• Title/Summary/Keyword: electrostatic field

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Thermodynamics of Partitioning of Substance P in Isotropic Acidic Bicelles

  • Baek, Seung Bin;Lee, Hyeong Ju;Lee, Hee Cheon;Kim, Chul
    • Bulletin of the Korean Chemical Society
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    • v.34 no.3
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    • pp.743-748
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    • 2013
  • The temperature dependence of the partition coefficients of a neuropeptide, substance P (SP), in isotropic acidic bicelles was investigated by using a pulsed field gradient nuclear magnetic resonance diffusion technique. The addition of negatively charged dimyristoylphosphatidylserine to the neutral bicelle changed the SP partitioning a little, which implies that the hydrophobic interaction between the hydrophobic residues of SP and the acyl chains of lipid molecules is the major interaction while the electrostatic interaction is minor in SP binding in a lipid membrane. From the temperature dependence of the partition coefficients, thermodynamic functions were calculated. The partitioning of SP into the acidic bicelles is enthalpy-driven, as it is for small unilamellar vesicles and dodecylphosphocholine micelles, while peptide partitioning into a large unilamellar vesicle is entropy-driven. This may mean that the size of lipid membranes is a more important factor for peptide binding than the surface curvature and surface charge density.

Analysis of LED reliability using SPICE-based 3-dimensional circuit model (3차원 SPICE 회로모델을 이용한 LED 신뢰성 분석)

  • Kim, Jin-Hwan;Yu, Soon-Jae;Seo, Jong-Wook
    • Proceedings of the IEEK Conference
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    • 2008.06a
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    • pp.391-392
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    • 2008
  • A SPICE-based 3-dimensional circuit model of Light-Emitting Diode(LED) was modified include the reverse breakdown properties. The new model is found to be accurate to study the failure mechanisms of LEDs under electrostatic discharge (ESD) and electronic overstress (EOS). It was found that the permanent damages under heavy reverse stress is mainly due to the high electric field strength in P-GaN layer.

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Aspects of Hard Breakdown Characteristics in a 2.2-nm-thick $SiO_2$ Film

  • Komiya, Kenji;Omura, Yasuhisa
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.2 no.3
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    • pp.164-169
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    • 2002
  • This paper mainly discusses the hard breakdown of 2.2-nm-thick $SiO_2$ films. It is shown that the hard breakdown event of a 2.2-nm-thick $SiO_2$ film greatly depends on the applied electric field. It is strongly suggested that the local weak spots created by applying a low initial stress to a 2.2-nm-thick $SiO_2$film resist the onset of hard breakdown. In other words, it is anticipated that the stored electrostatic energy is fast dissipated by trap-assisted tunneling in 2.2-nm-thick $SiO_2$ film. Consequently, it is strongly suggested that 2.2-nm-thick $SiO_2$ films are intrinsically quite robust.

A Numerica analysis on the lift-off motion of Free Conducting Particle in GIS (GIS내에 함유된 자유 도전성 파티클의 거동해석)

  • Lee, Bang-Wook;Koo, Ja-Yoon
    • Proceedings of the KIEE Conference
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    • 1996.07c
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    • pp.1925-1928
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    • 1996
  • In this work, the behavior of conducting wire type particles existing inside the cylinder type coaxial electrode has been systematically investigated by charge simulation method and electrostatic force analysis from the view point of the acquired charging before being lifted off into the gap under the high ac voltage. Spheroidal charge are adopted as a image charge for the CSM analysis in order to calculate the acquired charges of the particles which are erected on the surface of the outer electrode. For this purpose, different material of the particle and their lengths and diameters have been considered in view to calculate their lift-off field, acquired charge and to understand their effect on the lift-off voltage. The results imply that the particle lengths and diameter have an different influence on the particle behavior in GIS system.

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A Study on The Distribution of Surface Charge Density on Polymer Insulators (고분자애자의 표면전하밀도 분포에 관한 연구)

  • Yang, J.J.;Hwang, B.M.;Kim, K.S.;Lee, J.H.
    • Proceedings of the KIEE Conference
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    • 1997.11a
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    • pp.354-356
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    • 1997
  • In this paper, we study the distribution of surface charge density on polymer insulators. The electric field of polymer insulators is calculated by axisymetric 3-D FEM with dc source. And the surface charge density is calculated by electric scalar potential and boundary condition for electrostatic fields. Simulation model is the inclined type polymer insulator with a shed.

