• Title/Summary/Keyword: emission line spectrum

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Production and Process Monitoring of 5-Aminolevulinic Acid (ALA) by Recombinant E. coli II. process Monitoring by a 2-Dimensional Fluorescence Sensor (유전자 재조합 대장균에 의만 5-Aminolevulinic Acid (ALA)의 생산 및 공정 모니터링 II. 2차원 형광센서에 의안 공정 모니터링)

  • 이종일;정상윤;임용식;정상욱
    • KSBB Journal
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    • v.19 no.1
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    • pp.27-32
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    • 2004
  • 2-Dimensional fluorescence sensor has a wide range of excitation and emission wavelengths, that some biogenic fluorphors in a biological process can be monitored simultaneously. The production processes of 5-aminolevulinic aicd (ALA) by recombinant E. coli BL21 (DE3) pLysS harboring plasmid pFLS45 were on-line monitored by a 2-dimensional fluorescence sensor The characteristics of fluorescence spectrum was dependent upon physical and biological factors of a bioprocess such as culture pH, cell mass etc. Some off-line data were correlated to the fluorescence intensity well, which was monitored at some combination of excitation and emission wavelengths by the 2-dimensional fluorescence sensor.

Validation Study for Image Performance of I-131 Using GATE Simulation Program (GATE 시뮬레이션 프로그램을 이용한 I-131의 영상 특성의 타당성에 관한 연구)

  • Baek, Cheol-Ha;Kim, Dae Ho;Lee, Yong-Gu;Lee, Youngjin
    • Journal of the Institute of Electronics and Information Engineers
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    • v.54 no.5
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    • pp.133-137
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    • 2017
  • The purpose of this study was to validate for GATE (Geant4 Application for Tomographic Emission) simulation by comparing the results of GATE simulation and experiment in real SPECT system. Futhermore, we want to prove that it is possible that the quantitative research of gamma camera/SPECT imaging for therapeutic radio isotope by using GATE simulation. In this study, the SPECT system on simulation referred to the parameters of Stream-R Forte version 1.2 (Philips Medical System, Best and Heerlen, Netherlands). To understand the I-131 image of gamma camera/SPECT system, we acquired the energy spectrum and measured the full width at half maximum (FWHM) which comes from line spread function (LSF) with and without scatter material in real SPECT system. And to compare with experiment, we also measured the FWHM and acquired the energy spectrum without scatter material in GATE simulation. As a result, without scatter material, the energy peak was almost same location, which are located nearby 364 keV, and other spectrum factors are same tendency in both cases. The FWHM was increased by increasing the distance of source to detector, and the error rate was approximately 3.8%. When we used the line source with scatter material, energy spectrum also indicated similar tendency in both cases. As you confirmed earlier, GATE simulation included real instrument and radioisotope characters for therapeutic radioisotope. Therefore this result that it was possible that various quantitative study for therapeutic radioisotope imaging in gamma camera/SPECT using GATE simulation.

Synthesis and Luminescence Properties of Tb3+-Doped K2BaW2O8 Phosphors (Tb3+ 이온이 첨가된 K2BaW2O8 형광체의 합성 및 형광특성)

  • Jang, Kyoung-Hyuk;Koo, Jae-Heung;Seo, Hyo-Jin
    • Korean Journal of Materials Research
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    • v.22 no.9
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    • pp.489-493
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    • 2012
  • Green phosphors $K_2BaW_2O_8:Tb^{3+}$(1.0 mol%) were synthesized by solid state reaction method. Differential thermal analysis was applied to trace the reaction processes. Three endothermic values of 95, 706, and $1055^{\circ}C$ correspond to the loss of absorbed water, the release of carbon dioxide, and the beginning of the melting point, respectively. The phase purity of the powders was examined using powder X-ray diffraction(XRD). Two strong excitation bands in the wavelength region of 200-310 nm were found to be due to the ${WO_4}^{2-}$ exciton transition and the 4f-5d transition of $Tb^{3+}$ in $K_2BaW_2O_8$. The excitation spectrum presents several lines in the range of 310-380 nm; these are assigned to the 4f-4f transitions of the $Tb^{3+}$ ion. The strong emission line at around 550 nm, due to the $^5D_4{\rightarrow}^7F_5$ transition, is observed together with weak lines of the $^5D_4{\rightarrow}^7F_J$(J = 3, 4, and 6) transitions. A broad emission band peaking at 530 nm is observed at 10 K, while it disappears at room temperature. The decay times of $Tb^{3+}$ $^5D_4{\rightarrow}^7F_5$ emission are estimated to be 4.8 and 1.4 ms, respectively, at 10 and 295 K; those of the ${WO_4}^{2-}$ exciton emissions are 22 and 0.92 ${\mu}s$ at 10 and 200 K, respectively.

