• Title/Summary/Keyword: emission coefficient

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Estimation on Greenhouse Gases(GHGs) Emission of Large Forest Fire Area in 2013 (RapidEye 영상을 활용한 대형산불피해지의 온실가스 배출량 추정)

  • Won, Myoung-Soo;Kim, You-Seung;Kim, Kyong-Ha
    • Journal of the Korean Association of Geographic Information Studies
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    • v.17 no.3
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    • pp.54-67
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    • 2014
  • This study was performed to estimate Greenhouse gases(GHGs) emissions from biomass burning at large forest fire(Ulju, Pohang and Bonghwa) in 2013. The extended methodology to estimate GHGs adopted the IPCC(Intergovermental Panel on Climate Change) Guidelines(2006) equation. For classifying fire damaged area and analyzing burn severity of total three large-fire area damaged, this study used post-fire imagery from Rapideye imagery to compute the Maximum Likelihood Classifiction (MLC). The result of accuracy assessment on burn severity from imagery showed that average overall accuracy was 75.93% and Kapp coefficient was 0.67 Finally, GHGs emissions from biomass burning in the three large-fire area 2013 were estimated as follows: Ulju $CO_2$ 63,260, CO 5.207, $CH_4$ 360, $N_2O$ 28.0 and $NO_x$ $4.4g/kg^{-1}{\cdot}ha^{-1}$, Pohang $CO_2$ 28,675, CO 2.359, $CH_4$ 163, $N_2O$ 12.7 and $NO_x$ $1.9g/kg^{-1}{\cdot}ha^{-1}$ and Bonghwa $CO_2$ 53,086, CO 1,655, $CH_4$ 114, $N_2O$ 23.5 and $NO_x$ $3.6g/kg^{-1}{\cdot}ha^{-1}$.

Effects of Anion Supplementation on Growth Performance, Nutrient Digestibility, Meat Quality and Fecal Noxious Gas Content in Growing-finishing Pigs

  • Yan, L.;Han, D.L.;Meng, Q.W.;Lee, J.H.;Park, C.J.;Kim, I.H.
    • Asian-Australasian Journal of Animal Sciences
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    • v.23 no.8
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    • pp.1073-1079
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    • 2010
  • Forty-eight ((Duroc${\times}$Yorkshire)${\times}$Landrace) pigs with an average initial body weight (BW) of $48.47{\pm}1.13\;kg$ were used in a 12-week growth trial to investigate the influence of Anion (silicate) supplementation on growth performance, nutrient digestibility, meat quality and fecal noxious gas content in growing-finishing pigs. Pigs were allotted into three dietary treatments in a randomized complete block design according to sex and initial BW. Each dietary treatment consisted of four replications with four pigs per pen. Dietary treatments included: i) CON (basal diet), ii) HCI (basal diet+3 g/kg Anion), iii) HCII (basal diet+6 g/kg Anion). No significant difference (p>0.05) was detected for average daily gain (ADG), average daily feed intake (ADFI) and gain/feed ratio (G/F) throughout the experiment, although dietary supplementation of Anion numerically increased these characteristics compared with CON. The dietary HCI group significantly (p<0.05) increased the coefficient of total tract apparent digestibility (CTTAD) of dry matter (DM), nitrogen (N) and energy compared with the CON group (p<0.05). No significant difference was observed in meat quality except that meat firmness was linearly (p<0.05) increased by the Anion supplementation, while an increased tendency in meat color and a decreased tendency in 2-thiobarbituric acid reactive substances (TBARS) was also observed (p<0.10). Anion supplementation linearly (p<0.05) decreased the fecal $NH_3$ compared with the CON group. However, dietary Anion supplementation at 3 g/kg decreased the $H_2S$ concentration compared with CON, while no significant difference was detected in the HCII group, although the $H_2S$ emission was numerically decreased compared with CON. In conclusion, supplementation of the diet with 3 g/kg Anion was found to exert a beneficial effect on nutrient digestibility and meat quality of growing-finishing pigs, and concomitantly decreased the noxious gas emission without negative effect on growth performance.

