• Title/Summary/Keyword: effective modification method

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Novel route of enhancing the metal loading in highly active Pt/C electro-catalyst by polyol process (Polyol process를 통한 고비율 백금 담지 촉매 합성)

  • Oh, Hyung-Suk;Kim, Han-Sung
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.560-563
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    • 2008
  • A modified polyol process is developed to enhance Pt loading during the preparation of Pt/C catalysts. With the help of the zeta potential, the effect of pH on the electrostatic forces between the support and the Pt colloid is investigated. It is shown experimentally that the surface charge on the carbon support becomes more electropositive when the solution pH is changed from alkaline to acidic. However, this change does not affect the electronegative surface charge of Pt colloids already attained and stabilized by glycolate anions. This new behavior caused by the change in the solution pH accounts for the enhanced yield of the process and does not affect the Pt particle size. All our experimental results reveal that this simple modification is a cost effective method for the synthesis of highly Pt loaded Pt/C catalysts for fuel cells.

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A Study on the Flame Monitoring System Development (화염감시 시스템 개발에 관한 연구)

  • 백운보;황이철;이승종
    • Journal of the Korean Society for Precision Engineering
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    • v.21 no.2
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    • pp.60-66
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    • 2004
  • Increased energy costs have placed demands for improved combustion efficiency, high equipment availability, low maintenance and safe operation. Simultaneously low NOx modification, installed due to stricter environmental legislations, require very careful combustion management. The flame diagnostics system has been developed specially to meet these requirements. We aimed at gaining the relationship between burner flame image and emissions such as NOx and unburned carbon in furnace by utilizing the image processing method. For the first step of development, its possibility test was undertaken with bench furnace. The test proceeded to the second step with pilot furnace, the system was observed to be effective for evaluating the combustion conditions.

A Study on Damage Detection of Cutting Tool Using Neural Network and Cutting Force Signal (신경망과 절삭력신호 특성을 이용한 공구이상상태 감지에 관한 연구)

  • Lim, K.Y.;Mun, S.D.;Kim, S.I.;Kim, T.Y.
    • Journal of the Korean Society for Precision Engineering
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    • v.14 no.12
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    • pp.48-55
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    • 1997
  • A useful method to detect tool breakage suing neural network of cutting force signal is porposed and implemented in a basic cutting process. Cutting signal is gathered by tool dynamometer and normalized as a preprocessing. The cutting force signal level is continually monitored and compared with the predefined level. The neural network has been trained normalized sample data of the normal operation and cata-strophic tool failure using backpropagation learning process. The develop[ed system is verified to be very effective in real-time usage with minor modification in conventional cutting processes.

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A Study on the Development of Aluminum Seat Frame for Commercial Bus (상용 버스용 알루미늄 시트 프레임의 개발에 관한 연구)

  • 우호광;이상복;김상범;김헌영
    • Transactions of the Korean Society of Automotive Engineers
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    • v.12 no.3
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    • pp.91-100
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    • 2004
  • This study presents the development of a new aluminum seat frame for the commercial bus. Back moment and seat belt anchorage analysis of the conventional steel seat frame was conducted as a base model. Effective aluminum section dimensions for aluminum pipe were calculated from equivalent stiffness and equivalent weight study. Back moment and seat belt anchorage strength with the developed aluminum seat frame were compared to those of the base model. Additionally, to pass the fatigue test, shape modification of side frame assembly was conducted. From this study we could reduce the weight of seat frame more than 5 kg. And the current analysis model and procedure can provide useful informations in designing a new commercial car seat and can reduce the overall design cost and time.

Preparation of Copolymers by Controlled Radical Polymerization and their Applications

  • Choi, Kil-Yeong;Kim, Yong-Seok;Han, Seung-San;Lee, Jae-Heung
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.95-96
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    • 2006
  • Surface modification of clay minerals has become increasingly important for improving the practical applications of clays such as polymeric nanocomposites. We used the copolymer as modifiers having phenyl components, and successfully developed a route for the preparation of amine functionalized polymer based on oligostyrene and its block copolymers. The oligo(St-co-VBC)s with controlled molecular weight were synthesized via nitroxide mediated polymerization method. We also successfully prepared organophilic layered silicates whose surface is covered with styrenic copolymers. Through the analysis of chemical structure and morphology, we concluded that copolymers were very effective organic modifiers to change the surface characteristics of layered silicates.

