• Polymer(Korea)
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• v.30 no.1
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• pp.85-89
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• 2006

The effect of vapor grown carbon fiber (VGCF) contents on electrical and rheological properties of VGCF filled polyphenylene sulfide (PPS) composites prepared through melt mixing using a twin screw exruder was studied. This method was proved to be quite effective to produce good dispersion of VGCF in the matrix even for highly filled PPS. From the dependence of the electrical conductivity on VGCF content, the percolation phenomena began to occur above $10\;wt\%$. While there is only a marginal increase of viscosity for 1 and $5\;wt\%$ VGCF filled PPS, the composites containing $10\;wt\%$. While VGCF showed abrupt increase in viscosity as well as flattening of frequency vs modulus curve, indicating a transition from a liquid-like to a solid-like behavior due to the creation of VGCF network. This result agrees well to the fact that the network formation in the composite can be composite by rheological property dependence on filler content as well as by electrical conductivity measurement.

• International Journal of Highway Engineering
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• v.17 no.3
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• pp.85-95
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• 2015

PURPOSES : Recently, bonded concrete overlay has been used as an alternative solution in concrete pavement rehabilitation since its material properties are similar to those of the existing concrete pavements. Deteriorated concrete pavements need rapid rehabilitation in order to prevent traffic jams on Korean expressways. Moreover, speedy and effective repair methods are required. Therefore, the use of bonded concrete overlay with ultra-rapid hardening cement has increased in an effort to reopen promptly the expressways in Korea. However, mobile mixer is required for ultra-rapid hardening cement concrete mixing in the construction site. The use of mobile mixer causes various disadvantages aforementioned such as limitation of the construction supply, open-air storage of mixing materials, increase in construction cost, and etc. In this study, therefore, hydration accelerator in-situ mixing on polymer modified concrete produced in concrete plant is attempted in order to avoid the disadvantages of existing bonded concrete overlay method using ultra-rapid hardening cement. METHODS : Bonded concrete overlay materials using ultra-rapid hardening cement should be meet all the requirements including structural characteristics, compatibility, durability for field application. Therefore, This study aimed to evaluate the application of hydration accelerator in-situ mixing on polymer modified concrete by evaluating structural characteristics, compatibility, durability and economic efficiency for bonded concrete overlay. RESULTS : Test results of structural characteristics showed that the compressive, flexural strength and bond strength were exceed 21MPa, 3.15MPa and 1.4MPa, respectively, which are the target strengths of four hours age for the purpose of prompt traffic reopening. In addition, tests of compatibility, such as drying shrinkage, coefficient of thermal expansion and modulus of elasticity, and durability (chloride ions penetration resistance, freezing-thawing resistance, scaling resistance, abrasion resistance and crack resistance), showed that the hydration accelerator in-situ mixing on polymer modified concrete were satisfied the required criteria. CONCLUSIONS : It was known that the hydration accelerator in-situ mixing on polymer modified concrete overlay method was applicable for bonded concrete overlay and was a good alternative method to substitute the existing bonded concrete overlay method since structural characteristics, compatibility, durability were satisfied the criteria and its economic efficiency was excellent compare to the existing bonded concrete overlay methods.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.4
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• pp.2945-2950
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• 2015

While perfluoroalkane (PFA), a liquid state nucleating agent for a rigid polyurethane foam (RPUF) to enhance the thermal insulation property, has the excellent nucleating characteristics, it is very expensive as well as environmentally harmful due to the fluoride compound. Many researches, therefore, have been performed to develop the alternative nucleating agents to replace PFA. In the present work, a multi-wall carbon nanotube (MWCNT) was used as a sloid state nucleating agent, and thereby the effects on the property changes of the RPUF were carried out. Average cell size decreased from 165.6 for base RPUF to $162.9{\mu}m$ and cell uniformity was also enhanced, showing the standard cell-size deviation of 45.6 and 35.2, respectively. While k-factor of base PUF was $0.01763kcal/m.hr.^{\circ}C$, that of the sample with 0.01 phr MWCNT showed 1.02% reduced value of $0.01745kcal/m.hr.^{\circ}C$. Though the compressive yield stress is nearly the same as $0.030{\times}105Pa$ for the both samples, initial modulus of the sample with 0.01 phr MWCNT was higher than that of base sample. it was considered as the results that small amount of MWCNT could play a sufficient role as the effective nucleating agent for RPUF, showing that an echo-friendly RPUF with reduced-cost could be fabricated, which has an enhanced thermal and mechanical properties.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.19 no.4 s.74
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• pp.389-398
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• 2006

