• International Journal of Automotive Technology
• /
• 제5권4호
• /
• pp.221-238
• /
• 2004

Wall interactions of direct injection spray were investigated using laser-sheet imaging, shadowgraphy, wetted footprint and phase Doppler interferometry techniques. A narrow-cone high-pressure swirl injector is used to inject iso-octane fuel onto a plate, which has three different impact angles inside a pressurized chamber. Heated air and plate conditions were compared with unheated cases. Injection interval was also varied in the heated case to compare dry- and wet- wall impingement behaviors. High-speed macroscopic Mie-scattering images showed that presence of wall and air temperature has only minor effect on the bulk spray structure and penetration speed for the narrow-cone injector tested. The overall bulk motions of the spray plume and its spatial position at a given time are basically unaffected until a few millimeters before impacting the wall. The surface properties of the impact surface, such as the temperature, the presence of a preexisting liquid film also have a small effect on the amount of wetting or the wetted footprint; however, they have strong influence on what occurs just after impact or after a film is formed. The shadowgraph in particular shows that the plate temperature has a significant effect on vapor phase propagation. Generally, 10-20% faster horizontal vapor phase propagation is observed along the wall at elevated temperature condition. For impingement onto a preexisting film, more splash and evaporation were also observed. Contrary to some preconceptions, there is no significant splashing and droplet rebounding from surfaces that are interposed in the path of the DI gasoline spray, especially for the oblique impact angle cases. There also appears to be a dense spray front consists of large sac spray droplets in the oblique impact angle cases. The bulk of the spray is not impacted on the surface, but rather is deflected by it The microscopic details as depicted by phase Doppler measurements show that the outcome of the droplet impaction events can be significantly influenced. Only droplets at the spray front have high enough Weber numbers for wall impact to wet, splash or rebound. Using the sign of vertical velocity, the time-resolved downward droplets and upward droplets are compared. The Weber number of upward moving droplets, which seldom exceeds unity, also decreases as the impact angle decreases, as the droplets tend to impact less and move along the wall in the deflected spray plume.

• Journal of Ecology and Environment
• /
• 제38권3호
• /
• pp.293-305
• /
• 2015

In order to understand the mechanisms of conversion between different algal dominance, an experiment was performed in a greenhouse from 22 June to 10 July 2011. The experiment included a treatment group subjected to three instances of nutrient enrichment and a control with no nutrient enrichment. The initial water was dominated by Ankistrodesmus of Chlorophyta. The average water temperature at 08:30 h and 14:00 h during the experiment was $31.6^{\circ}C$ and $34.6^{\circ}C$, respectively. The results showed that the total nitrogen (TN), total phosphorus (TP), dissolved total nitrogen (DTN), dissolved total phosphorus (DTP), and soluble reactive phosphorus (SRP) concentrations in the treatment were significantly higher than in the control (P < 0.05). However, the TN/TP and DTN/DTP in the control was higher than in the treatment (P < 0.05). The dominant algae in the control did not change during the experiment, while the dominant algae in the treatment switched to Planktothrix of Cyanophyta on day 9. The chlorophyll a (Chl-a), wet weight of all algae, wet weight of Cyanophyta, and percentage of Cyanophyta in the control were all significantly lower than in the treatment (P < 0.05). Amounts of zooplankton, especially rotifers, were present at the end of the experimental period. The density of rotifers between the control and treatment was not significantly different (P > 0.05), while the copepod density in the treatment was higher than in the control (P < 0.05). We conclude that green algae dominance quickly switches to cyanobacteria dominance after nutrient enrichment in a greenhouse with elevated temperature.

• 한국콘크리트학회:학술대회논문집
• /
• 한국콘크리트학회 1995년도 봄 학술발표회 논문집
• /
• pp.396-401
• /
• 1995

Epoxy coated reinforcing steels (ECRs) were acquired from ten sources and coatings from each source were initially characterized in terms of defects, thickness, solvent extraction weight loss and hardness. Testing involved exposure in three aqueous solutions at elevated temperature (8$0^{\circ}C$) and in chloride-contaminated concrete slabs under outdoor exposure, It was found that the density and size of coating defects was the promary factor affecting ECR performance. The equivalent circuit analysis using electrochemical impedance spectroscopy (EIS) data indicated that the impedance response for well-performing ECR specimens showed no signs of active degradation at the interface although diffusional processes similar to those noted for poorly performing bars occurred here. Experimental results also indicated a relationship between corrosion behavior and bar source. Weight loss upon solvent extraction correlated with impedance reduction from hot water exposure. Coating defects during most of the tests, especially in high pH solutions containing chloride ions. ECRs with excessive coating defects, either initially present or ones which developed in service, performed poorly in every test category regardless of source. Forms of coating failure were extensive rusting at defects, blistering, wet adhesion loss, cathodic delamination, underfilm corrosion and coating cracks. These occurred sequentially or concurrently, depending on the condition of the ECR and nature of the environment

