• Journal of the Korean Chemical Society
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• v.39 no.5
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• pp.356-363
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• 1995

The chemical behavior of the transition metal (Nb4+ and Mo4+) complexes with organoligand (dichloro-bis(η-cyclopentadienyl) has been investigated by the UV/vis-spectrophotometric, magnetic, and electrochemical method. The two or three energy absorption bands are observed by the spectra of these complexes. The magnitude of crystal field splitting energy, the spin pairing energy and bond strength was obtained from the spectra of the complexes. These are found to be delocalization, low-spin state, and strong bonding strength. The magnetic dipolemoment are found to be paramagnetic and diamagnetic complexes. The redox reaction processes of complexes were investigated by cyclic voltammetry in aprotic media. As a result the redox reaction proceses of Nb-C complex was couple-single reaction with diffusion and reaction current one electron process, and also Mo-C complex was couple-single reaction with reaction current of one electron process.

• Journal of the Korean Chemical Society
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• v.40 no.1
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• pp.65-71
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• 1996

The chemical behaviour of the Eu(Ⅲ) complexes with organic ligands(tris[3-(trifluoromethylhydroxymethylene-camphorato)]) and tris[3-heptafluoropropylhydroxymethylene-camphorato)] has been investigated by the UV/vis-spectrophotometric, magnetic, and electrochemcial methods. The two or three energy absorption bands are observed by the spectra of these complexes. The magnitude of crystal field splitting energy, the spin pair energy and strength were obtained from the spectra of the complexes. These complexes are found to be delocalization, low-spin state, and strong bonding strenth of electron configuration. The magnetic dipolemoment are found to be diamagnetic. The redox reaction processes of complexes were investigated by cyclic voltammetry in aprotic solvent. The redox reaction processes of complexes are turned out to be single or double reaction with respect to one electron diffusion current.

• Journal of the Korea Society of Computer and Information
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• v.17 no.11
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• pp.47-52
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• 2012

Today the Internet is being used in all areas. However, part of everyday life, the lack of ethics on the Internet, the Internet lies in state. Especially the youth, should exploit the anonymity. As a result, has caused many problems. Fps online game from young people enjoy the use of profanity and slang, and increasing the damage of cyber violence has also increased. The damage type of cyber violence, abusive and slang, and the age, the lower the investigation was to increase the damage. Lot of publicity and public service advertising is in progress in order to prevent problems, but its expected effects is lacking. In addition, using abusive and slang words, This is a fundamental and provide a service to handle deleted or blinds, but if you can not see the solution. In this paper suggests the language convert that can be applied to Fps online games. Language the conversion process, if applicable to the game, the abusive and slang language, helps to purify. Proposed language the conversion process is expected to reduce cyber violence used abusive and slang.

• Journal of Magnetics
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• v.13 no.1
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• pp.23-29
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• 2008

The magnetic and other physical characteristics of $Mn_xSi_{1-x}Te$ have been investigated by electron magnetic resonance (EMR), X-ray diffraction (XRD) and other experiments. $Mn_xSi_{1-x}Te$ is found to have corundum structure for manganese contents up to 10% and also to be ferromagnetic for temperatures below 80 K. While ferromagnetic resonance signal coexists with the usual paramagnetic resonance signal, invariance of the g-factor inferred from the electron paramagnetic resonance signals throughout all temperature ranges clearly confirms that the manganese ions are in the electronic 3d5 state. The temperature dependence of EMR line-width is the same as other diluted magnetic semiconductors. From the EMR signals relaxation times $T_2$ and $T_1$ of $Mn_xSi_{1-x}Te$ compounds are estimated to be about $4.4{\times}10^{-10}s$ and $9.3{\times}10^{-8}s$ respectively and are found to vary slightly with temperature or composition change. Exchange narrowing of the EMR line-width becomes dominant for the sample in which the substitution ratio, x = 30%. For one sample, in which x = 0.5%, spin glass-like behavior is indicated by EMR signals for temperatures lower than 60 K. This behavior may authentic for samples within a certain range of x.

• Journal of the Institute of Electronics Engineers of Korea CI
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• v.47 no.4
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• pp.102-108
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• 2010

The photovoltaic system changes solar energy into DC by solar cell and this DC is inverted into AC which is used in general houses by inverter. Recently, the use of power of the photovoltaic system is increased. Therefore, the study of 3 phase solar system to transmit large power is very important. This paper proposes a method that finds simply faults and diagnoses the switch open faults of 3-phase pulse width modulation (PWM) inverter of grid-connected photovoltaic system. The proposed method in $\alpha\beta$ plane uses the patterns of trajectory image as the characteristic parameters and differenciates a normal state and open states of switches. Then, the result is made into tree. The tree is composed of 21 fault patterns and the parameters to classify faults are a shape, a trajectory area, a distributed angle, and a typical vector angle. The result shows that the proposed method diagnosed fault diagnoses, classified correctly them, and made a pattern tree by fault patterns.