Structural optimization design has been developed with finite element analysis using effective and fast computational technology. Especially topology optimization design has been recently often used since it yields an optimal topology as well as an optimal shape under satisfied constraints. In general in finite element analysis, it is assumed that the structural material properties such as Young's modulus and Poisson's ratio and the variable of applied loading are fixed with obvious values in structure. However practically these values may take uncertainties because of environmental effect or manufactural error of structures. Therefore static or dynamic analysis of the structures may make an error, then finally it may have an influence on qualify of optimal design. In this study, the topology optimization design of structure is carried out using so called the interval finite element method, and the analysis method Is proposed. The results are also validated by comparing with conventional topology optimization results of density distribution method and finite element analysis results. The present method can be used to predict the optimal topology of linear elastostatic structures with respect to structural uncertainty of behavior.

• Polymer(Korea)
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• v.33 no.3
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• pp.224-229
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• 2009

The dielectric properties of semi-IPN poly(phenylene oxide)(PPO) blend/$BaTiO_3$(BT) composites are investigated. The composites are fabricated via melt-mixing of crosslinker and peroxide in precursor PPO composite obtained by precipitating the suspension consisted of PPO, BT and toluene into methylethyl ketone, poor solvent of PPO. The permittivity of the precursor PPO composites shows higher value than that of integral-blended PPO composites by extruder and coincides with the theoretical value calculated by logarithmic rule of mixture. The blend of PPO and cross-linked triallyl isocyanurate is most effective for lowering the permittivity and loss tangent owing to the suppression of the orientation polarization of matrix. In contrast, 4,4'-(1,3-phenylene diisopropylidene) bisaniline, which has amine unit in its structure, increases the permittivity as well as loss tangent of the composite, but it has the ability to densify the matrix resin and the interfacial adhesion between the matrix and filler to improves flexural strength and modulus.

• Transactions of the Korean Society of Mechanical Engineers
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• v.17 no.10
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• pp.2498-2508
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• 1993

$Al/SiC/Al_{2}O_{3}$ hybrid composites are fabricated by squeeze infiltration method. From the misconstructive of $Al/SiC/Al_{2}O_{3}$ hybrid composites fabricated by squeeze infiltration method, uniform distribution of reinforcements and good bondings are found. Hardness value of $Al/SiC/Al_{2}O_{3}$ hybrid composites increases linearly with the volume fraction of reinforcement because SiC whisker and $Al_{2}$O$_{3}$ fiber have an outstanding hardness. Optimal aging conditions are obtained by examining the hardness of $Al/SiC/Al_{2}O_{3}$ hybrid composites with different aging time. Tensile properties such as Young's modulus and ultimate tensile strength are improved up to 30% and 40% by the addition of reinforcements, respectively. Failure mode of $Al/SiC/Al_{2}O_{3}$ hybrid composites is ductile on microstructural level. Through the abrasive wear test and wear surface analysis, wear behaviour and mechanism of 6061 aluminum and $Al/SiC/Al_{2}O_{3}$ hybrid composites are characterized under various testing conditions. The addition of SiC whisker to $Al/SiC/Al_{2}O_{3}$ composites gives rise to improvement of the wear resistance. The wear resistance of $Al/SiC/Al_{2}O_{3}$ hybrid composites is superior to that of Al/SiC composites. The wear mechanism of aluminum alloy is mainly abrasive wear at low speed range and adhesive and melt wear at high speed range. In contrast, that of $Al/SiC/Al_{2}O_{3}$ hybrid composites is abrasive wear at all speed range, but severe wear when counter material is stainless steel. As the testing temperature increases, wear loss of aluminum alloy decreases because the matrix is getting more ductile, but that of $Al/SiC/Al_{2}O_{3}$ hybrid composites is hardly varied. Oil lubricant is more effective to reduce the wear loss of aluminum alloy and $Al/SiC/Al_{2}O_{3}$ hybrid composites at high speed range.