PM2.5 Simulations for the Seoul Metropolitan Area: (III) Application of the Modeled and Observed PM2.5 Ratio on the Contribution Estimation (수도권 초미세먼지 농도모사: (III) 관측농도 대비 모사농도 비율 적용에 따른 기여도 변화 검토)

  • Bae, Changhan;Yoo, Chul;Kim, Byeong-Uk;Kim, Hyun Cheol;Kim, Soontae
    • Journal of Korean Society for Atmospheric Environment
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    • v.33 no.5
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    • pp.445-457
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    • 2017
  • In this study, we developed an approach to better account for uncertainties in estimated contributions from fine particulate matter ($PM_{2.5}$) modeling. Our approach computes a Concentration Correction Factor (CCF) which is a ratio of observed concentrations to baseline model concentrations. We multiply modeled direct contribution estimates with CCF to obtain revised contributions. Overall, the modeling system showed reasonably good performance, correlation coefficient R of 0.82 and normalized mean bias of 2%, although the model underestimated some PM species concentrations. We also noticed that model biases vary seasonally. We compared contribution estimates of major source sectors before and after applying CCFs. We observed that different source sectors showed variable magnitudes of sensitivities to the CCF application. For example, the total primary $PM_{2.5}$ contribution was increased $2.4{\mu}g/m^3$ or 63% after the CCF application. Out of a $2.4{\mu}g/m^3$ increment, line sources and area source made up $1.3{\mu}g/m^3$ and $0.9{\mu}g/m^3$ which is 92% of the total contribution changes. We postulated two major reasons for variations in estimated contributions after the CCF application: (1) monthly variability of unadjusted contributions due to emission source characteristics and (2) physico-chemical differences in environmental conditions that emitted precursors undergo. Since emissions-to-$PM_{2.5}$ concentration conversion rate is an important piece of information to prioritize control strategy, we examined the effects of CCF application on the estimated conversion rates. We found that the application of CCFs can alter the rank of conversion efficiencies of source sectors. Finally, we discussed caveats of our current approach such as no consideration of ion neutralization which warrants further studies.

Temperature Dependence on Dry Etching of $ZrO_2$ Thin Films in $Cl_2/BCl_3$/Ar Inductively Coupled Plasma ($Cl_2/BCl_3$/Ar 유도 결합 플라즈마에서 온도에 따른 $ZrO_2$ 박막의 식각)

  • Yang, Xue;Kim, Dong-Pyo;Lee, Cheol-In;Um, Doo-Seung;Kim, Chang-Il
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.145-145
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    • 2008
  • High-k materials have been paid much more attention for their characteristics with high permittivity to reduce the leakage current through the scaled gate oxide. Among the high-k materials, $ZrO_2$ is one of the most attractive ones combing such favorable properties as a high dielectric constant (k= 20 ~ 25), wide band gap (5 ~ 7 eV) as well as a close thermal expansion coefficient with Si that results in good thermal stability of the $ZrO_2$/Si structure. During the etching process, plasma etching has been widely used to define fine-line patterns, selectively remove materials over topography, planarize surfaces, and trip photoresist. About the high-k materials etching, the relation between the etch characteristics of high-k dielectric materials and plasma properties is required to be studied more to match standard processing procedure with low damaged removal process. Among several etching techniques, we chose the inductively coupled plasma (ICP) for high-density plasma, easy control of ion energy and flux, low ownership and simple structure. And the $BCl_3$ was included in the gas due to the effective extraction of oxygen in the form of $BCl_xO_y$ compounds. During the etching process, the wafer surface temperature is an important parameter, until now, there is less study on temperature parameter. In this study, the etch mechanism of $ZrO_2$ thin film was investigated in function of $Cl_2$ addition to $BCl_3$/Ar gas mixture ratio, RF power and DC-bias power based on substrate temperature increased from $10^{\circ}C$ to $80^{\circ}C$. The variations of relative volume densities for the particles were measured with optical emission spectroscopy (OES). The surface imagination was measured by scanning emission spectroscope (SEM). The chemical state of film was investigated using energy dispersive X-ray (EDX).