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Potential-Field-Based Anycast Routing in Large-Scale Wireless Mesh Networks : A Distributed Algorithm based on Finite Difference Method (광역 무선 메쉬 네트워크에서 포텐셜 필드 기반 애니캐스트 라우팅 : 유한 차분법 응용 분산 알고리즘)

  • Jung, Sang-Su;Kserawi, Malaz;Rhee, June-Koo Kevin
    • Journal of KIISE:Computing Practices and Letters
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    • v.16 no.6
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    • pp.683-687
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    • 2010
  • In this paper, we propose an anycast routing scheme for large-scale wireless mesh networks, which requires only one-hop local information with no flooding overhead. We develop an analytical model for anycast mesh networks based on an electrostatic theory. A finite difference method contributes to achieving gateway load balancing with constant control overheads. We verify the performance of the proposed scheme by simulations.

A study on the effects of variously configured magnets on the characteristics of inductively coupled plasma (자장의 배열 및 형태가 유도결합형 플라즈마에 미치는 효과에 관한 연구)

  • 황순원;이영준;유지범;이재찬;염근영
    • Journal of the Korean institute of surface engineering
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    • v.32 no.4
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    • pp.513-520
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    • 1999
  • In this study, we investigated the effects of variously configured magnets on the characteristics of the plasmas to enhance plasma uniformity and density of an inductively coupled plasma source. As the magnets, Helmholtz type axial electromagnets and various multi-dipole magnets types around the chamber wall were used. To characterize the plasma as a function of the combination of the magnets and magnetic field strengths, ion density, electron temperature, and plasma potential were measured using an electrostatic probe along the chamber diameter for Ar plasmas. The measured maximum ion densities were $8$\times$10^{ 11}$$cm^{-3}$ with 600W inductive power and at 5mTorr of operational pressure and the uniformity of ion density was less than 5.9% at 2mTorr of operational pressure. The combination of an optimized multi-dipole magnet type and an axial electromagnet showed the lowest electron temperature (3eV) and plasma potential ($34V{p}$ )

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Changes of Chemical Concentrations during Pulsed Plasma Process of Silane (실란 펄스 플라즈마 공정에서의 화학농도 변화)

  • Kim, Dong-Joo;Kim, Kyo-Seon
    • Journal of Industrial Technology
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    • v.25 no.A
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    • pp.141-149
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    • 2005
  • We investigated numerically the evolutions of several chemical species which are important for film growth and particle generation in the pulsed $SiH_4$ plasmas. During the plasma-on, the $SiH_x$ concentration increases with time mainly by the generation reaction from $SiH_4$, but, during the plasma-off, decreases because of the hydrogen adsorption reaction. During the plasma-on, the concentrations of negative ions increase with time by the polymerization reactions of negative ions and those become almost zero in the sheath regions because of the electrostatic repulsion. During the plasma-off, the concentrations of negative ions decrease with time by the neutralization reactions with positive ions and some negative ions can diffuse toward the sheath regions because there is no electric field inside the reactor. The polymerized negative ions of higher mass can be reduced successfully by using the pulsed plasma process.

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The Behavior of Negative Ions in Silane Plasma Chemical Vapor Deposition (실란 플라즈마 화학증착에서의 음이온거동)

  • Kim, Kyo-Seon
    • Journal of Industrial Technology
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    • v.14
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    • pp.63-75
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    • 1994
  • The objective of this research is to analyze the phenomena of negative ion behavior in silane plasma chemical vapor deposition. Based on the plasma chemistry, the model equations for the formation and transport of negative ions were proposed and solved. The evolutions of gaseous species along the reactor were presented for several conditions of process variables such as reactor pressure, total gas flow rate, and electric field. Based on the model results, it is found that : (1) The concentration profiles of positive ions show the sharp peaks at the center of plasma reactor. (2) Most of negative ions are located in bulk plasma region, because the negative ions are excluded from the sheath region by electrostatic repulsion.

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QSAR Studies on 6-Nitroquipazine Analogues as Serotonin Transporter

  • Lee, In-Young;Lee, Kyung-A;Lee, Bon-Su;Chi, Dae-Yoon;Kim, Chan-Kyung
    • Bulletin of the Korean Chemical Society
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    • v.27 no.12
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    • pp.1969-1975
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    • 2006
  • 3D-QSAR model that correlates the biological activities with the chemical structures of quipazine derivatives acting on the serotonine transporter (SERT) was developed by comparative molecular field analysis (CoMFA). Total 8 models were constructed and a more accurate model, using close 1 $\AA$ grid spacing and StDev*Coefficients weight value gave better results. The contour maps with the best model, the resulting cross-validated correlation ($q^2$ : 0.744), and non-cross-validated correlation ($r^2$ : 0.966) indicate the steric and electrostatic environment of inhibitors in the SERT binding pocket. This study can be used as a putative picture of the pharmacophore in the design of novel and potent inhibitors.