• 대한전기학회논문지:전기물성ㆍ응용부문C
• /
• 제51권2호
• /
• pp.92-97
• /
• 2002

One of the important roles of a DNA chip is the capability of detecting genetic diseases and mutations by analyzing DNA sequence. For a successful electrochemical genotyping, several aspects should be considered including the chemical treatment of electrode surface, DNA immobilization on electrode, hybridization, choice of an intercalator to be selectively bound to double standee DNA, and an equipment for detecting and analyzing the output signal. Au was used as the electrode material, 2-mercaptoethanol was used for linking DNA to Au electrode, and methylene blue was used as an indicator that can be bound to a double stranded DNA selectively. From the analysis of reductive current of this indicator that was bound to a double stranded DNA on an electrode, a normal double stranded DNA was able to be distinguished from a single stranded DNA in just a few seconds. Also, it was found that the peak reduction current of indicator is proportional to the concentration of target DNA to be hybridized with probe DNA. Therefore, it is possible to realize a sim71e and cheats DNA sensor using the electrochemical measurement for genotyping.

• 전기화학회지
• /
• 제15권3호
• /
• pp.115-123
• /
• 2012

리튬이차전지의 수요가 소형 휴대용 전자기기에서 중대형 전기자동차와 에너지저장장치로 변화함에 따라, 요구되는 전지 특성도 크게 달라지고 있다. 10년 이상의 장기 신뢰성, 팩 수준의 안전성, 가격 경쟁력 확보 등 기존 소형 전지보다 크게 강화된 요구 조건뿐만 아니라, 고출력 특성도 함께 필요로 한다. 그런데, 출력을 측정하기 위해서는 전압과 전류가 동시에 측정 및 제어되어야 하기 때문에, 기존의 단위셀 용량 측정보다 훨씬 어렵다. 또한, 측정 방법의 선택뿐만 아니라 출력유지시간, 충전상태(State-of-Charge, SOC), Cut-off 조건, 측정온도 등의 측정 조건에 따라서도 그 측정값이 크게 달라지는 경향이 있다. 본 논문에서는 HPPC (Hybrid Pulse Power Characterization)법, J-pulse(Japan Electric Vehicle Association Standards, JEVS D 713)법, 정출력 측정법(Constant Power Measurement)의 측정 원리 및 실제 실험에 어떻게 적용해야 하는지 설명하고, HEV(Hybrid Electric Vehicle)용 단위셀을 이용해 출력법간 측정 결과를 비교 분석한다.

• 한국표면공학회:학술대회논문집
• /
• 한국표면공학회 2007년도 추계학술대회 논문집
• /
• pp.26-26
• /
• 2007

To attest zinc electrodeposition mechanism, electric circuit models for zinc electro reaction on Pt electrode are analyzed from the a.c. impedance data. Electrochemical reactions of zinc deposition are composed of the three electrochemical reactions on the cathode layer and of the induced electrode layers.

• 센서학회지
• /
• 제33권2호
• /
• pp.63-69
• /
• 2024

A novel method for measuring hydrogen concentration is introduced, along with its working principle and a novel detection algorithm. This configuration requires no additional reference compartment for potentiometric electrochemical measurements; therefore, it is the most suitable for measuring dissolved hydrogen in the liquid phase. The sensor's electromotive force saturates at a certain point, depending on the hydrogen concentration during the heating process of the sensor operation. This dynamic temperature scanning method provides higher sensitivity than the constant temperature measurement method.

• Journal of Microbiology and Biotechnology
• /
• 제14권5호
• /
• pp.1043-1046
• /
• 2004

The stability and electrochemical properties of a self-assembled layer of spinach ferredoxin on a quartz substrate and on a highly oriented pyrolytic graphite electrode were investigated. To fabricate the ferredoxin self-assembly layer, dimyristoylphosphatidylcholine was first deposited onto a substrate for ferredoxin immobilization. Surface analysis of the ferredoxin layer was carried out by atomic force microscopy to verify the ferredoxin immobilization. To verify ferredoxin immobilization on the lipid layer and to confirm the maintenance of redox activity, absorption spectrum measurement was carried out. Finally, cyclic-voltammetry measurements were performed on the ferredoxin layers and the redox potentials were obtained. The redox potential of immobilized ferredoxin had a formal potential value of -540 mV. It is suggested that the redox-potential measurement of self-assembled ferredoxin molecules could be used to construct a biosensor and biodevice.