Growth and photoluminescence properties of Er : Mg : LiNbO$_3$single crystal fibers by $\mu$-PD method ($\mu$-PD법에 의한 Er : Mg : LiNbO$_3$fiber 결정 성장 및 형광특성)

  • 양우석;윤대호
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.10 no.6
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    • pp.389-393
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    • 2000
  • High-quality $Er^{3+}$ doped Mg : $LiNbO_3$single crystal fibers were grown by a micro-pulling down ($\mu$-PD) method. Single crystal fibers were pulled down through the nozzle, at a pulling down rate of 0.5 mm/min and using a Pt crucible with a nozzle 1 mm in diameter in air atmosphere. Defects such as bubbles, cracks and inclusions were not detected in any of the grown crystals. The optical transmission of Er : Mg : $LiNbO_3$crystal was measured and the energy levels of $Er_2O_3$ ion could be calculated. The photoluminescence spectrum of crystal fibers showed an energy band emission with the strongest line corresponding to the $^4I_{3/2}{\to}^4I_{15/2}$transition. The concentration dependence of the entire wavelength region emission intensity upon excitation intensity measured emission intensity for the 3 mol% MgO doped fibers was larger than that for the 1, 5 mol% MgO doped fibers.

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Ho3+-Doped Amorphous Dielectrics:Emission and Excitation Spectra of the 1.6 μm Fluorescence (Ho3+ 첨가 비정질 유전체 : 1.6μm 헝광의 방출 및 여기 스펙트럼)

  • 최용규
    • Journal of the Korean Ceramic Society
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    • v.41 no.8
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    • pp.618-622
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    • 2004
  • Excitation spectra of the 1.6 rm emission originating from $Ho^{3+}$$^{5}$ I$_{5}$ \longrightarrow$^{5}$ I$_{7}$ transition in fluoride, sulfide, and selenide glasses were measured at wavelengths around 900nm where the fluorescing $^{5}$ I$_{5}$ level is located. In specific energy range where the frequency upconversion populating $^{5}$ F$_{1}$ state happens, the excitation efficiency of the 1.6 fm emission was deteriorated in fluoride and sulfide hosts. In selenide however spectral line shapes of the excitation spectrum and the '$^{5}$ I$_{8}$ \longrightarrow$^{5}$ I$_{5}$ absorption spectrum looked seemingly identical to each other. Differences in optical nonlinearity as well as electronic band gap energy of the host glasses used are responsible for the experimental observations. On the other hand, codoping of rare earths such as Tb$^{3+}$, Dy$^{3+}$, Eu$^{3+}$, and Nd$^{3+}$ was effective in decreasint the terminating $^{5}$ I$_{7}$ level lifetime. However, at the same time, some of the codopants increased unnecessary absorption at the 1.6 $\mu$m wavelengths via their ground state absorption. Though the lifetime quenching effect of Eu$^{3+}$ was moderate, it exhibited no additional extrinsic absorption at the 1.6 $\mu$m band.EX>m band.

Emission spectroscopic diagnostics of argon arc Plasma in Plasma focus device for advanced lithography light source (차세대 리소그래피 빛샘 발생을 위한 플라스마 집속장치의 아르곤 아크 플라스마의 방출 스펙트럼 진단)

  • Hong, Y.J.;Moon, M.W.;Lee, S.B.;Oh, P.Y.;Song, K.B.;Hong, B.H.;Seo, Y.H.;Yi, W.J.;Shin, H.M.;Choi, E.H.
    • Journal of the Korean Vacuum Society
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    • v.15 no.6
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    • pp.581-586
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    • 2006
  • We have generated the argon plasma in the diode chamber based on the established coaxial electrode type and investigated the emitted visible light for emission spectroscopy. We applied various voltages $2\sim3.5kV$ to the device by 0.5kV, and obtained the emission spectrum data for the focused plasma in the diode chamber on the argon pressure of 330 mTorr. The Ar I and Ar II emission line are observed. The electron temperature and ion density have been measured by the Boltzmann plot and Saha equation from assumption of local thermodynamic equilibrium (LTE) The Ar I and Ar II ion densities have been calculated to be $\sim10^{15}/cc\;and\;~10^{13}/cc$, respectively, from Saha equation.

Electronic Structure and Chemical Reactivity of Transition Metal Complexes (Part 16). A Spectroscopic Study on the Electronic Structure of cis-[Cr(cyclam)$Cl_2$]Cl (전이금속 착물의 전자 구조 및 화학적 반응성 (제 16 보). cis-[Cr(cyclam)$Cl_2$]Cl의 전자 구조에 관한 분광학적 연구)

  • Choi, Jong-Ha
    • Journal of the Korean Chemical Society
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    • v.39 no.7
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    • pp.501-507
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    • 1995
  • The electronic structure of cis-$[Cr(cyclam)Cl_2]Cl$ has been investigated by the emission and excitation spectroscopy at 77K, and infrared and visible spectroscopy at room temperature. The ten electronic transitions due to spin-allowed and spin-forbidden are assigned. The zero-phonon line in the excitation spectrum splits into two components by $139\;cm^{-1}$, and it can be reproduced by modern ligand field theory. According to the results of ligand field analysis, we can confirm that nitrogen atoms of the cyclam ligand have a strong ${\sigma}$-donor character, but chloride ligand has weak ${\sigma}-$ and ${\pi}-$donor properties toward chromium(III) ion.

