• 제목/요약/키워드: emission coefficient

검색결과 449건 처리시간 0.027초

Improved Thermal, Structural and Electrical Properties of Elastic-Epoxy Blends System

  • Lee, Kyoung-Yong;Lee, Kwan-Woo;Choi, Yong-Sung;Park, Dae-Hee
    • KIEE International Transactions on Electrophysics and Applications
    • /
    • 제4C권5호
    • /
    • pp.230-235
    • /
    • 2004
  • In this paper, epoxy elasticity factors were investigated by TMA (Thermomechanical Analysis), DMTA (Dynamic Mechanical Thermal Analysis) and FESEM (Field Emission Scanning Electron Microscope) to improve toughness and reduce brittleness of existing epoxy resin. Dumbbell shaped specimens were made and tested at rates of 0, 20 and 35phr (part per hundred resins). TMA temperatures ranged from -2$0^{\circ}C$ to 20$0^{\circ}C$. Tg (glass transition temperature) of elastic epoxy was measured by thermal analysis. Also investigated were thermal expansion coefficient ($\alpha$), modulus and Tan$\delta$ (loss factor). And we analyzed structure through FESEM, could find elastic-factors of elastic epoxy that is not existing-epoxy. In addition, we measured permittivity and Tan$\delta$ for investigation of the electrical properties of elastic epoxy. Permittivity and Tan$\delta$ depend on elastomer composition. Namely, permittivity and Tan$\delta$ increase according to the elastomer contents. For experimental analysis results, 20phr was considered an excellent specimen.

Solvent Extraction, Preconcentration and Determination of Thorium with Monoaza 18-Crown-6 Derivative

  • Dolak, I.;Karakaplan, M.;Ziyadanogullar, B.;Ziyadanogullari, R.
    • Bulletin of the Korean Chemical Society
    • /
    • 제32권5호
    • /
    • pp.1564-1568
    • /
    • 2011
  • A solvent extraction separation, preconcentration and determination of thorium with a new crown, 2-ethyl-N-benzyl-4,7,10,13,16-pentaoxa-1-azacyclooctadecane (MACE), is described in the study. The amount of thorium in the aqueous phase and organic phase was determined by Inductively Coupled Plasma-Optical Emission Spectroscopy and Ultraviolet-Visible, respectively. Thorium loaded organic phase was quantitatively stripped in a stage by using 1.0 M $HNO_3$. Thorium was effectively extracted with MACE in the pH range of 6-7 to produce a 3:2 complex ratio in the chloroform. A highly sensitive and rapid spectrophotometric method was described for determination of trace amounts of thorium with MACE. The effective molar absorption coefficient at 281 nm is $1.98{\times}10^3\;mol^{-1}cm^{-1}$, and the system complies with Beer's law in the range from 0.464 to 2.32 ${\mu}gm\;L^{-1}$ of thorium. Thorium was also determined in standard and environmental samples.

Symmetric Bis-Azospiropyrans: Synthesis, Characterization and Colorimetric Study

  • Nourmohammadian, Farahnaz;Abdi, Ali Ashtiani
    • Bulletin of the Korean Chemical Society
    • /
    • 제34권6호
    • /
    • pp.1727-1734
    • /
    • 2013
  • Synthesis and characterization of some novel symmetric bis-azospiropyrans are reported in this study. These bis-azospiropyrans are bifunctional chromophores with two spiropyrans linked by a bis-azo extended aromatic system that produce more color strength (large molar absorption coefficient in mero forms) due to appending two azospiropyran chromophores on one molecule. Comparing to the molar absorption coefficients of the conventional spiropyran chromophores (${\varepsilon}=0.31{\times}10^4\;M^{-1}{\cdot}cm^{-1}$) and mono-azospiropyran chromophores ($1.35{\times}10^4\;M^{-1}{\cdot}cm^{-1}$), the novel synthesized photochromes showed astonishingly increased molar absorption coefficients ($2.3-3.8{\times}10^4\;M^{-1}{\cdot}cm^{-1}$) at the same conditions. Such high molar absorption coefficients confers high sensitivity to light and more color intensity of mero form, that leads to improvement of their light sensitivity and better discrimination of spiro (OFF) form from mero (ON) ones in molecular switches. The structures were deduced from their MS, FT-IR, and $^1H$-NMR spectroscopic data and CHN analysis. All the synthesized photochemically bifunctional compounds revealed fluorescent emission in their colorless form which was faded out after exposing to UV light. Fluorescence quantum yield values of the mero forms were 0.25-0.81 and two high fluorescence quantum yield values (0.60 and 0.81) were found in these series.