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Diffusion Weighted Imaging Can Distinguish Benign from Malignant Mediastinal Tumors and Mass Lesions: Comparison with Positron Emission Tomography

  • Usuda, Katsuo;Maeda, Sumiko;Motono, Nozomu;Ueno, Masakatsu;Tanaka, Makoto;Machida, Yuichiro;Matoba, Munetaka;Watanabe, Naoto;Tonami, Hisao;Ueda, Yoshimichi;Sagawa, Motoyasu
    • Asian Pacific Journal of Cancer Prevention
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    • v.16 no.15
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    • pp.6469-6475
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    • 2015
  • Background: Diffusion-weighted magnetic resonance imaging (DWI) makes it possible to detect malignant tumors based on the diffusion of water molecules. It is uncertain whether DWI is more useful than positron emission tomography-computed tomography (PET-CT) for distinguishing benign from malignant mediastinal tumors and mass lesions. Materials and Methods: Sixteen malignant mediastinal tumors (thymomas 7, thymic cancers 3, malignant lymphomas 3, malignant germ cell tumors 2, and thymic carcinoid 1) and 12 benign mediastinal tumors or mass lesions were assessed in this study. DWI and PET-CT were performed before biopsy or surgery. Results: The apparent diffusion coefficient (ADC) value ($1.51{\pm}0.46{\times}10^{-3}mm^2/sec$) of malignant mediastinal tumors was significantly lower than that ($2.96{\pm}0.86{\times}10^{-3}mm^2/sec$) of benign mediastinal tumors and mass lesions (P<0.0001). Maximum standardized uptake value (SUVmax) ($11.30{\pm}11.22$) of malignant mediastinal tumors was significantly higher than that ($2.53{\pm}3.92$) of benign mediastinal tumors and mass lesions (P=0.0159). Using the optimal cutoff value (OCV) $2.21{\times}10^{-3}mm^2/sec$ for ADC and 2.93 for SUVmax, the sensitivity (100%) by DWI was not significantly higher than that (93.8%) by PET-CT for malignant mediastinal tumors. The specificity (83.3%) by DWI was not significantly higher than that (66.7%) for benign mediastinal tumors and mass lesions. The accuracy (92.9%) by DWI was not significantly higher than that (82.1%) by PET-CT for mediastinal tumors and mass lesions. Conclusions: There was no significant difference between diagnostic capability of DWI and that of PET-CT for distinguishing mediastinal tumors and mass lesions. DWI is useful in distinguishing benign from malignant mediastinal tumors and mass lesions.

Atmospheric Distribution of PCDD/F Concentrations in Gyeonggi-do, South Korea (경기도 내 대기 중 다이옥신 분포 특성에 관한 연구)