• International Journal of Aeronautical and Space Sciences
• /
• 제13권2호
• /
• pp.229-237
• /
• 2012

In this study, the failure mechanism of sandwich-to-laminate T-joints under pull-off loading was investigated by experiment and the finite element method. A total of 26 T-joint specimens were manufactured and tested in order to investigate the effects of both adhesive thickness (0.4, 2.0, and 4.0 mm) and environmental conditions on the failure of the joints. The results showed that failure occurred mainly as intralaminar failure in the first layer of the sandwich face, which was contacted to the paste adhesive. The failure load did not significantly change with increasing adhesive thickness in both RTD (Room Temperature and Dry) and ETW (Elevated Temperature and Wet) conditions. In the case of ETW conditions, however, the failure load increased slightly with an increase in adhesive thickness. The joints tested in ETW conditions had higher failure loads than those tested in RTD conditions. In addition to the experiment, a finite element analysis was also conducted to investigate the failure of the joint. The stress inside the first ply of the sandwich face was of interest because during the experiment, failure always occurred there. The analysis results showed good agreement with the trend of experimental results, except for the case of the smallest adhesive thickness. The highest stress was predicted in the regions where initial failure was observed in the experiment. The maximum stress was almost constant when the adhesive thickness was beyond 2 mm.

• 한국의류산업학회지
• /
• 제21권4호
• /
• pp.509-514
• /
• 2019

Cotton fabrics were treated with gelatin to enhance dyeability and color strength when using Caesalpinia sappan dye. Gelatin was used as the protein and a pad-dry- cure method was used for the treatment process (2, 4, 6, 8, 10, 12, 14g/l concentration). Pretreated fabrics were mordanted with 10% alum. Fabrics were then dyed with freeze-dried sappan wood water extract powder form. Dyed samples were assessed in regards to dyeing behavior and color fastness. Comparing untreated and gelatin treated samples from the SEM images indicated that the Gelatin treatment (10g/l) resulted in an enhanced surface roughness that was relative to that of untreated cotton. Padding cotton with gelatin at 6g/l concentration afforded dyed fabrics with a 2 times increase in the K/S value over that of untreated fabrics. All dyed samples were red color with a significant enhancement in the sample color strength (K/S) being observed for pretreated samples. pH values favor dye absorption with pH 7 yielding the highest color strength. Dyeing at an elevated temperature resulted in a lower color strength and reddish-dull color. Longer dyeing times created greater color strengths for untreated and gelatin treated cotton. Increased dye concentrations resulted in higher K/S values for both gelatin treated and untreated cotton. As for color fastness, gelatin treated and untreated cotton fabrics dyed with sappan wood extract showed a relatively low rating in washing fastness (color change 1 rating), light fastness (1 rating), and rubbing fastness (wet:1-2, dry:3-4 rating).

• 한국진공학회지
• /
• 제6권1호
• /
• pp.9-19
• /
• 1997

본 연구에서는 실리콘 웨이퍼 표면에 존재하는 미량의 Zn, Fe, Ti 금속 오염물들이 UV-excited chlorine radical을 이용한 건식세정 방법으로 제거되는 반응과정을 찾아내고자 하였다. 실리콘 웨이퍼 상에 진공증착법으로 원형패턴이 있는 Zn, Fe, Ti 박막을 증착시켜 상온 및 $200^{\circ}C$에서 UV/$Cl_2$세정하였을 때, 염소 래디컬($Cl^*$)이 Fe, Zn, Ti와 반응하여 제거되 는 것을 반응 전후 광학현미경과 SEM을 통해 표면 형상 변화를 관찰하였고, in-line으로 연결된 XPS를 통해서 반응 후 웨이퍼 표면에 남아있는 화합물의 화학적 결합상태를 관찰 하였으며, UV/$Cl_2$ 세정 후 실리콘 기판이 손상받는 정도를 알기 위해 AFM으로 표면 거칠 기를 측정하였다. 광학현미경과 SEM의 분석 결과에 의하면 Zn와 Fe는 쉽게 제거되는 반면 염화물을 형성하기 보다는 휘발성이 적은 산화물을 형성하는 경향이 강한 Ti은 약간만 제 거되는 것을 확인하였다. XPS분석을을 통해서 이들 금속 오염물들이 chlorine radical과 반 응하여 웨이퍼 표면에 금속 염화물을 형성하고 있는 것을 확인하였고, UV/$Cl_2$세정처리를 하였을 때 실리콘 웨이퍼의 표면 거칠기가 약간 증가하는 것을 알 수 있었다. 지금까지의 결 과를 볼 때, 습식세정과 UV/$Cl_2$건식세정을 병행하면 플라즈마 및 레이저를 사용하는 다른 건식세정 방법에 비하여 보다 저온에서 실리콘 기판의 큰 손상 없이 비교적 용이하게 금속 오염물을 제거할 수 있음을 제안 하였다.