Nitrogen Incorporation of Nanostructured Amorphous Carbon Thin Films by Aerosol-Assisted Chemical Vapor Deposition

  • Fadzilah, A.N.;Dayana, K.;Rusop, M.
    • Transactions on Electrical and Electronic Materials
    • /
    • 제14권4호
    • /
    • pp.165-171
    • /
    • 2013
  • Nanostructured pure a-C and nitrogen doped a-C: N thin films with small particle size of, ~50 nm were obtained by Aerosol-assisted CVD method from the natural precursor camphor oil. Five samples were prepared for the a-C and a-C: N respectively, with the deposition temperatures ranging from $400^{\circ}C$ to $600^{\circ}C$. At high temperature, the AFM clarifies an even smoother image, due to the increase of the energetic carbon ion bombardment at the surface of the thin film. An ohmic contact was acquired from the current-voltage solar simulator characterization. The higher conductivity of a-C: N, of ${\sim}{\times}10^{-2}Scm^{-1}$ is due to the decrease in defects since the spin density gap decrease with the nitrogen addition. Pure a-C exhibit absorption coefficient, ${\alpha}$ of $10^4cm^{-1}$, whereas for a-C:N, ${\alpha}$ is of $10^5cm^{-1}$. The high ${\sigma}$ value of a-C:N is due to the presence of more graphitic component ($sp^2$ carbon bonding) in the carbon films.

원격 측정 기법을 이용한 토양 함수비의 측정 (Soil Moisture Content Estimation Using Remote Sensing Technique)

  • 이재수
    • 대한토목학회논문집
    • /
    • 제14권3호
    • /
    • pp.535-542
    • /
    • 1994
  • 원격 측정 방법은 지표로부터 방출된 방사선의 관측으로부터 지표면의 특성을 추정하는데 기초를 두고 있으며 이 방법을 사용하여 연구되어지는 수문학적 인자에는 지표면 온도, 증발산, 토양 함수비, 강우 그리고 강설 등이 있다. 본 연구에서는 관측된 광명온도와 모의된 광명온도로부터 피복이 안된 토양의 함수비 산정에 대한 방법을 소개한다. 피복이 안된 토양에서의 초단파 방출은 함수비, 토양의 온도와 표면 조도에 의존하게 된다. 이 방법은 표면 조도의 영향을 고려하기 위한 Fresnel 반사 계수의 수정과 함께 방사선 전달 모델(radiative transfer model)에 기본을 두고 있는데 피복이 안된 매끈한 표면과 서로 다른 표면 조도를 가진 표면에 대해 분석을 실시한다. 연구의 결과는 표면 조도의 영향이 토양의 광명온도를 증가시키고 광명온도와 함수비 사이의 감소경사를 작게함을 보여주고 있다.

  • PDF

흡기포트 분사방식의 가솔린 엔진에서 냉시동시 혼합기 형성에 관한 연구 (A Study on Mixture Preparation in a Port Fuel Injection Sl Engine During Engine Starting)

  • 황승환;이종화;민경덕
    • 한국자동차공학회논문집
    • /
    • 제10권4호
    • /
    • pp.15-22
    • /
    • 2002
  • As the emission regulations on the automobiles have been increasingly stringent, precise control of air/fuel ration is one of the most important issues on the gasoline engines. Although many researches have been carried out to identify the fuel transport phenomena in the port fuel injection gasolines, mixture preparation in the cylinder has not been fully understood due to the complexity of fuel film behavior, In this paper, the mixture preparation during cold engine start is studied by using a Fast Response Flame ionization Detector.(FRFID) In order to estimate the transportation of injected fuel from the intake port into cylinder, the wall wetting fuel model was used. The two coefficient($\alpha$,$\beta$) of the wall-wetting fuel model was determined from the measured fuel mass that was inducted into the cylinder at the first cycle after injection cut-in. $\alpha$( ratio of directly inducted fuel mass into cylinder from injected fuel mass) and $\beta$ (ratio of indirectly inducted fuel mass into cylinder from wall wetted fuel film on the wall) was increased with increasing cooling water temperature. To reduce a air/fuel ratio fluctuation during cold engine start, the appropriate fuel injection rate was obtained from the wall wetting fuel model. Result of air/fuel ratio control, air/fuel excursion was reduced.