• Journal of the Korea Concrete Institute
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• v.14 no.4
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• pp.521-529
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• 2002

A restraint coefficient for creep and dry shrinkage deformation of concrete in a composite section was derived to calculate the residual stress, and an equation for the loss rate of the pre-compression force was proposed. The derived restraint coefficient was computed by using the transformed section properties for the age-adjusted effective modulus of elasticity. The long-term behavior of complicate composite sections could be analyzed easily with the restraint coefficient. The articles of the current design code was examined for PSC and steel composite sections. The dry shrinkage strains of $150 ~ 200$\times$10^{-6}$ for the computations of the statically indeterminate force and the expansion joint could be under-estimated for less restrained sections such as the reinforced concrete. The dry shrinkage strain of $180$\times$10^{-6}$ for the computation of residual stress in the steel composite section was unreasonably less value. The loss rate of 16.3% of the design code for the PSC composite section in this study was conservative for the long-term deformation of the ACI 205 but could not be used safely for that of the Eurocode 2. For pre-compressed concrete slab in the steel composite section, the loss rate of prestressed force with low strength reinforcement was much larger than that with high strength tendon. The loss rate of concrete pre-compression increased, while that of pre-tension decreased due to the restraint of the steel girder.

• Journal of the Korea Concrete Institute
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• v.23 no.1
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• pp.77-86
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• 2011

The concrete creep deformation of a hybrid composite section can cause additional deformation of the composite section and the stress relaxation of pre-compressive stress on the concrete section due to partial restraint of the deformation. In this study, the stress relaxation coefficient method (SRCM) is derived for simple analysis of complicate hybrid or composite sections for engineering purpose. Also, an equation of the stress relaxation coefficient (SRC) required for the SRCM is proposed. The SRCM is derived with the parameters of a creep coefficient, section and loading properties using the same method as the constant-creep step-by-step method (CC-SSM). The errors of the SRCM is improved by using the proposed SRC equation than the average SRC's which were estimated from the CC-SSM. The root mean square error (RMSE) of the SRCM with the proposed SRC equation for concrete with creep coefficient less than 3 was less than 1.2% to the creep deformation at the free condition and was 3.3% for the 99% reliability. The proposed SRC equation reflects the internal restraint of composite sections, and the effective modulus of elasticity computed with the proposed SRC can be used effectively to estimate the rigidity of a composite section in a numerical analysis which can be applied in analysis of the external restrain effect of boundary conditions.

• Journal of the Korean GEO-environmental Society
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• v.13 no.6
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• pp.19-26
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• 2012

In this study, geotechnical tests including unconfined compression test were carried out to evaluate the ground improvement effect of the hardening agent, which has been developed by using inter-chemical reactions between slag, fly ash, phosphogypsum and bypass dust on the weathered granite soil and dredged marine clay. Test results show that the strength of weathered granite soil mixed with hardening agent B-2, which uses phosphogypsum as an activator, is higher than that of B-1, which uses bypass dust as an activator. Strengths of B-1 & B-2 hardening agent mixed soil show only 44%~60% of strength of OPC(Ordinary Portland Cement, OPC) mixed soil. However, since B-1 and B-2 agents are made of industrial by-products, they seem economically more effective than ordinary portland cement as well as other present hardening agents. Test results on dredged marine clay show that unconfined compression strength increases with amount of agent and curing days. Unconfined compression strength of 14% B-1 agent mixed soil increases linearly with curing days and reaches only 40% of OPC mixed soil. While unconfined compression strength of 14% B-2 agent mixed soil increases exponentially and reaches 133% of OPC mixed soil. Relationship between deformation modulus and unconfined compression strength of B-1 and B-2 mixed soil can be expressed as $E_{50}=(20{\sim}47)_{qu,28}$, which is similar with lower limit of OPC mixed dredged marine clay.

• Journal of the Korean Geotechnical Society
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• v.29 no.11
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• pp.119-127
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• 2013

Recently, several researches on the development of new economical foundation types have been performed to support floating structures as many offshore structures have been constructed. This study focused on the evaluation of bearing capacity of group suction piles, which are connected by a concrete pile cap. The offshore floating structures are mainly subjected to horizontal loading, so the horizontal bearing capacities of the group suction piles were analyzed by performing 3-dimensional finite element analyses. The group suction piles are expected to behave as a rigid pile due to its shallow embedded depth. Therefore, the detailed soil modeling was necessary to simulate the bearing behavior of soils under low confining pressure. The modulus and the strength of soils were modelled to increase with effective confining pressure in soils. For the parametric study, the center-to-center spacing between piles was varied and two soil types of clay and sands were applied. The analyses results showed that the yielding load of the group pile increased with the increase of the pile spacing and the yielding load of the group piles with 5D spacing was about 3 times larger than that of the single pile with free rotation.