• 한국방사성폐기물학회:학술대회논문집
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• 한국방사성폐기물학회 2005년도 Proceedings of The 6th korea-china joint workshop on nuclear waste management
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• pp.39-50
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• 2005

Electrolytic reduction of uranium oxide to uranium metal was studied in a $LiCl-Li_{2}O$ molten salt system. The reduction mechanism of the uranium oxide to a uranium metal has been studied by means of a cyclic voltammetry. Effects of the layer thickness of the uranium oxide and the thickness of the MgO on the overpotential of the cathode and the anode were investigated by means of a chronopotentiometry. From the cyclic voltamograms, the decomposition potentials of the metal oxides are the determining factors for the mechanism of the reduction of the uranium oxide in a $LiCl-3\;wt{\%} Li_{2}O$ molten salt and the two mechanisms of the electrolytic reduction were considered with regards to the applied cathode potential. In the chronopotentiograms, the exchange current and the transfer coefficient based on the Tafel behavior were obtained with regard to the layer thickness of the uranium oxide which is loaded into the porous MgO membrane and the thickness of the porous MgO membrane. The maximum allowable currents for the changes of the layer thickness of the uranium oxide and the thickness of the MgO membrane were also obtained from the limiting potential which is the decomposition potential of LiCl.

• 한국염색가공학회지
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• 제14권4호
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• pp.249-258
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• 2002

Natural silk is formed by two proteins : the crystalline fibroin (inside the silk thread) and amorphous sericin (as a tube outside the thread). The degumming process is used to eliminate the external sericin prior to dyeing ; generally it makes use of soaps at about pH 10. Sericin is the protein constituent that "gums"together the fibroin filaments of cocoon silk. It constitutes about 25% of the weight of the cocoon, is soluble in hot water and "gels" on cooling. The removal of sericin from raw silk, known as degumming, is a simple but important process usually employing hot dilute soap or alkaline solution and occasionally dilute acids or enzymic methods. During degumming, alkali is taken up by the sericin and the free acid from the soap is formed ; this may be deposited on the fiber, reducing the rate of degumming and protecting it from hydrolysis. Alkali is often added to maintain or restore the pH of the baths, but it is rarely used alone, since it leaves the silk rather harsh in handle. If complete sericin removal is required as for printing, sodium carbonate may be added. If the pH of the bath exceeds 11, the fibroin is attacked. Recently, According to the development of electrolysis, we can be obtained the electrolytic reduction water(above pH 11.5) and electrolytic oxidation water (below pH 3). The aim of this work was to study a degumming process using electrolytic water and a possibility of sericin recovery. The new degumming process used electrolytic water operates at $95^\circ{C}$ for 2hr. without any reagents. The wastewater of this process are formed by a solution of sericin in water. This conditions suggest the study of a possible recovery of this protein (sericin) which has an amino acid composition suitable for many used in cosmetics, textile finishing agents, animal feeding, etc. The degumming process using electrolytic water is available to reduce treatment costs and pollute and at the same time to recover sericin.

• 조명전기설비학회논문지
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• 제17권6호
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• pp.77-82
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• 2003

본 논문에서는 강한 불평등전계를 형성시킬 수 있는 다선형전극을 강전해수 발생장치내에 설치하여 전계집중효과에 의해 발생되는 기포내의 선행방전의 형태와 기포방전이 수소이온농도와 산화환원전위반응에 미치는 영향을 검토하고자 하였다. 실험결과, 강전해수 발생장치내의 양전극측을 다선형으로 함으로써 양전극측에서 발생되는 기포내에서 비유전율 차이에 의한 기포내의 선행방전을 관찰할 수 있었다. 그리고 기포방전에 의해 발생된 이온들이 강전해수 발생장치내에 용해됨으로써 전해수의 이온농도를 증가시켰다. 이때 발생된 고농도의 이온들을 분리집속 시키고 산화환원작용을 크게 증가시켜 고농도의 강전해수를 발생시킬 수 있었다.

• 전기학회논문지P
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• 제56권2호
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• pp.104-108
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• 2007

This paper deals with an approach to the reduction of potential rise according to the buried depth of structure. In order to analyze the surface potential rise of structure, an electrolytic tank which simulates the semi-infinite earth has been used. The potential rise has been measured and analyzed for types of structure using an electrolytic tank experimental apparatus in real time. The structure models were designed through reducing real buildings and fabricated with four types on a scale of one-one hundred sixty. When a test current flowed through structure models, potential gradient was the highest value in case of the outline frame type(structure model A). The distributions of surface potential rise are dependent on the resistivity and absorption percentage in concrete attached to structure model.