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Theoretical study on electrical behavior of carbon chain inserted single-walled carbon nanotubes compared with Pt doped one

  • Cui, Hao;Zhang, Xiaoxing;Xiao, Hanyan;Tang, Ju
    • Carbon letters
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    • v.25
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    • pp.55-59
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    • 2018
  • Carbon chain inserted carbon nanotubes (CNTs) have been experimentally proven having undergone pronounced property change in terms of electrical conductivity compared with pure CNTs. This paper simulates the geometry of carbon chain inserted CNTs and analyzes the mechanism for conductivity change after insertion of carbon chain. The geometric simulation of Pt doped CNT was also implemented for comparison with the inserted one. The results indicate that both modification by Pt atom on the surface of CNT and addition of carbon chain in the channel of the tube are effective methods for transforming the electrical properties of the CNT, leading to the redistribution of electron and thereby causing the conductivity change in obtained configurations. All the calculations were obtained based on density functional theory method.

The Design of a Power Supply for Planer Type of the Dielectric Barrier Discharge Ozone Reactor with Impedance Matching (유전체 장벽 방전을 이용한 오존 발생기의 전원장치 최적 설계 및 비교)

  • Kim, Bong-Seong;Shin, Young-Chul;Ko, Kwang-Cheol
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.1
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    • pp.57-63
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    • 2011
  • Dielectric Barrier Discharge (DBD) reactor with sinsodual AC type of power supply is very widely adopted for its compact size and effective discharging mechanism to generate high density of ozone radicals. However, at the aspect of design on power supply, its optimal switching conditions and topology is achieved by empirical test. Therefore, throughout this paper, it is proposed a design method of DBD power supply to guarantee a maximum ozone yield rate in accordance with DBD reactor modification and impedance variation when rapid gas discharging in the DBD reactor is proceeded.

Flame Image Analysis Systems for Combustion Conditions Monitoring (연소상태 감시용 화염 영상분석 시스템)

  • 백운보;한성현
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2003.06a
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    • pp.499-502
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    • 2003
  • Increase energy costs have placed demands for improved combustion efficiency, high equipment availability, low maintenance and safe operation. Simultaneously low NOx modification, installed due to stricter environmental legislation, require very careful combustion management. We aimed at gaining the relationship between burner flame image and emissions such as NOx and unburned carbon in furnace by utilizing the image processing method. For the first step of development, its possibility test was undertaken with bench furnace. The test proceeded to the second step with pilot furnace, the system was observed to be effective for evaluating the combustion conditions. By using this technology, it is possible to perform continuous monitoring of the combustion conditions and instant detection of individual changes for each burner to prevent future loss of ignition.

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Coating Color Immobilization Content 측정기법 및 영향인자에 대한 연구

  • 곽상효;김진현
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2000.04a
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    • pp.103-110
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    • 2000
  • This study was done in order to increase production speed using coater dryer in maximum capacity without print mottle. The aim of this study was to measure coating color immobilization content(CCIC) and to decrease CCIC through coating color optimization. The final goal of this study was the prevention of print mottle in maximum drying condition by CCIC control. As a result the measuring method of CCIC was set by brightness transition and the effective factors in pigments and binders were defined. With color optimization considered this factors, CCIC was decreased by 4%. Through this CCIC decrease and modification of coater utility, the print mottle was prevented even though using coater dryer in maximum.

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Development of PET Flame Retardant Sheets for Industrial Materials by Control of Manufacturing Process (제조공정제어에 의한 친환경 고성능 산업용 PET 난연시트 제조기술의 개발)

  • Kim, Hea-In;Hong, Yo-Han;Park, Soo-Min
    • Textile Coloration and Finishing
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    • v.21 no.4
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    • pp.46-56
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    • 2009
  • In order to establish the standard manufacturing condition of PET flame retardant sheets, physicochetnical properties of the samples made by the conventional flame-retardant finishing were systematically investigated, including compatibility among flame retardant agent and finishing auxiliaries, surface property, and wicking property. From this results, the addition of washing and renapping process after the shearing process was required for the more effective in producing PET flame-retardant sheet by the standard finishing. The effect of the modification of the regular flame retardant finishing process was studied by FTIR, TGA, and flame retardancy test.