• Title/Summary/Keyword: electrolyte concentration

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Fabrication of CO2 Sensor Membrane by Photolithographic Method (사진식각법을 이용한 CO2 센서 감지막의 제조)

  • Park, Lee Soon;Kim, Sang Tae;Koh, Kwang-Nak
    • Applied Chemistry for Engineering
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    • v.9 no.1
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    • pp.6-12
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    • 1998
  • A FET(Field Effect Transistor) type dissolved $CO_2$ sensor based on Severinghaus type $CO_2$ sensor was fabricated by the photolithographic process. The sensor consists of Ag/AgCl reference electrode and membranes (hydrogel membrane and $CO_2$ gas permeable membrane) on the pH-ISFET base chip. Ag/AgCl reference electrode was fabricated as follows. Ag layer was thermally evaporated and then its upper surface was chemically chloridized into the AgCl. The hydrogel used as an internal electrolyte solution was fabricated by a photolithographic method using 2-hydroxyethyl methacrylate(HEMA) and acrylamide. $CO_2$ permeable membrane on the top of the hydrogel layer was formed by photolithographic process with UV-oligomer. The FET type $pCO_2$ sensor fabricated by photolithographic method showed good linearity within the concentration range of $10^{-3}{\sim}10^0mole/{\ell}$ of dissolved $CO_2$ in aqueous solution with high sensitivity.

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A study on the removal of As, Sb, Bi from the copper sulfate solutions by Ion exchange resin containing Aminophosphosphonic acid as a functional group (황산동용액(黃酸銅溶液)에서 Aminophosphosphonic acid 관능기를 가진 이온교환수지에 의한 As, Sb, Bi 제거(除去)에 관한 연구(硏究))

  • Ahn, Jae-Woo;Seo, Jae-Seong
    • Resources Recycling
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    • v.21 no.5
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    • pp.50-57
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    • 2012
  • A comparative study has been carried out on the removal of impurities such As, Sb, Bi from the copper sulfate solution by ion exchange resin containing aminophosphosphonic acid as functional group. The various parameters which affect the removal of impurities; such as the reaction temperature, the reaction time, the amount of ion-exchange resins, the concentration of sulfuric acid in electrolyte, were studied. The basic experimental results showed that about 88% of Sb & 94% of Bi can be adsorbed in these chelate resins and removed from the copper sulfate solutions but As was removed below 10% from the solutions. And the selective elution of Bi and Sb from the adsorbed ion exchange resin also can be achieved by $H_2SO_4$ or HCl solutions. The results also showed that 98.1% of Sb and 96.6% of Bi can be adsorbed from the copper sulfate solutions after 2 Bed-volume of continuous ion exchange column test.

The Effect of Gamitongseong-san(GTS) on Spontaneously Hypertensive Rat(SHR) (가미통성산(加味通聖散)이 자발성 고혈압 흰쥐에 미치는 영향)

  • Choi, Eun-Hee;Lim, Dae-Woong;Jung, Tae-San;An, Ga-Yong;Chun, Hea-Sun;Jeon, Sang-Yun;Hong, Seok
    • The Journal of Internal Korean Medicine
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    • v.31 no.3
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    • pp.554-568
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    • 2010
  • Objective : This study was examined to investigate the effect of Gamitongseong-san(GTS) extract on spontaneous hypertension. Methods : After administering GTS extract to SHR for 4 weeks, we measured anti-oxygen effects, weight of body, heart and kidney, blood pressure, heart rate, aldosterone, catecholamine, electrolyte, uric acid, and BUN. Results : 1. GTS increased 2,2-diphenyl-1-picrylhydrazyl(DPPH) scavenging activity and superoxide dismutase(SOD) similar activity depending on the concentration. 2. GTS significantly decreased heart weight in spontaneously hypertensive rat. 3. GTS significantly decreased blood pressure and heart rate in SHR. 4. GTS significantly decreased aldosterone. 5. GTS significantly decreased norepinephrine and epinephrine. 6. GTS significantly decreased $K^+$. 7. GTS significantly decreased BUN. Conclusions : These results suggest that GTS may be usefully applied for the treatment of hypertension.