  • Heo, Jong-Won;Min, Yoon-Ki;Kim, Dong-Gi;Choi, Il-Woo;Kim, Jong-Soo;Song, Il-Seok;Lee, Gangwoong
    • Journal of Korean Society for Atmospheric Environment
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    • v.31 no.6
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    • pp.548-561
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    • 2015
  • Atmospheric concentrations of polychlorinated dibezo-p-dioxins and furans (PCDD/Fs) were investigated at urban-residential (Group I: Suwon, Guri and Goyang), industrial (Group II: Ansan, Siheung and Bucheon), urban-rural mixed (Group III: Yangju, Pocheon and Dongducheon) and rural regions (Group IV: Yangpyeong) in Gyeonggi-do from February 2012 to November 2012 quarterly. The concentrations of PCDD/Fs ranged from 0.018 to $0.109pgTEQm^{-3}$ in Group I (mean value: $0.061pgTEQm^{-3}$), 0.059 to $0.367pgTEQm^{-3}$ in Group II (mean value: $0.179pgTEQm^{-3}$), 0.072 to $0.836pgTEQm^{-3}$ in Group III (mean value: $0.334pgTEQm^{-3}$) and 0.014 to $0.066pgTEQm^{-3}$ in Group IV (mean value: $0.034pgTEQm^{-3}$), respectively. In spite of the less PCDD/F emission sources than Group II (industrial regions), the level of PCDD/Fs in urban-rural mixed area showed the highest values with high fluctuation. It's likely that the Group III was affected by fugitive emissions such like biomass burning and unregulated open burning. The mean contribution of particle phase to total PCDD/F concentration was above 83% because most of PCDD/F congeners were partitioned into particle phase. We evaluated their gas-to-particles equilibriums with the regression between the particle-gas partition coefficient, $K_P(m^3{\mu}g^{-1})$ and corresponding subcooled liquid vapor pressure ($P_L$). The logarithm-$K_P$ of PCDD/Fs was poorly correlated with $P_L$ at low ambient temperature (below $10^{\circ}C$) and the slope (m) values for log-log plots of the $K_P$ vs. $P_L$ was steeper in the Group 2 and Group 3 than residential area. It implies that the slope values were likely influenced by both the direct emission source of PCDD/Fs and ambient temperature.

Evaluation for Loss Rate of Carbon Dioxide by Sample Storage Method (시료 보관 방법에 따른 이산화탄소 시료의 유실율 평가)

  • Cho, Chang-Sang;Lee, See-Hyung;Lim, Ki-Kyo;Yoo, Jung-Hwa;Sa, Jae-Hwan;Jeon, Byung-Gwan;Jeon, Eui-Chan
    • Journal of Climate Change Research
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    • v.2 no.4
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    • pp.309-316
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    • 2011
  • The study evaluated the loss rate of carbon dioxide, which is the prevalent greenhouse gas, according to the method of keeping specimens using standard gases. In order to examine the difference generated by a bag of storing specimens, it checked the loss rate according to concentration and time by making a 2nd set of standard gases in a Tedlar bag and an Aluminium bag. The containers lost gases at a rate of 5% or more after 6 day, and 10% or more after 15 days in both bags. In time, it was confirmed that the loss rate of the Aluminium bag was higher than that of the Tedlar bag. Specifically, there was no significant difference between the two bags after 12 days had passed, but by the 15th day, it was confirmed that the loss in an Aluminium bag was more severe than that in the Tedlar bag. The study went on to check the relations between the humidity in storage and the loss rate. The results showed that there was no significant effect of humidity on the loss rate until 72 hours had passed, when the loss rate in the Tedlar bag with high humidity was about 5% higher than that of the Tedlar bag in dry conditions. This study examined the loss rate of carbon dioxide, a typical greenhouse gas. It is important to note that the loss rate was determined by calculating highly reliable carbon dioxide emission and emission coefficient data, with consideration to the method of keeping specimens.

Effect of Sulfur Dioxide and Hydrogen Fluoride on Rice Plant Growth in Industrial Estate (공업단지 주변에서의 아황산가스 및 불화수소가 수도 생육에 미치는 영향)

  • Wan Cheol, Park;Kwang-Ho Kim;Ki Joon, Kim
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.36 no.1
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    • pp.17-21
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    • 1991
  • The study was performed to investigate the effects of gaseous emission of sulfur dioxide and hydrogen fluoride on the growth of rice plant under stressed field conditions. This study is specifically dealt with multiple effects of sulfur dioxide and hydrogen fluoride on various plant growth indicators such as leaf damage, weight of grain, panicles per hill, spikelets per panicle and percent fertility. It appears that there is a good correlation between ambient concentrations of sulfur oxides and sulfur contents found in leaves with an average correlation coefficient of 0.868 within a 1% significance level. A better multiple correlation was found between percent leaf damage and sulfur and fluorine contents found in leaf with a significance of 1% level. The correlation coefficient ranges from 0.807 to 0.978 with an average being 0.922. An evaluation of data observed has demonstrated that both panicles per hill and percent fertility are significantly affected by air pollutants. As expected, hydrogen fluorides have more effects than sulfur oxides. It is, however, interesting to note that spikelets per panicle has slightly been affected while no indication of effects on l000-grain weight has been observed. This may lead to a conclusion that a reduction in yield of rice under polluted field conditions may have more been caused by the diminution panicles per hill and percent fertility rather than by the diminution of spikelets per panicle and grain weight.

