• The Journal of Korea Institute of Information, Electronics, and Communication Technology
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• v.7 no.1
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• pp.36-39
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• 2014

MFC(microbial fuel cell) is the device to produce the electricity by using the microbes which are living in the waste water. In this paper, the electric characteristics of the MFC were investigated according to each different structure and electrode materials. The voltage being reversed phenomenon was observed in the MFC which uses the cupper plate as the cathode material. This result comes from the oxidation reaction of the cupper plate electrode in this MFC. And this MFC has lower output voltage than one that has a platinum plate electrode. The smaller gap distance of the cupper plate electrode of the MFC showed the higher output voltage. The larger electrode area of the cupper plate electrode showed that the reaching time of the output voltage to the maximum value was delayed.

• Transactions of the Korean hydrogen and new energy society
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• v.34 no.6
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• pp.575-580
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• 2023

An electrode was prepared by dip-coating NiFe₂O₄ powder on stainless steel (SUS) support for the application in the alkaline water electrolysis. The prepared electrode was analyzed using scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDXS), and was evaluated for the voltage properties with the change of current density in oxygen evolution reaction (OER) and hydrgen evolution reaction (HER) using 1, 3 and 7 M KOH solution. From the SEM and EDXS analysis, it was confirmed that the prepared electrode had NiFe₂O₄ on the SUS support. In OER and HER, the voltage in the 7 M KOH solution had a value of 1.35 and -1.90 V at 0.2 and -0.2 A/cm² of the current density, respectively. It was considered that the prepared electrode could be use as an electrode in the alkaline water electrolysis from the experimental results.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.11b
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• pp.585-588
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• 2001

Thin. Boron-doped conducting diamond films are expected to be excellent electrodes for industrial electrolysis. Boron-doped conducting diamond films were used as anode for generating ozone gas by electrolysis of acidic solution. In this work, we have studied ozone generating system using Boron-doped Diamond electrode. Electrochemical cell and ozone generating system were designed for decreasing the temperature of the system. which was elevated during the reaction. by circulation of electrolyte in the system. In order to determine the ozone generation properties of diamond electrode. experimental conditions, electrolyte concentration, temperature, flow rate and reaction time were varied diversely. As a result, we could confirm that ozone gas was generated successfully and the performance of diamond electrode was stable while $PbO_2$ electrode was disintegrated. Actually we are found that ozone amount increased by lowering the temperature of electrolyte.

• Journal of Electrochemical Science and Technology
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• v.2 no.3
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• pp.136-142
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• 2011

$Li_4Ti_5O_{12}$ is prepared through a solid-state reaction between $Li_2CO_3$ and anatase $TiO_2$ for applications in lithium-ion batteries. The rate capability is measured and the electrode polarization is analyzed through the galvanostatic intermittent titration technique (GITT). The rate characteristics and electrode polarization are highly sensitive to the amount of carbon loading. Polarization of the $Li_4Ti_5O_{12}$ electrode continuously increases as the reaction proceeds in both the charge and discharge processes. This relation indicates that both electron conduction and lithium diffusion are significant factors in the polarization of the electrode. The transition metal (Cu, Ni, Fe) ion added during the synthesis of $Li_4Ti_5O_{12}$ for improving the electrical conductivity also greatly enhances the rate capability.

• Transactions of the Korean hydrogen and new energy society
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• v.11 no.4
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• pp.179-188
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• 2000

The anodic reaction of hydrogen/oxygen gas mixture at platinum or palladium electrode interfacing with a solid polymer electrolyte was investigated using AC impedance method. The impedance spectrum of the electrode reactions of the mixture depends on the gas composition, electrode roughness, the mode of electrochemical operation and the cell potential. For electrolysis mode of operation, the spectrum taken for the reaction on a rough platinum electrode for the gas mixture revealed clearly that the local anodic reduction of oxygen gas takes place concurrently with the anodic oxidation of hydrogen gas.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.11a
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• pp.585-588
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• 2001

Thin, Boron-doped conducting diamond films are expected to be excellent electrodes for industrial electrolysis. Boron-doped conducting diamond films were used as anode for generating ozone gas by electrolysis of acidic solution. In this work, we have studied ozone generating system using Boron-doped Diamond electrode. Electrochemical cell and ozone generating system were designed for decreasing the temperature of the system, which was elevated during the reaction. by circulation of electrolyte in the system. In order to determine the ozone generation properties of diamond electrode, experimental conditions, electrolyte concentration, temperature, flow rate and reaction time were varied diversely. As a result, we could confirm that ozone gas was generated successfully and the performance of diamond electrode was stable while PbO$_2$ electrode was disintegrated. Actually we are found that ozone amount increased by lowering the temperature of electrolyte.