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Intrinsic alignments of emission line galaxies at z ~1.4 from the FastSound redshift survey

  • Tonegawa, Motonari;Okumura, Teppei;Totani, Tomonori;Dalton, Gavin;Yabe, Kiyoto
    • The Bulletin of The Korean Astronomical Society
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    • v.42 no.2
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    • pp.54.1-54.1
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    • 2017
  • Intrinsic alignments (IA), the coherent alignment of intrinsic galaxy orientations, can be a source of a systematic error of weak lensing surveys. The redshift evolution of IA also contains information about the physics of galaxy formation and evolution. We present the first measurement of IA at high redshift, z~1.4, using the spectroscopic catalog of blue star-forming galaxies of the FastSound redshift survey, with the galaxy shape information from the Canada-Hawaii-France telescope lensing survey. The IA signal is consistent with zero with power-law amplitudes fitted to the projected correlation functions for density-shape and shape-shape correlation components, $A_{\delta+}=-0.0040\pm 0.0754$ and $A_{++}=-0.0159\pm 0.0271$, respectively. These results are consistent with those obtained from blue galaxies at lower redshifts (e.g., $A_{\delta+}=0.0035_{-0.0389}^{+0.0387}$ and $A_{++}=0.0045_{-0.0168}^{+0.0166}$ at z=0.51 from the WiggleZ survey), suggesting no strong redshift evolution of IA. The upper limit of the constrained IA amplitude corresponds to a few percent contamination to the weak-lensing shear power spectrum, resulting in systematic uncertainties on the cosmological parameter estimations by $-0.035<\Delta \sigma_8<0.026$ and $-0.025<\Delta \Omega_{\mathrm m}<0.019$.

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Local $H{\alpha}$ Emitters: Low-z Analogs of z>4 Star-Forming Galaxies

  • Shim, Hyunjin;Chary, Ranga-Ram
    • The Bulletin of The Korean Astronomical Society
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    • v.37 no.2
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    • pp.71.1-71.1
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    • 2012
  • We have identified local analogs of strong $H{\alpha}$ Emitters (HAEs) that dominate the z~4 Lyman-break galaxy population using the Sloan Digital Sky Survey (SDSS). At z<0.4, only 0.04% of galaxies are classified as HAEs with $H{\alpha}$ equivalent width larger than $500{\AA}$, comparable to that of z~4 HAEs. The $H{\alpha}$-to-UV luminosity ratio of local HAEs is consistent with that of z~4 HAEs, indicating relatively large specific star formation rate in these galaxies compared to traditionally studied UV-selected Lyman break analogs. Local HAEs are young, less evolved galaxies with low metallicity. It is still difficult to constrain whether the star formation in local HAEs is powered by minor mergers or by cosmological cold gas accretion. However, the stacked optical spectrum of local HAEs shows several strong ionization lines, for example HeII 4686 emission line, which are shown in Wolf-Rayet galaxies. Thus it is highly likely that local HAEs are galaxies with an elevated ionization parameter, either due to a high electron density or large escape fraction of hydrogen ionizing photons.

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High-resolution optical and near-infrared spectroscopic study of 2MASS J06593158-0405277

  • Park, Sunkyung;Lee, Jeong-Eun;Pyo, Tae-Soo;Sung, Hyun-Il;Lee, Sang-Gak;Kang, Wonseok;Oh, Hyung-Il;Yoon, Tae Seog;Mace, Gregory N.;Jaffe, Daniel T.;Yoon, Sung-Yong;Green, Joel D.
    • The Bulletin of The Korean Astronomical Society
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    • v.44 no.2
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    • pp.50.2-50.2
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    • 2019
  • We present the results of high-resolution (R ≥ 30,000) optical and near-infrared spectroscopic monitoring observations of a FU Orionis-type object, 2MASS J06593158-0405277. We have monitored 2MASS J06593158-0405277 with the Bohyunsan Optical Echelle Spectrograph (BOES) and the Immersion GRating INfrared Spectrograph (IGRINS) since December 2014. Various features produced by wind, disk, and outflow/jet were detected. The wind features varied over time and disappeared about a year after the outburst occurred. The double-peaked line profiles were detected in the optical and near-infrared, and the line widths decrease with increasing wavelength. The disk features in the optical spectra are fit well with G2-type or G5-type stellar spectra convolved with a disk rotational profile of about 45 km s-1, which corresponds to a disk radius of about 71 Rfor a central mass of 0.75 M. Disk features in near-infrared spectra are fit well with a K1-type stellar spectrum convolved with a disk rotational profile of about 35 km s-1, which corresponds to a disk radius of about 117 R for a central mass of 0.75 M. We also detected [S II] and H2 emission lines, which are rarely found in FUors but are usually found in the earlier stage of young stellar objects. Therefore, we suggest that 2MASS J06593158-0405277 is in the relatively earlier part of Class II stage.

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