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Generation Rate and Content Variation of Manganese in Stainless Steel Welding (스테인레스 강 용접중 발생하는 망간의 발생량 및 함량변화에 관한 연구)

  • Yoon, Chung Sik;Kim, Jeong Han
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.16 no.3
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    • pp.254-263
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    • 2006
  • Manganese has a role as both toxic and essential in humans. Manganese is also an essential component in the welding because it increases the hardness and strength, prevents steel from cracking of welding part and acts as a deoxidizing agent to form a stable weld. In this study, manganese generation rate and its content was determined in flux cored arc welding on stainless steel. Domestic two products and foreign four products of flux cored wires were tested in the well designed fume generation chamber as a function of input power. Welding fume was measured by gravimetric method and metal manganese was determined by inductively coupled plasma-atomic emission spectrophotometer. The outer shell of the flux cored wire tube and inner flux were analyzed by scanning electron microscopy to determine their metal compositions. Manganese generation rate($FGR_{mn}$) was increased as the input power increased. It was 16.3 mg/min at the low input power, 38.1 mg/min at the optimal input power, and up to 55.4 mg/min at the high input power. This means that $FGR_{mn}$ is increased at the work place if welder raise the current and/or voltage for the high productivity. The slope coefficient of $FGR_{mn}$ was smaller than that of the generation rate of total fume(FGR). Also, the correlation coefficient of $FGR_{mn}$ was 0.65 whereas that of FGR is 0.91. $FGR_{mn}$ was equal or higher in the domestic products than that of the foreign products although FGR was similar. From the electron microscopic analytical data, we concluded that outer shell of the wire was composed mainly of iron, chromium, nickel and less than 1.2 % of manganese. There are many metal ingredients such as iron, silica, manganese, zirconium, titanium, nickel, potassium, and aluminum in the inner flux but they were not homogeneous. It was found that both $FGR_{mn}$ and content of manganese was higher and more varied in domestic flux cored wires than those of foreign products. To reduce worker exposure to fumes and hazardous component at the source, further research is needed to develop new welding filler materials that improve the quality of flux cored wire in respect to these points. Welder should keep in mind that the FGR, $FGR_{mn}$ and probably the generation rate of other hazardous metals were increased as the input power increase for the high productivity.

Fundamental Heat Analysis about the Thermoelectric Generation System Using the Waste Heat of Exhaust Gas from Ship (선박의 배기가스 폐열을 활용한 열전발전시스템에 관한 기초 열해석)

  • Kim, Myoung-Jun;Ga, Gwang-Jin;Chea, Gyu-Hoon;Kim, In-Seup
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.22 no.5
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    • pp.583-592
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    • 2016
  • IMO (International Maritime Organization) in the UN (United Nations) set up that aim at reducing $CO_2$ emission from ship by up to 30 percent until 2030. The final purpose of this study is the development of marine thermoelectric generation system using waste heat from vessel of internal combustion engines. Before the development of marine thermoelectric generation system, this paper carried out the fundamental heat analysis of marine thermoelectric generation system. It was able to obtain the valuable results about the efficiency improvement of the thermoelectric generation system. The results is as follows : 1) It was confirmed that the efficiency of thermoelectric generation system improves to 8.917 % with increasing the temperature difference of peltier module by reducing the temperature difference between peltier module and heat source at the hot side. 2) System efficiency according to change in the external load resistance was confirmed that the change width of about 6 % which does not significantly occur. 3) System efficiency in the case stainless steel at the same condition is 8.707 %. System efficiency could be confirmed that the stainless steel is higher than duralumin (8.605 %), copper (8.607 %).