• 대한화학회지
• /
• 제47권3호
• /
• pp.220-228
• /
• 2003

본 연구는 섬유 교질-현탁액내 PAE 고분자 전해질의 흡착성향과 Lanumuir 및 Freundlich식 흡착 평형에 대한 열역학적 특성을 규명하기 위하여 수행되었다. 섬유의 계면동전위적 특성은 흐름-전기적 방법의 제타전위 측정에 의해 분석되었고, PAE 고분자 흡착량은 고분자 전해질용액의 PCD 적정을 통해 측정되었다. PAE 고분자 내첨은 지료의 제타전위에 크게 영향을 미쳤으며 내첨 초기에는 제타전위 상승 효과가 크게 나타났지만 시간의 경과와 함께 전하 감쇄현상을 나타내었다. PAE 고분자는 저온 또는 상온에서 준-Langmuir 흡착 거동을 보여주었으나 온도가 증가하면서 Freundlich 지수항(v)이 비례적으로 높아지는 결과를 나타내었다. PAE 고분자의 Gibbs 흡착 자유에너지로부터 산출한 트레인 수$(N_{seg})$는 상온에서 약 7~8의 범위로 나타났고 고분자 고리의 노출반경은 약 215 nm로서 $10^{\circ}C$ 온도상승에 대해 점차 9%씩 증가하였다. 지료 내 PAE 고분자의 흡착 엔탈피는 -27~-29 kJ/mol이며 저에너지 물리흡착임이 규명되었다.

• 한국수산과학회지
• /
• 제28권4호
• /
• pp.412-420
• /
• 1995

일정한 에너지를 함유한 사료내의 에너지 /단백질의 비를 11.5, 8.7, 7.0으로 각각 다르게 제조한 사료를 조피볼락, S. schlegeli이 치어에 공급시킨 후 24시간동안 2시간 간격으로 산소소비율과 암모니아 질소배설률을 측정하고 어체를 분석하여 이들에 미치는 사료내 에너지 /단백질비의 영향을 알아보았다. 사료 I, IIl, III을 각각 공급시킨 실험군의 평균산소소비율은 각각 $0,93\pm0.02^a,\;0.92\pm0.02^a\;and\;1.03\pm0.03^bml\;O_2/g/h$ml 이었다. 즉, 사료 III 공급군의 평균산소소비율이 다른 사료공급군에 비해 유의하게 높았다. 사료 공급 후 24시간동안 평균 암모니아 질소배설률은 사료내 에너지/단백질비가 증가함에 따라 증가하였으며, 사료 I, II, III의 공급군에서 평균 암모니아 배설률은 각각 $9.14\pm0.39^a,\;12.41\pm 0.53^a\;and\;14.89\pm0.55^c\;{\mu}g\;N/g/h$ 로 나타났고 각 실험군간의 평균암모니아 배설률값들은 모두 유의한 차를 보이고 있다 (P<0.05). 어체내 단백질 함량은 사료 II의 공급군에서 $62.2\%$로 가장 높게 나타났으며, 사료 I, II 공급군에 비해 유의하게 높았다 (P<0.05). 그리고 체내 지질 함량은 사료 II의 공급군에서 $16.0\%$로 가장 낮게 나타났고, 사료 I의 공급군에서는$23.2\%$로 가장 높게 나타났다. 회분함량은 에너지/단백질비가 낮아짐에 따라 약간씩 증가하며 탄수화물 함량은 사료 I에서 $5.51\%$로 가장 높게 나타났다. 그러나 지질, 회분 및 탄수화물의 함량은 사료 I, II, III의 공급군간에 유의한 차이는 없었다 (P>0.05). 따라서 본 실험에서는 사료 II가 생리학적인 측면에서 관찰한 결과 조피볼락 치어에 대해 가장 적합한 것으로 여겨진다.