• Title/Summary/Keyword: emitting layer

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Polymer Light-Emitting Diodes Based on Poly(3-hexyl thiophene)

  • Chang, Seoul;Kim, Nam-Hee
    • Fibers and Polymers
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    • v.1 no.1
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    • pp.25-31
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    • 2000
  • Poly(3-hexyl thiophene)(P3HT) and poly(3-dodecyl thiophene)(P3DT) were polymerized by oxidative coupling with ferric chloride. The P3HT light-emitting device emitted red light and it could be observable in the ordinary indoor light. The device had the turn-on electric field of about 3$\times$$10^7$ V/m. The maximum electroluminescene (EL) intensity was obtained when the thickness of polymer layer was about 130 nm in IT0/P3HT/Al device. The maximum external quantum yield was 0.002%. The maximum luminance was 21 cd/$m^2$. The EL intensity decreases with increasing the crystallinity of the polymer layer. By using the oriented poly(3-alkyl thiophene)(PAT) layer as an electroluminescent layer in the ITO/polymer/Al light-emitting devices, the polarized EL light emission was observed. The EL intensity ratio of parallel to perpendicular direction to the stretch direction for P3HT was about 1.40.

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Highly Efficient Green Phosphorescent Organic Light Emitting Diodes

  • Lee, Se-Hyung;Park, Hyung-Dol;Kang, Jae-Wook;Kim, Hyong-Jun;Kim, Jang-Joo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.496-498
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    • 2008
  • We have developed green phosphorescent organic light-emitting diodes (OLEDs) with high quantum efficiency. Wide-energy-gap material, 1,1-bis[(di-4-tolylamino) phenyl]cyclohexane (TAPC), with high triplet energy level was used as a hole transporting layer. Electrophosphorescent devices fabricated using TAPC as a hole-transporting layer and N,N'-dicarbazolyl-4,4'-biphenyl (CBP) doped with fac-tris(2-phenylpyridine) iridium [Ir(ppy)3] as the emitting layer showed the maximum external quantum efficiency ($\eta_{ext}$) of 19.8 %, which is much higher than the devices adopting 4,4'-bis[N-(1-naphthyl)-N-phenyl-amino]biphenyl (NPB) (${\eta}B_{ext}=14.6%$) as a hole transporting layer.

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Self-organized gradient hole injection to improve the performance of organic light-emitting diodes

  • Lee, Tae-Woo;Chung, Young-Su;Kwon, O-Hyun;Park, Jong-Jin;Chang, Seoung-Wook;Kim, Mu-Hyun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1813-1818
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    • 2006
  • We demonstrate a new approach to form gradient hole injection layer (HIL) in organic light-emitting diodes (OLEDs). Single spincoating of hole-injecting conducting polymer compositions with a perfluorinated ionomer results in gradient workfunction through the layer by self-organization, which lead to remarkably efficient single layer polymer light-emitting diodes (PLEDs) (${\sim}21$ cd/A). The device lifetime was significantly improved (${\sim50$ times) compared with the conventional hole injection layer, poly(3,4-ethylenedioxy-thiophene)/polystyrene sulfonate. This solution processed HIL also produced dramatically enhanced luminous efficiency (${\sim}34$ cd/A) in vacuum- deposited green fluorescent OLEDs while the vacuum deposited HIL gave the luminous efficiency of ${\sim}23$ cd/A in the same device structure.

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Electrical and Optical Properties of Organic Light Emitting Devices Using Blue Fluorescent and Orange Phosphorescent Materials (청색형광재료와 황색인광 재료를 이용한 OLEDs의 전기 및 광학적 특성)

  • Seo, Yu-Seok;Moon, Dae-Gyu
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.155-155
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    • 2010
  • We have investigated organic light-emitting devices by doping phosphorescent orange and fluorescent blue emitters into the separate layers of single host. The electroluminescence spectra and current efficiency were strongly dependent on the location of each doped layers. The luminance-voltage (L-V) characteristics of the device2 (ITO/Hole Transport Layer/Orange Phosphorescent emissive layer/Blue Fluorescent emissive layer/Electron Transport Layer/liF/Al) showed the maximum current efficiency of 19.5 cd/A.

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Effects of Electron Transport Layers on Electrical and Optical Characteristics of Blue Phosphorescent Organic Light Emitting Diodes (전자수송층이 청색 인광 OLED의 전기 및 광학적 특성에 미치는 영향)

  • Suh, Won-Gyu;Moon, Dae-Gyu
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.4
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    • pp.323-326
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    • 2009
  • We have developed blue-emitting phosphorescent organic light emitting diodes (OLEDs) using 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline (BCP) and tris (8-quinolinolato)aluminum ($Alq_3$) electron transport layers. As blue dopant and host materials, bis[(4,6-di-fluorophenyl)-pyridinate-N,C2']picolinate (FIrpic) and N,N'-dicarbazolyl-3,5-benzene (mCP) were used, respectively. The driving voltage, current efficiency and emission characteristics of devices were investigated. While the driving voltage was about $1{\sim}2$ V lower in the device with an $Alq_3$ layer, the current efficiency was about 66 % higher in the device with BCP electron transport layer. the blue phosphorescent OLED with BCP layer exhibited higher purity of color, resulting from a relatively weak electroluminescence intensity at 500 nm.

