• 환경위생공학
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• 제13권3호
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• pp.72-78
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• 1998

For investigation into gas permeation characteristics, the porous alumina membrane with asymmetrical structure, having upper layer with 10 nanometer under of pore diameter and lower layer with 36 nanometer of pore diameter, was prepared by anodic oxidation using DC power supply of constant current mode in an aqueous solution of sulfuric acid. The aluminium plate was pre-treated with thermal oxidation, chemical polishing and electrochemical polishing before anodic oxidation. Because the pore size depended upon the electrolyte, electrolyte concentration, temperature, current density, and so on, the the membranes were prepared by controling the current density, as a very low current density for upper layer of membrane and a high current density for lower layer of membrane. By control of current quantity, the thicknesses of upper layer of membranes were about $6{\;}{\mu}m$ and the total thicknesses of membranes were about $80-90{\;}{\mu}m$. We found that the mechanism of gas permeation depended on model of the Knudsen flow for the membrane prepared at each condition.

• 한국산학기술학회:학술대회논문집
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• 한국산학기술학회 2011년도 춘계학술논문집 1부
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• pp.158-160
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• 2011

본 연구에서는 리튬 금속을 음극소재로 사용하기 위해 수지상 리튬의 성장을 억제하기 위한 지침을 얻기 위한 목적으로 TEM(Transmission Electron Microscope)과 임피던스를 주된 분석 수단으로 이용하여 2. 15 M LiBETI/ PC, 2.04 M $LiClO_4$/ PC 전해질은 1 M LiBETI/ PC, 1 M $LiClO_4$/ PC 전해질보다 얇고 치밀한 SEI(Solid Electrolyte Interphase) 구조를 가지고, 클로로포름에 의해 SEI의 유기물이 녹아 두께가 얇아 졌다. 임피던스를 측정한 결과 두꺼운 두께를 가진 SEI는 저항이 더 크고, 클로로포름 처리 후에는 저항이 커진 것을 확인할 수 있었다.

• 한국표면공학회지
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• 제51권1호
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• pp.27-33
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• 2018

In the present work, we demonstrate the feasibility to form large inner diameter $TiO_2$ nanotubes by anodization of Ti in a HF/ethylene glycol electrolyte. In order to achieve the large inner diameter $TiO_2$ nanotubes, optimization of the anodization condition is required. We discover the key factors in the formation of large inner diameter $TiO_2$ nanotubes are concentration of water in the electrolyte, anodization temperatures, and high-applied potential. Under optimum conditions, the inner diameters of $TiO_2$ nanotubes are 379 nm. The results are approximately 3 folders larger than the general case.

• 한국표면공학회지
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• 제30권4호
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• pp.231-238
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• 1997

Tantalum oxide thin filme has an amorphous structure and a high resistivity. Its stoichiometric structure was $Ta_2O_{5.3}$ and the transmission ratio was 80%. The high resistivity of $Ta_2O_{5.3}$ thin film electrolyte made an EC windows without electrical shottness, but the bleached/colored cur rent was very low because of the low ion conductivith. Upon adding moisture into the system, the $\Delta$T increased upto 25 %. proton concentration increase was the main cases to improve optical property. The influence of adding precious or transition metal film(~100 $\AA$ thickness) in $Ta_2O_5$layer on the color change performance was observed. The metal insertion layers had formed hydroxide and they behaved as a stable proton source. The transmission diffrnece and cycle life were greatly enhanced in the case of Ti inssertion.The $\Delta$T was 50% and the cycle life was 18, 000.

• 한국세라믹학회지
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• 제45권11호
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• pp.662-666
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• 2008

Electrochemical properties of carbon cryogel electrode for the application of composite electrode materials mixed with metal oxide in supercapacitor have been studied. Carbon cryogels were synthesized by sol-gel polycondensation of resorcinol with form aldehyde, followed by a freeze drying, and then pyrolysis in an inert atmosphere. Physical properties of carbon cryogel were characterized by BET, X-ray diffraction (XRD) and scanning electron microscopy (SEM). It is found that carbon cryogel is amorphous material. The electrochemical properties of carbon cryogel were measured by cyclic voltammetry as a function of concentration of liquid electrolyte, galvanostatic charge-discharge with different scan rates and electrochemical impedance measurements. The result of cyclic voltammetry indicated that the specific capacitance value of a carbon cryogel electrode was approximately 150.2 F/g (at 5 mV/s in 6M KOH electrolyte).