웨이블렛-신경망을 이용한 부분방전 종류와 진단에 관한연구 (A Study on Diagnosis of Partial Discharge Type Using Wavelet Transform-Neural Network)

  • 박재준;전현구;전병훈;김성홍;권동진
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2002년도 하계학술대회 논문집 Vol.3 No.2
    • /
    • pp.894-899
    • /
    • 2002
  • In this papers, we proposed the new method in order to diagnosis partial discharge type of transformers. For wavelet transform, Daubechies filter is used, we can obtain wavelet coefficients which is used to extract feature of statistical parameters (maximum value, average value, dispersion, skewness, kurtosis) about high frequency current signal per 3-electrode type (needle-plane electrode, IEC electrode and Void electrode.). Also. these coefficients are used to identify Signal of internal partial discharge in transformer. As a result. from compare of high frequency current signal amplitude and average value. we are obtained results of IEC electrode> Void electrode> Needle-Plane electrode. otherwise. In case of skewness and kurtosis, we are obtained results of Void electrode> IEC electrode > Needle-Plane electrode. As Improved method in order to diagnosis partial discharge type of transformers, we use neural network.

  • PDF

Influence of constraint MgO deposition onto phosphors on luminance properties in AC Plasma Display Panels

  • Jeoung, Jin-Man;OH, P.Y.;Moon, M.W.;Lee, J.H.;Jeong, J.E.;Lee, H.J.;Han, Y.K.;Lee, S.B.;Jeong, S.H.;Yoo, C.K.;Yoo, N.R.;Choi, E.H.;Ko, B.D.
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 한국정보디스플레이학회 2005년도 International Meeting on Information Displayvol.II
    • /
    • pp.1215-1217
    • /
    • 2005
  • One of the important problems in recent AC-PDP technology is the image sticking. In this research, we have investigated the PDP cell with constraint deposition MgO on phosphor, the electrical and optical properties in the PDP cell were examined. Also, we have investigated the correlation with image sticking and degraded MgO protective layer, phosphor in AC-PDP. As a result, we measured the secondary electron emission coefficient ${\gamma}$, discharge characteristics and Brightness for the constraint degraded phosphor are compared with those of nondegraded phosphor.

  • PDF

대출력 Gauss형 Nd:글라스 레이저 비임의 증폭특성에 관한 연구 (A Study on the Amplification Characteristics of High-Power Gaussian Nd:Glass Laser Beam)

  • 강형부;장용무
    • 대한전기학회논문지
    • /
    • 제36권10호
    • /
    • pp.741-747
    • /
    • 1987
  • The high-power Nd:glass system with five-stage amplifier was designed and its amplification characteristics was studied for developing high-power Nd:glass laser system as an energy driver of inertial confinement fusion(ICF). In order to study the amplification characteristics of remporal and spacial Gaussian laser beam, the dependence of them on pumping efficiency and rod loss were studied and discussed. The output energy of this system using phosphate Nd glass rod(LHG-7,LHG-8) and silicate Nd glass rod(LSG-91H), respectively, was calculated by the computer simulation using Avizonis-Grotbeck and Frantz Nodvik equations. As results of this simulation, it was found that the shorter the risetime of laser pulse, the larger the amplification factor and that the larger peak value of laser pulse, the lower the amplification factor. The output inergies of 179J, 344J, and 7J were obtained by the designed five-stage amplified high-power Nd:glass laser system using glass rods of LHG-7,LHG-8, and LSG-91H, respectively. From the results it was found that the laser system using the LHG-8 glass rod was the most excellent one among the systems and the cross section for stimulated emission of the gain coefficient was essentially important parameter for the amplification characteristics.

  • PDF

과급기의 고압력비 원심압축기 공력설계 및 시험평가 (Performance Test and Aerodynamic Design on the High Pressure Ratio Centrifugal Compressor of a Turbocharger)

  • 김홍원;류승협;이근식
    • 한국유체기계학회 논문집
    • /
    • 제17권6호
    • /
    • pp.13-20
    • /
    • 2014
  • It is necessary to design a compressor with high pressure ratio that satisfies the IMO(international maritime organization) NOx emission regulation for the marine diesel engine. Impeller was designed using the modified slip factor with the flow coefficient. The main purpose of this study is to investigate the sensitivity of the compressor performance by the vaned diffuser geometries. The first vaned diffuser type was based on a NACA airfoil, the second was channel diffuser, and the third was conformally transformated configuration of a NACA65(4A10)06 airfoil. The sensitivity of the performance was calculated using a commercial CFD program for three different diffuser geometries. The channel diffuser showed the wide range of operation and higher pressure characteristics, comparing with the others. This is attributed to the flow stability at diffuser. Combined with this results with impeller design, the optimized compressor was designed and verified by the test results.