Daily Rhythms and Effect of Short-term Starvation on the of Health Parameters in Olive Flounder Paralichthys olivaceus (넙치(Pralichthys olivaceus)의 혈액건강지표의 활동일주기와 단기절식에 따른 생리적 반응)

  • Noh, Gyeong Eon;Kim, Woo-Jin;Kim, Hyun Chul;Park, Choul-Ji;Park, Jong-Won
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.50 no.5
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    • pp.534-540
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    • 2017
  • This study was conducted to determine the circadian rhythm and the effect of starvation for the health assessment of olive flounder Paralichthys olivaceus, reared under 12:12 LD (light:dark) cycle and fed 1% of their body weight once a day. The blood collection was implemented from 10 fish every 3 hours for a day, and analyzed to serval health parameters of the experimental fish. Plasma cortisol, glucose and total protein concentration reflected diel rhythms with high level of photophase and low level of scotophse despites of glutamic oxalacetic transaminase (GOT) and glutamic pyruvate transaminase (GPT) showing no rhythmicity, while electrolyte (sodium, potassium and chloride ion) concentrations arrived at the peak 18 hour and then slowly down. In the experiment of starvation, the result showed that there were no significant differences of the health parameters between the starved group and the fed. In short, our findings described the existence of circadian cortisol with glucose in flat fish, and indicated that the starvation does not almost affect the health of fish.

Effect of Mulberry Charcoal Treatment on the Growth and Physiological Properties of Kentucky Bluegrass Grown under Salt Stress Condition (뽕나무 숯 처리가 Kentucky Bluegrass의 염해에 따른 생육과 생리적 반응에 미치는 영향)

  • Bae, Euu-Ji;Jeong, Sung-Woo;Park, Nam-Chang;Lee, Kwang-Su;Shin, Hyun-Cheol;Huh, Moo-Ryong
    • Asian Journal of Turfgrass Science
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    • v.25 no.1
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    • pp.112-117
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    • 2011
  • This research was conducted to determine the effect of the pre-treatment of mulberry charcoal on the salt tolerance response in Kentucky bluegrass 'Perfection'. As this results, 400 mM NaCl treatment reduced turf growth such a fresh and dry weight, and induced physiological damages like decreased chlorophyll content and increased electrolyte leakage. The pre-treatment of mulberry charcoal, however, mitigated those growth and physiological responses associated with NaCl stress, regardless of the concentrations of charcoal solution. Furthermore, it was observed that higher K ion concentration by mulberry charcoal pre-treatment reduced Na ion in shoot. This research suggests to be a possibility of planting turf grasses in reclaimed land or higher salt accumulated area using a mulberry charcoal treatment.

Interfacial Features of Colloidal Particles in Aqueous Environment and Change in Its Stability According to Influential Conditions (수중 콜로이드성 고형물의 계면화학적 특성 및 영향 인자 조건에 따른 안정성의 변화)

  • Shin, Sung-Hye;Kim, Dong-Su
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.12
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    • pp.2227-2238
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    • 2000
  • The interfacial features of suspension system made of $CaCO_3$ particles have been investigated for the purpose of designing its effective treatment process. For the examination of variation of electrokinetic potential as a function of pH. the value of potential was observed to shift in the negative direction, which was thought to be due to the adsorption of hydroxide ion on the particle surface. Adsorption of surfactant on suspended particles resulted in the change of surface charge and shift in electrokinetic potential, which was dependent upon the sign of head charge and concentration of surfactant. Addition of inorganic salts affected stability of suspension greatly and sedimentation rate of suspension was influenced by the electric valence and amount of ions produced by dissolution of inorganic coagulants. DLVO theory made it possible to construct a energy profile diagram and a close correlation was found between experimental result and theoretically derived consequences. Non-specific adsorption of indifferent electrolyte resulted in the compression of electrical double layer and specific adsorption induced the shift of IEP and PZC in the opposite direction.