• Corrosion Science and Technology
• /
• 제13권6호
• /
• pp.224-232
• /
• 2014

Effect of pretreatments on the graphene coated bipolar plate of proton exchange membrane fuel cell(PEMFC) was investigated in simulated environments for PEMFC by using electrochemical measurement techniques. Interfacial contact resistance(ICR) between the graphene coated bipolar plate and the gas diffusion layer(GDL) was measured. The value of ICR decreased with an increase in compaction stress($20N/cm^2{\sim}220N/cm^2$). ICR of graphene coated bipolar plate was higher than that of bare 316L stainless steel. However, Potentiodynamic measurement results showed that the corrosion resistance of graphene coated bipolar plate was higher than that of bare 316L stainless steel. $H_2SO_4$ acid pretreatment was the most effective among various pretreatments. The lowest ICR and the corrosion current density were obtained when using $H_2SO_4$ solution pretreatment.

• 한국염색가공학회지
• /
• 제25권2호
• /
• pp.83-88
• /
• 2013

Rhodamine dyes have been studied in various scientific areas due to their excellent photophysical properties. In particular, these rhodamine dyes are one of the most famous fluorophores as signal unit in chemosensor study. This is related to spirolactam ring system in rhodamine dyes. When the spirolactam ring is closed, there is nonfluorescence and colorless. Whereas, ring-opening of the corresponding spirolactam induces strong fluorescence and color. These absorption and emission changes are related to structural changes as well as electron energy potential levels such as HOMO and LUMO values. In this study, two different structures of rhodamine 6G hydrazide depending on the spirolactam ring system were investigated using absorption measurement, electrochemical measurement and computational calculations.

• Corrosion Science and Technology
• /
• 제8권5호
• /
• pp.203-207
• /
• 2009

Electrochemical methods have been widely used to study the performances and mechanisms for the degradation of organic and inorganic coatings. In this study, EN(Electrochemical noise) measurement was applied to the protective properties and review the parameters analyzed noise signals in the time and in the frequency domain for epoxy resin based coated steels during exposure to hot sea water($40^{\circ}C$) and salt spray for 200 days. It was also found that $R_n$(Noise resistance), $R_{sn}$($f_{min}$)(Spectral noise resistance) and 2H(Hurst exponent) represented the performance of epoxy coated steels. $R_n$ can be determined as the ratio of the standard deviations of potential and current noise signals and is decreased to exposure time. Data qualities can be easily checked by PSD(Power Spectral Density) plot and $V_{psd}$, $I_{psd}$ and $R_{sn}$($f_{min}$) is useful to research the protective performances and mechanisms of coated steels. Hurst exponent represents the degradation of coated steels. But, it is difficult to directly apply the protective criterion to the evaluation of epoxy coated steels used the shipbuilding processes.

• 한국신재생에너지학회:학술대회논문집
• /
• 한국신재생에너지학회 2010년도 춘계학술대회 초록집
• /
• pp.163.2-163.2
• /
• 2010

In this work, nano-flake shaped nickel oxide (NiO) films were synthesized by chemical bath deposition technique for electrochemical capacitors. The deposition was carried out for 1 and 2 h at room temperature using nickel foam as the substrate and the current collector. The structure and morphology of prepared NiO film were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). And, electrochemical properties were characterized by cyclic voltammetry, galvanostatic charge-discharge, and AC impedence measurement. It was found that the NiO film was constructed by many interconnected NiO nano-flakes which arranged vertically to the substrate, forming a net-like structure with large pores. The open macropores may facilitate the electrolyte penetration and ion migration, resulted in the utilization of nickel oxide due to the increased surface area for electrochemical reactions. Furthermore, it was found that the deposition onto nickel foam as substrate and curent collector led to decrease of the ion transfer resistance so that its specific capacitance of a NiO film had high value than NiO nano flake powder.

• Journal of Electrochemical Science and Technology
• /
• 제5권4호
• /
• pp.109-114
• /
• 2014

The $Li_3V_2(PO_4)_3$/graphene nano-particles composite was successfully synthesized by a facile sol-gel method. The addition of a graphene in $Li_3V_2(PO_4)_3(LVP)$(LVP) showed the high crystallinity and influenced the morphology of the $Li_3V_2(PO_4)_3$ particles observed in X-ray diffraction (XRD) and scanning electron microscopy (SEM). The LVP/graphene samples were well connected, resulting in fast charge transfer. The effect of the addition graphene nano-particles on electrochemical performance of the materials was investigated. Compared with the pristine LVP, the LVP/graphene composite delivered a higher discharge capacity of $122mAh\;g^{-1}$ at 0.1 C-rate, better rate capability and cyclability in the potential range of 3.0-4.3 V. The electrochemical impedance spectra (EIS) measurement showed the improved electronic conductivity for the LVP/graphene composite, which can ensure the high specific capacity and rate capability.