• Journal of Environmental Science International
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• v.17 no.3
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• pp.335-342
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• 2008

This study based on electro-coagulation & oxidation reaction is applied to wastewater treatment. Electro-oxidation reaction is used to remove cyanide(CN) which is contained in plating wastewater. Cyanide is transferred by gases such as $NH_3,\;NO_x,\;CO_2$. Analysis result and removal efficiency of Cyanide which is contained in heavy metal wastewater of plating plant, are shown as following paragraph. In electrode arrangement experiment, removal efficiency of carbon electrode(-)/STS316L electrode(+) arrangement method is superior to carbon electrode(-)/carbon electrode(+) arrangement method. Removal efficiencies of cyanide in different HRT such as 30 min, 45 min, 60 min, 75 min and 90 min are 85.5%, 93.1%, 98.0%, 98.7% and 99.4% respectively in carbon electrode(-)/STS316L electrode(+) arrangement method. Finally we can estimate the critical point at HRT of 60 min which the variation of removal efficiency is decreased and HRT to obtain removal efficiency of less than 1 mg/LCN is minimum 90 min.

• Journal of Environmental Health Sciences
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• v.23 no.1
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• pp.43-49
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• 1997

This study was aimed to estimate removal efficiency(%) of BER(Biofilm-Electrode Reactor) and A.S(Activated Sludge) treatments. When were analyzed COD$_{Cr}$, NH$_3$-N and T-P by current density and reaction time, the results were as follows : 1) In BER treatment, the removal efficiency of COD$_{Cr}$ in domestic wastewater was 79-86% when current density was 2.39 mA/dm$2$(15mA)-3.98 mA/dm$^2$(25mA) and reaction time was 48 hr. 2) Removal efficiency of NH$_3$-N was 71-73% when current density was 2.39-3.98 mA/dm$^2$ and reaction time 48 hr. 3) When the reaction time was 48 hr removal efficiency(%) of BER treatment for COD$_{Cr}$, NH$_3$-N and T-P were more excellent than A.S. treatment. And then we prospect that was because activated microorganism colonies attached in biofilm on surface of electrode pannel. Therefore, In order to derive BER treatment efficiency(%) should establish optimum conditions of pH, temp., reaction time, current density and biochemical and electrochemical states.

• Bulletin of the Korean Chemical Society
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• v.32 no.2
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• pp.571-575
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• 2011

Graphite-based electrodes were prepared using synthetic graphite (MCMB 1028) or natural graphite (NG) powder using a dimensionally stable anode (DSA) as a substrate. Their electrochemical properties were investigated in vanadiumbased electrolytes to determine how to increase the durability and improve the energy efficiency of redox flow batteries. Cyclic voltammetry (CV) was performed in the voltage range of -0.7 V to 1.6 V vs. SCE at various scan rates to analyze the vanadium redox reaction. The graphite-based electrodes showed a fast redox reaction and good reversibility in a highly concentrated acidic electrolyte. The increased electrochemical activity of the NG-based electrode for the $V^{4+}/V^{5+}$ redox reaction can be attributed to the increased surface concentration of functional groups from the addition of conductive material that served as a catalyst. Therefore, it is expected that this electrode can be used to increase the power density and energy density of redox flow batteries.

• Journal of the Korean Chemical Society
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• v.14 no.2
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• pp.141-145
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• 1970

The reduction of Mo-thiocyanate (V) complex on dropping mercury electrode has been studied at ionic strength 0.6 with pH less than 2.3. D-C polarogram obtained from acidic solutions are reversible, diffusion controlled current. The electrode reaction of Mo-thiocyanate(V) may be represented as follows. $MoO(SCN)_3\;+\;2H^+\;+\;2e\;{\to}\;Mo(SCN)_2{^+}\;+\;H_2O\;+\;SCN^-$From this reaction, the half wave potential assumed to be $E_{1/2}\;=\;E_0'\;-\;0.059\;pH\;-\;0.03\;log{\;frac{[Mo(SCN)_2{^+}][SCN^-]}{[MoO(SCN)_3]}}$Considering the dissociation of this complex, however, it was estimated that the electrode reaction may be written by. $MoO^{+3}\;+\;3SCN^-\;+\;2H^+\;+\;2e\;{\to}\;Mo(SCN)_2{^+}\;+\;SCN^-\;+\;H_2O$.