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Modeling and Optimization of High Strength Wastewater Treatment Using the Electro Oxidation Process (전기산화공법을 이용한 고농도폐수 처리공정의 모델링 및 최적화)

  • Lee, Hongmin;Lee, Sangsun;Hwang, Sungwon;Jin, Dongbok
    • Korean Chemical Engineering Research
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    • v.54 no.3
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    • pp.340-349
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    • 2016
  • Electro oxidation system was designed in this study for the reduction of COD (Chemical Oxygen Demand) from high-strength wastewater, produced during refinery turnaround period. First, BDD (Boron Doped Diamond) electrode was synthesized and electro oxidation system of actual industrial wastewater was developed by adopting the synthesized BDD electrode. The experiments were carried out under various operating conditions under certain range of current density, pH, electrolyte concentration and reaction time. Secondly, reaction kinetics were identified based on the experimental results, and the kinetics were embedded into a genetic mathematical model of the electro oxidation system. Lastly, design and operating parameters of the process were optimized to maximize the efficiency of the pretreatment system. The coefficient of determination ($R^2$) of the model was found to be 0.982, and it proved high accuracy of the model compared with experimental results.

Ionic Equilibria in $ZnSO_4-Na_2SO_4-H_2SO_4-NaOH-H_2O$ System ($ZnSO_4-Na_2SO_4-H_2SO_4-NaOH-H_2O$계의 이온 평형)

  • 이만승;박현주;나춘기
    • Resources Recycling
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    • v.11 no.1
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    • pp.19-25
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    • 2002
  • For $ZnSO_4$-$Na_2$$SO_4$-$H_2$ $SO_4$-$NaOH-H_2$O system, pH of solutions with different electrolyte concentrations was measured at $25^{\circ}C$ and ionic equilibria were analyzed by using K-value method. Activity of water and activity coefficients of solutes were calculated by Pitzer equation. The equilibrium concentration and activity coefficients of solutes were calculated from initial experimental conditions. At high ionic strength of 4m, the pH values calculated were in good agreement with those measured. In the experimental ranges of ionic strength of solution from 3.5 to 4.3 m, the mean activity coefcient of $ZnSO_4$calculated agreed well with those obtained from literature.

An Experimental Study on the Property and Stability of W/O Emulsion by Various Structures of Emulsifier (유화제의 구조에 따른 W/O 에멀젼의 특성 및 안정도에 관한 연구)

  • Kim, Woon-Ha;Lee, Kwang-Sik;Lee, Kun-Kook
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.38 no.2
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    • pp.119-131
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    • 2012
  • The W/O emulsion is widely used for cosmetics because of its water-proofing benefit and long-lasting moisturizing effect. However, because of low stability of the W/O emulsion, it is very important to control the concentration of electrolyte and emulsifying agent, and ratio of water phase. Among these factors, we focused on the effects of different structures of emulsifying agents on the change of stability. Emulsifying agents were sorted into polyglyceryl ester, silicone and sugar series. We also examined the emulsifyingability of emulsifier by changing the ratio of normal and silicon oil in the oil phase. Through these experimental results, we figured out the property of w/o emulsion depending on the types of emulsifiers, and observed the stability of emulsion considering the change of particles and viscosity over time.

Characteristics of Chromium Addition on Raney Nickel Catalyst for AFC (AFC용 Raney 니켈 촉매의 크롬 첨가 특성)

  • Lee, Hong-Ki
    • Korean Journal of Materials Research
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    • v.11 no.8
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    • pp.703-707
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    • 2001
  • The effects of chromium addition on the catalytic activity of Raney nickel in alkaline fuel cell (AFC) have been studied. When the catalysts are prepared from various contents of chromium, the electrochemical characteristics shows the highest mass activity of 3.588 A/g. Operating temperature and electrolyte concentration of half cell were $80^{\circ}C$ and 6N KOH, respectively. With the addition of chromium, the particle size is diminished from 12.11 $\mu\textrm{m}$ to 11.07 $\mu\textrm{m}$ and the decrease of particle size contributes to the enlargement of the specific surface area from 0.653 $\m^2$/g to 0.685$\m^2$/g. The residual aluminium contents of Raney nickel surface are considerably influenced by the particle size and chromium acts as sintering inhibitor.

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