Improved Efficiency and Lifetime for Organic Light-emitting Devices based on Mixed-hole Transporting Layer (혼합된 정공 수송 층을 이용한 유기발광소자의 효율 및 수명 개선)

  • Seo, Jl-Hyun;Park, Jung-Hyun;Park, Il-Hong;Kim, Jun-Ho;Kim, Young-Kwan
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.3
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    • pp.257-262
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    • 2007
  • Organic light-emitting diodes (OLEDs) with the high efficieney and long lifetime are of growing interest in next-generation displays. Among the factors influencing OLEDs properties, one of unstable factor is $Alq_3$ cationic species caused by the excess holes resided in $Alq_3$ layer. Therefore, we suppressed the accumulation of excess holes by using the mixed-hole transporting layer (MHTL) of NPB and CBP in multilayer green OLEDs. The devices with MHTL showed improved characteristics in the luminous efficiency and lifetime. More characteristics and the carrier transport mechanism will be discussed.

Transparent Conducting Zinc-Tin-Oxide Layer for Application to Blue Light Emitting-diode

  • Kim, Do-Hyeon;Kim, Gi-Yong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.346.2-346.2
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    • 2014
  • To use the GaN based light-emitting diodes (LEDs) as solid state lighting sources, the improvement of light extraction and internal quantum efficiency is essential factors for high brightness LEDs. In this study, we suggested the new materials system of a zinc tin oxide (ZTO) layer formed on blue LED epi-structures to improve the light extraction. ZTO is a representative n-type oxide material consisted of ZnO and SnO system. Moreover, ZTO is one of the promising oxide semiconductor material. Even though ZTO has higher chemical stability than IGZO owing to its SnO2 content this has high mobility and high reliability. After formation of ZTO layer on p-GaN layer by using the spin coating method, structural and optical properties are investigated. The x-ray diffraction (XRD) measurement results show the successful formation of ZTO. The photoluminescence (PL) and absorption spectrum shows that it has 3.6-4.1eV band gap. Finally, the light extraction properties of ZTO/LED chip using electroluminescence (EL) measurement were investigated. The experimental and theoretical analyses were simultaneously conducted.

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Effects of PEDOT:PSS Buffer Layer in a Device Structure of ITO/PEDOT:PSS/TPD/Alq3/Cathode

  • Ahn, Joon-Ho;Lee, Joon-Ung
    • Transactions on Electrical and Electronic Materials
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    • v.6 no.1
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    • pp.25-28
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    • 2005
  • We have investigated the effects of hole-injection buffer layer in organic light-emitting diodes using poly(3,4-ethylenedioxythiophene):poly(stylenesulfonate)(PEDOT:PSS) in a device structure of $ITO/PEDOT:PSS/TPD/Alq_{3}/cathode$. Polymer PEDOT:PSS buffer layer was made by spin casting method. Current-voltage, luminance-voltage characteristics and efficiency of device were measured at room temperature with a variation of cathode materials; Al, LiF/Al, LiAl, and Ca/Al. The device with LiF/Al cathode shows an improvement of external quantum efficiency approximately by a factor of ten compared to that of Al cathode only device. Our observation shows that cathode is important in improving the efficiency of the organic light-emitting diodes.

Influence of green phosphorescent organic light-emitting devices of host by hole transport layer

  • Yoon, Do-Yeol;Lee, Chan-Jae;Moon, Dae-Gyu;Lee, Jeong-No
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.814-816
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    • 2009
  • We have investigated the effect of host on the device charactistics of green phosphorescent organic light emitting devices consising of mCP, CBP and TPBi. Electrons were confined within the device by inserting hole transport layer between the electro transport and the emitting layer. When the appropriate interlayers were added, the device with TPBI host layer performances were found to be dramatically enhanced, with current efficiency and lifetime of 18cd/A and 18hour.

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Improved Efficiency and Lifetime for Organic Light-Emitting Devices Based on Mixed-Hole Transporting Layer (혼합된 정공 수송 층을 이용한 유기발광소자의 효율 및 수명 개선)

  • Seo, Ji-Hyun;Park, Jung-Hyun;Kim, Jun-Ho;Kim, Young-Kwan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.67-68
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    • 2006
  • Organic light-emitting devices (OLEDs) with the high efficiency and long lifetime are of growing interest in next-generation displays. Among the factors influencing OLEDs properties, one of unstable factor is $Alq_3$ cationic species caused by the excess holes resided in $Alq_3$ layer. Therefore, we suppressed the accumulation of excess holes by using the mixed-hole transporting layer (MHTL) of NPB and CBP in multilayer green OLEDs. The devices with MHTL showed improved characteristics in the luminance efficiency and lifetime. More characteristics and the carrier transport mechanism will be discussed.

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