systems in Latex-Modified Concretes with Cement Types (시멘트 종류에 따른 라텍스개질 콘크리트의 미세공극 구조 분석)

  • Yun, Kyong-Ku;Jeong, Won-Kyong;Kim, Ki-Heun;Kim, Kyong-Jin
    • International Journal of Highway Engineering
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    • v.7 no.1 s.23
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    • pp.73-82
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    • 2005
  • Linear traverse method and point count method described at ASTM have been widely used to estimate the air void system in hardened concrete. These methods, however, are rarely used at present, because they require many efforts and time consuming works. Also these results depend on each person's decision, and are not repeatable. Thus, new image analysis method using microscope and computer processes has been approached for analyzing air void system in hardened concrete. The purpose of this study was to analysis the air void systems in latex-modified concretes using a reasonable and objective image analysis method with main experimental variables such as cement types(ordinary portland cement, rapid setting cement) and latex contents(0%,15%). In the results of this study, the use of polymer latex showed that it could be attributed to its air void systems, due to the fact that the latex emulsion acts as an air-entraining agent, which thus generally guarantees an adequate air-void system.

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A Simple Method for Measuring the Immobilization Solids of Coating Colors Using an AA-CWR Water Retention Meter

  • Park, Chang-hak;Lee, Do-Ik;Margaret K. Joyce
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.34 no.5
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    • pp.39-48
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    • 2002
  • The water retention of coating colors can be accurately measured by devices such as an AA-GWR water retention meter whose principle of measurement Is based on pressure filtration of coatings under an externally applied air pressure over a certain period of time. It was hypothesized that such devices could be also used to determine the immobilization solids (IMS) of coating colors by determining a sudden drop in the rate of dewatering, that is, a sudden change in the drainage curves. To test this hypothesis, the immobilization solids of coating colors containing various thickeners and water retention additives at different levels were first accurately measured by a modified immobilization tester based on the well-known gloss drop method, and then their values were compared with those obtained by an AA-GWR water retention tester. They agreed very well and showed that the standard deviation is only 0.14% in the IMS points between both methods. This good agreement was not surprising because both test methods are based on the same end-point, that is, the immobilization solids point at which menisci begin to form at the coating surface. Theoretical considerations supporting this new method for measuring the immobilization solids of coating colors are presented and some recommendations for the test method are discussed. Also, the effect of various thickeners and water retention additives on the properties and printability of coated papers is discussed.

Gly-His-Lys Conjugated Chitosan and its Cell Proliferation Effects (Gly-His-Lys 펩타이드가 결합된 키토산과 그의 세포증식 효과에 관한 연구)

  • Ha Byung-Jo;Lee Yoon-Sik;Park Soo Nam
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.30 no.3 s.47
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    • pp.399-404
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    • 2004
  • Novel GHK-conjugated chitosan was prepared by the solid-phase method using $N^{\alpha}-Fmoc$ amino acids/BOP coupling reagent. For this purpose, the chitosan microbeads which had a mean diameter of 70 um were prepared by the W/O emulsion-phase separation method. The GHK was successfully coupled to the chitosan microbeads by stepwise solid-phase method. The result of amino aid analysis was in good agreement with the theoretical values; $Gly_{1.02}\;of\;His_{1.13}\;Lys_{0.96).$. The cell proliferation effect of the GHK-bound chitosan microbeads was measured by MTT assay. We concluded that GHK-bound chitosan microbeads gave higher cell Proliferation effect than chitosan microbeads.

Stability of W/O Nanoemulsions with Low Viscosity Prepared by PIC Method (PIC 방법으로 제조된 저점도 W/O 나노에멀젼의 안정성)

  • Cho, Wan Goo
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.42 no.2
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    • pp.127-133
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    • 2016
  • In this study, water-in-oil (W/O) nanoemulsions of water/Span 80-Nikkol BL 25/oil system were prepared by the PIC method at elevated temperature. This method allows the formation of finely dispersed W/O nanoemulsions with low viscosity in this system. However, macroemulsions rather than nanoemulsions were prepared by PIC method at room temperature. As a result of the significant change of interfacial tension with temperature, the emulsion droplet size decreases from $2{\mu}m$ to 100 nm with the increase in temperature from $30^{\circ}C$ to $80^{\circ}C$. The droplet size of nanoemulsions prepared at $80^{\circ}C$ was in the range of 50 ~ 200 nm and the internal phase content could reach as high as 15 wt%. The most stable nanoemulsion was formed in the vicinity of 7.0 of optimum HLB of the emulsifier mixture. The obtained nanoemulsions were stable without obvious change in droplet size in one month. This study provides valuable information for optimizing the formation of W/O nanoemulsions with low viscosity. These results suggest that W/O nanoemulsions of low viscosity could be useful for cosmetics with soft feeling.

CFD Analysis on Flow Characteristics of Oil Film Coating Nozzle (유막 코팅 노즐의 유동특성에 관한 CFD해석)

  • Jung, Se-Hoon;Ahn, Seuig-Ill;Shin, Byeong-Rog
    • The KSFM Journal of Fluid Machinery
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    • v.11 no.5
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    • pp.50-56
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    • 2008
  • Metal cutting operations involve generation of heat due to friction between the tool and the pieces. This heat needs to be carried away otherwise it creates white spots. To reduce this abnormal heat cutting fluid is used. Cutting fluid also has an important role in the lubrication of the cutting edges of machine tools and the pieces they are shaping, and in sluicing away the resulting swarf. As a cutting fluid, water is a great conductor of heat but is not stable at high temperatures, so to improve stability an emulsion type mixed fluid with water and oil is often used. It is pumped over the cutting site of cutting machines as a state of atomized water droplet coated with oil by using jet. In this paper, to develop cutting fluid supplying nozzle to obtain ultra thin oil film for coating water droplet, a numerical analysis of three dimensional mixed fluid Jet through multi-stage nozzle was carried out by using a finite volume method. Jet flow characteristics such as nozzle exit velocity, development of mixing region, re-entrance and jet intensity were analyzed. Detailed mixing process of fluids such as air, water and oil in the nozzle were also investigated. It is easy to understand complex flow pattern in multi-stage nozzle. Important flow Information for advance design of cutting fluid supplying nozzle was drawn.