• 조명전기설비학회논문지
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• 제29권9호
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• pp.81-88
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• 2015

LED has been great attentions in lighting industry because of its long life-time, high efficiency, excellent light output characteristics. However, the life-time of the LED driving system is decreased because of the electrolytic capacitor which is used in the power conversion system for driving LED lighting. Therefore the capacitance reduction methods have been studied to replace an electrolytic capacitor with film or tantalum capacitor. This paper presents the Single stage PFC flyback converter with the simplified third harmonic current injection circuit to reduce output capacitance and the proposed system is theoretically analyzed and verified through the experiment.

• 해양환경안전학회지
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• 제8권2호
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• pp.23-27
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• 2002

Reballasting at sea, as recommended by the IMO guidelines, currently provides the best-available measure to reduce the risk of transfer of harmful aquatic organisms, but is subject to serious ship-safety limits. It is therefore extremely important that alternative, effective ballast water management and treatment methods are developed as soon as possible, to replace reballasting at sea. Filtration-Ultraviolet radiation-Electrolytic process (FUE) was evaluated for disinfection of seawater used In ballast water Optimal current density and UV light intensity were 2.0A/dm$^2$ and, 220㎼/$\textrm{cm}^2$/m with which 100% reduction time was 2sec in a Ultraviolet radiation-Electrolytic process. This study showed that FUE process was effective for the disinfection of commonly isolated bacteria and bacillus from ballast water.

• 조명전기설비학회논문지
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• 제30권3호
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• pp.59-64
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• 2016

Applications of electrolytic ion water generated by the oxidation-reduction have gradually been expanded due to their strong sterilizing power and a surface active force. We demonstrate the effect of the multi-layer type electrode for effective ion water generation. The multi-layer type electrode has ability to generate stronger acid and alkali water by increase of the electrode reactive area. Also power consumption efficiency enhances because the electrodes disposed in middle position of the reactive cell raise the usage rate by overlapped effect as an electrolysis electrode.

• Journal of Electrochemical Science and Technology
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• 제4권2호
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• pp.71-80
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• 2013

The study of methyl viologen ($MV^{2+}$) mediated oxygen reduction in electrolytic ethanol media possesses potential application in the electrochemical synthesis of hydrogen peroxide mainly due to the advantages of the much increased solubility of molecular oxygen ($O_2$) and high degree of reversibility of $MV^{2+/{\bullet}+}$ redox couple. The diffusion coefficients of both $MV^{2+}$ and $O_2$ were investigated via electrochemical techniques. For the first time, $MV^{2+}$ mediated $O_2$ reduction in electrolytic ethanol solution has been proved to be feasible on both boron-doped diamond and micro-carbon disc electrodes. The electrocatalytic response is demonstrated to be due to the radical cation, $MV^{{\bullet}+}$. The homogeneous electron transfer step is suggested to be the rate determining step with a rate constant of $(1{\pm}0.1){\times}10^5M^{-1}s^{-1}$. With the aid of a simulation program describing the EC' mechanism, by increasing the concentration ratio of $MV^{2+}$ to $O_2$ electrochemical catalysis can be switched from a partial to a 'total catalysis' regime.

• 한국염색가공학회지
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• 제18권6호
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• pp.43-48
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• 2006

Electrolytic water(EW), studied in recent decades in the Japan, Russia and United State of America, have shown promise as a method of disinfection whereby low levels of free chlorine, sodium hypochlorite, or hypochlorous acid may be produced in situ in Nacl-containing solution. These methods have shown promise in destruction of microorganisms in medical, dental environment, and in the agriculture and food industry. A recently EW treatment system was evaluated for reducing scouring agent and other surfactants in the washing and scouring process of textile industry Unfortunately, there is, to my knowledge, no serious studies of the properties of EW for textile industry In order to study the characteristics of EW and confirm the possibility of applications in textile industry processes, the pH, surface activity, penetration force, surface tension, and contact angle of EW was measured under various conditions. In general terms, What all this shows is that there is fundamental difference between the properties of EW and that of distilled water.

• 한국안전학회지
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• 제29권1호
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• pp.7-14
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• 2014

Inverter module, which feeds the converted power to the traction motor for EMU. Consists of the power semiconductors with their gate drive unit(GDU)s and the control computer for driving, voltage, current and speed controls. Electrolytic condenser, connected to the gate drive unit and a core component to drive the power semiconductor, has problems such as reduction in lifetime and malfunction caused by electrical and mechanical characteristic changes from heat generation during high speed switching for generation of stable power. In this study, To check the service life of electrolytic condenser, the test was carried out in two ways. First, In the case of accelerated life testing of condenser, the Arrhenius model is a way of life testing. Another way is to analyze the reliability of the failure data by the method of parametric data analysis. Eventually, life time by accelerated life test than a method of failure data analysis(Weibull distribution) was found to be slightly larger output.