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 춘계학술대회 논문집 유기절연재료 전자세라믹 방전플라즈마 연구회
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• pp.88-91
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• 2001

The mechanical properties and surface luminous intensities of copper foil have been studied with variation of the amount of additives into the electrolyte. Especially, organic compound of HEC was added from 0.1 to 10ppm for the propose of increasing the mechanical property and the surface state. The total thickness of electrodeposited copper foil was decreased with increasing the amount of organic compounds. There was not so much significant effect of the current density. It has been observed that mechanical property and surface luminous intensity increase with increasing concentration of organic compounds.

• 대한안전경영과학회:학술대회논문집
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• 대한안전경영과학회 2003년도 추계학술대회
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• pp.335-343
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• 2003

In the electrode fabrication of unit cell, it was ascertained that electrochemical characteristics were greatly increased with 90 wt.% of BP-20, 5 wt.% of Super P and 5 wt.% of mixed binder [P(VdF-co-HFP) : PVP =7 : 3] The self-discharge of unit cell showed that diffusion process was controlled by the ion concentration difference of initial electrolyte due to the characteristics of Electric Double Layer Capacitor (EDLC) charged by ion adsorption in the beginning, but this by current leakage through the double-layer at the electrode/electrolyte interface had a minor effect and voltages of curves were remained constant regardless of electrode material. The electrochemical characteristics of 2.3 V/3,000 F grade EDLC were as follows: 0.35 m of DC-ESR (100 A discharge), 0.14 mof AC-ESR (AC amplitude 100 mV), 2.80 Wh/kg (3.73 Wh/L) of energy density and 4.64 kW /kg (6.19 kW/L) of power density. Power output was compatible with electric vehicle applications, uninterrupted power supply and engine starter, in due consideration of Ragone relations.

• 반도체디스플레이기술학회지
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• 제7권4호
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• pp.45-49
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• 2008

For the commercialization of polymer electrolyte membrane fuel cell (PEMFC), some serious problems such as the decrease of platinum use as catalysts and a larger overpotential of oxygen reduction reaction (ORR) at cathode must be solved. In this study, 20%Pt/C and 20%PtCo/C catalysts for the cathode of PEMFC were synthesized from the chemical reduction method and evaluated using an electrochemical measurement. The ORR activity of synthesized 20%Pt/C and 20%PtCo/C had higher than that of the 20%Pt/C on the market. The synthesized 20%PtCo/C with the cobalt concentration (Pt:Co atomic ratio) from 5 to 20% showed the highest ORR activity.

• 한국시뮬레이션학회논문지
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• 제14권2호
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• pp.45-55
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• 2005

There are electric double layer capacitance, polarization resistance and solution resistance in the interface between electrode and solution. Electrode process could be evaluated by the electrical impedance analysis. The necessities of the electrochemical cell analysis with high speed impedance analyzer are followings: minimization of the effects of electric stimulation on electrochemical cell and the concentration of reactive materials, and optimization of impedance signal resolution. This paper represents the design criteria for the selection and stimulation to develop fast impedance analyzer prototype for a electrochemical cell. It was suggested that the design of 470k sample/s sampling rate, 13 bit ABC resolution, and 140ms recording time is required for high speed impedance analysis system in frequency range between dc and 10kHz.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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• pp.1130-1132
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• 2009

We propose a novel way for enhancement of efficiency on a quasi solid-state dye-sensitized solar cell (DSSC). It contained gel type electrolyte mixing the liquid crystal (LC) of specific concentration and applied voltage for alignment of the LC. Aligned LC is supported charge transfer inside electrolyte and efficiency is increased in DSSC. We made a quasi solid-state DSSC which applied DC voltage or not and have measured the power conversion efficiency (PCE) and the fill factor. From measurement, we obtain high performances in case of cell applied voltage compare to reference cell.