• 제목/요약/키워드: electrolytic decomposition

검색결과 13건 처리시간 0.021초

Characteristics of Decomposition for Refractory Organic Compounds in Aqueous Solution by Sonolysis and Electrolysis (초음파와 전기분해를 이용한 수중의 난분해성 유기물질의 분해 특성)

  • Jeong, Jae-Baek;Lee, Seong-Ho;Bae, Jun-Ung
    • Journal of the Korean Chemical Society
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    • 제50권6호
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    • pp.454-463
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    • 2006
  • refractory organic compounds in aqueous solution are not readily removed by the existing conventional wastewater treatment process. In recent years, the sonolysis and electrochemical oxidation process had been shown to be promising for wastewater treatment due to the effectiveness and easiness in operation. This study was performed to investigate the characteristics of sonolytic and electrolytic decomposition as the basic data for development of the wastewater treatment process. Trichloroethylene(TCE) and 2,4- dichlorophenol(2,4-DCP) were used as the samples, and their destruction efficiency were measured with various operating parameters, such as initial solution concentration, initial solution pH, reaction temperature, sonic power and current density. Also, the decomposition mechanism conformed indirectly with the effect of NaHCO3 as a radical scavenger on the decomposition reaction. Thermal decompositon reaction is predominant for TCE but thermal and radical decompositon reactions were dominant for 2,4-DCP. Results showed that the destruction efficiencies of all samples were above 65% within 120 minutes by sonolysis and electrolysis at the same time, and were increased with increasing initial concentration, sonic power and current density. Destruction efficiency of TCE was high in the acidic solution, but 2,4-DCP showed high destruction efficiency in basic solution.

Fabrication of Flow Cell Using Carbon Fiber and Electrochemical Decomposition Characteristics for Organic Dyes (탄소섬유전극을 이용한 흐름형 전기분해조 제작 및 유기염료의 전기화학적 분해 연구)

  • Park, Deog-Su
    • Journal of Environmental Science International
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    • 제21권11호
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    • pp.1371-1377
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    • 2012
  • The simulated dyes solution containing Basic Red 46(BR 46), Yellow 21(Y 21), and Maxilon Blue 30(MB 30) were electrochemically oxidized using carbon fiber as an anode. The electrolyses were performed in a electrolytic flow cell constructed by Vycor glass tube. The carbon fiber was positioned in the inside of Vycor glass tube and platinum wire coiled around outside of tube as a cathode. Several operating variables, such as current, time, pH and flow rate of solution were studied. Increasing current density would lead to a corresponding increase in the dye removal efficiency 99.2 % at a 200 mA. The electrolyses time could also improve and removal efficiency was about 99 % after 1.5 hours of electrolyses. The removal efficiency was increased with the increase of flow rate of solution and optimum flow rate was 5 mL/min. THe pHs of solution affect the removal efficiency. The removal efficiency was decreased with the increase of pH of solution and optimum pH was 5.05 (0.1 M $KNO_3$).

On a Cleaning of COVID-19 Prevention Masks with Electrolytic Decomposition Water (전기분해수로 코로나방역용 마스크의 세정에 관한연구)

  • Tian, Zhixing;Bae, Myung-Jin
    • The Journal of the Convergence on Culture Technology
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    • 제8권1호
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    • pp.591-596
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    • 2022
  • Various COVID-19 quarantine guidelines and measures are being taken by country at the WHO, but the number of confirmed cases has not decreased significantly. In order to prevent the inflow and outflow of COVID-19 through individual droplets, it is mandatory to wear a mask anytime, anywhere. However, as virus bacteria entering the mask amplify, it pollutes the mask and causes a disgusting smell. In this paper, a new method of preventing the spread of COVID-19 was proposed by sterilizing the mask with a dental gait spray introduced into the mask that has been used for a long time. Dental gargle water is usually produced by electrolysis of tap water, and the unstable ion water (HOCl) dissolved in water penetrates the cell barrier of various viruses and fails to act in its nucleus, causing water to self-purify. As a result of the experiment, when the mask used for a long time was washed with gargle water spray, the washed mask was dried after 10 minutes, and the smell of virus droplets or saliva almost disappeared. In particular, as a result of MOS testing the fit of the subjects who participated in the mask cleaning, it was excellent at 4.4 on average. Therefore, the mask was disposable, but if the spray was washed in the proposed method more than twice a day, the mask could be used in a comfortable state for more than a week.