• Bulletin of the Korean Chemical Society
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• v.32 no.8
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• pp.2683-2688
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• 2011

Silica-manganese oxides with a core-shell structure were synthesized via precipitation of manganese oxides on the $SiO_2$ core while varying the concentration of a precipitation agent. Elemental analysis, crystalline property investigation, and morphology observations using low- and high-resolution electron microscopes were applied to the synthesized silica-manganese oxides with the core-shell structure. As the concentration of the precipitating agent increased, the manganese oxide shells around the $SiO_2$ core sequentially appeared as $Mn_3O_4$ particles, $Mn_2O_3+Mn_3O_4$ thin layers, and ${\alpha}-MnO_2$ urchin-like phases. The prepared samples were assembled as electrodes in a supercapacitor with 0.1 M $Na_2SO_4$ electrolyte, and their electrochemical properties were examined using cyclic voltammetry and charge-discharge cycling. The maximum specific capacitance obtained was 197 F $g^{-1}$ for the $SiO_2-MnO_2$ electrode due to the higher electronic conductivity of the $MnO_2$ shell compared to those of the $Mn_2O_3$ and $Mn_3O_4$ phases.

• Journal of the Korean Geographical Society
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• v.50 no.5
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• pp.557-569
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• 2015

This study aims to illustrate the national images of United Kingdom, France, and Germany based on the descriptions in the Korean middle school Social Studies textbooks in comparative perspective. In order to identify and compare the national images of the three countries, the author uses a framework for analysis consisting cognitive, normative, and relational factors. The main findings are as follows. First, the most frequently shown topics and issues are democratic institutions in the case of United Kingdom, respect for human rights in the case of France, and sustainable environment in the case of Germany. Second, for all the three countries, the most frequent factor among the three is cognitive one, followed by normative and then relational factors. Third, United Kingdom is described as a country of social unrest and conflict as well as a democratic country with long history and tradition. Fourth, France is described as a country of respect/abuse of human rights, potential for high tech industry, and largest agricultural state in Europe. Fifth, Germany is described more as a country of a leading country for global environmental protection than as a country with electronic and information technology.

• Journal of the Korean Ceramic Society
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• v.51 no.1
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• pp.51-56
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• 2014

Mixed ionic and electronic conducting $K_2NiF_4$-type oxide, $Nd_{2-x}Sr_xNiO_{4+\delta}$ (x = 0, 0.4, 0.6) powders were synthesized by a solid-state reaction technique and solid oxide fuel cells consisting of a $Nd_{2-x}Sr_xNiO_{4+\delta}-GDC$ cathode, a Ni-YSZ anode and 8YSZ as an electrolyte were fabricated. The effect of strontium substitution for neodymium on the electrical and electrochemical properties was examined. The electrical conductivity increased with an increase in the Sr doping content, while it appears that the excess oxygen (${\delta}$) decreased. Sr doping into $Nd_2NiO_{4+\delta}$ resulted in an increase in the cathode polarization resistance and an decrease in the power density of the cell. These phenomena may be associated with the decreased amount of excess oxygen noted in the $Nd_{2-x}Sr_xNiO_{4+\delta}$ cathode.

• Journal of the Korean Ceramic Society
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• v.54 no.4
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• pp.323-330
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• 2017

To understand the defect chemistry of multiferroic $BiFeO_3-based$ systems, we synthesized nonstoichiometric $Bi_{1+x}FeO_{3{\pm}{\delta}}$ ceramics by conventional solid-state reaction method and studied their structural, dielectric and high-temperature charge transport properties. Incorporation of an excess amount of $Bi_2O_3$ lowered the Bi deficiency in $BiFeO_3$. Polarization versus electric field (P-E) hysteresis loop and dielectric properties were found to be improved by the $Bi_2O_3$ addition. To better understand the defect effects on the multiferroic properties, the high temperature equilibrium electrical conductivity was measured under various oxygen partial pressures ($pO_2{^{\prime}}s$). The charge transport behavior was also examined through thermopower measurement. It was found that the oxygen vacancies contribute to high ionic conduction, showing $pO_2$ independency, and the electronic carrier is electron (n-type) in air and Ar gas atmospheres.

• The Journal of the Institute of Internet, Broadcasting and Communication
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• v.15 no.5
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• pp.147-154
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• 2015

Satellite broadcasting networks, like if you have if you have just received information that everyone must bring the required security attributes this earth should be done as encryption. In this paper, a satellite communication network AH additional security header in transport mode IPsec VPN by applying the SHA-256 and MD-5 authentication algorithm to authenticate the data portion Error rate and analyze the BER and Throughput. First, to generate a normal IP packet added to IPsec transport mode security header AH were constructed internal authentication data by applying the SHA-256 and MD-5 algorithm. Channel coder was applied to the Rate Compatible Punctured Turbo Codes, packet retransmission scheme Hybrid-ARQ Type-II and Type-III were used. Modulation method was applied to the BPSK, the wireless channel Markov channel (Rician 80%, Rayleigh 20% and Rician 90%, Rayleigh 10%) as an authentication algorithm according to the satellite channel state analyzed how they affect the error rate and Throughput.