• Advances in environmental research
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• 제2권4호
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• pp.261-277
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• 2013

The degradation of alachlor has been investigated using sonolysis (US), photocatalysis (UV) and sonophotocatalysis (US/UV) using three photocatalyst viz. $TiO_2$ (mixture of anatase and rutile), $TiO_2$ (anatase) and ZnO. The effect of photocatalyst loading on the extent of degradation of alachlor has been investigated by varying $TiO_2$ (both types) loading over the range of 0.01 g/L to 0.1 g/L and ZnO loading over the range of 0.05 g/L to 0.3 g/L. The optimum loading of the catalyst was found to be dependent on the type of operation i.e., photocatalysis alone or the combined operation of sonolysis and photocatalysis. All the combined processes gave complete degradation of alachlor with maximum rate of degradation being obtained in the case of sonophotocatalytic process also showing synergistic effect at optimized loading of photocatalyst. About 50% to 60% reduction in TOC has been obtained using the combined process of sonophotocatalysis depending on the operating conditions. The alachlor degradation fitted first order kinetics for all the processes under investigation. It has been observed that the $TiO_2$ (mixtrure of anatase and rutile) is the most active photocatalyst among the three photocatalysts studied in the current work. The effect of addition of radical enhancers and scavengers on sonophotocatalytic degradation of alachlor has been investigated in order to decipher the controlling mechanism. The alachlor degradation products have been identified using LC-MS method.

• 펄프종이기술
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• 제33권2호
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• pp.49-57
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• 2001

This study was performed to identify the effect of calendering variables on the properties of coated paper such as sheet gloss, surface roughness, opacity, etc. The effect of calendering variables including the number of nips, pressure, machine speed and moisture content on the properties of coated paper was investigated. The calender was installed with two steel rolls and one cotton-made roll. With this calender, the coated sheets were passed through the calender from 1 to 4 times, applying the linear pressure on calender rolls, 5 through 100kg/cm and operating the machine speed 3 to 12m/min. Also, the moisture content of coated sheet was varied about 5 and 10%. It was found that sheet gloss and surface roughness of coated paper was increased with increasing the number of passing nips, linear roll pressure and the moisture content of coated paper. But it was shown that the opacity and brightness of coated paper were decreased under the above conditions due to the blackening. It was also suggested that the soft nip possibly increased the thermoplasticity of coating layer with the heat of steel roll, resulting in the reinforcement of surface properties positively. The sheet gloss and surface roughness of coated paper could be improved by the longer dwell time over the rolls.

• 한국자동차공학회논문집
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• 제22권7호
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• pp.98-106
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• 2014

Emission standards for passenger diesel engines are becoming more and more stringent. Especially, Europe started the regulation of nano-particles from 2011 with EURO 5b. The objective of this study is to investigate the effect of fuel injection strategy on combustion and nano-particle emission in a small diesel engine. In this study, we conducted combustion analysis and measured both the weight of PM and number of nano-particels. At first, the optimum injection timing was determined with fixed engine operating conditions, such as engine speed, load, and fuel injection quantity. After that, the injection timing was controlled, and the effect of pilot injection was investigated. The number of nano-particles increased as engine load decreases, and it increased up to 10 times depending on the change of injection timing. The weight of PM emissions was increased at low load, and the PM emissions increased with increasing the number of pilot injections.

• Macromolecular Research
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• 제12권6호
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• pp.608-614
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• 2004

Isotactic polypropylene (PP) surfaces were modified with argon and oxygen plasmas using a radio­frequency (RF) glow discharge at 240 mTorr and 40 W. The changes in topography and surface structure were investigated by atomic force microscopy (AFM) in conjunction with specular reflectance of infrared (IR) microspectroscopy. Under our operating conditions, the AFM image analysis revealed that longer plasma treatment resulted in significant ablation on the PP surface, regardless of the kind of plasma employed, but the topography was dependent on the nature of the gases. Specular reflectance IR spectroscopic analysis indicated that the constant removal of surface material was an important ablative aspect when using either plasma, but the nature of the ablative behavior and the resultant aging effects were clearly dependent on the choice of plasma. The use of argon plasma resulted in a negligible aging effect; in contrast, the use of oxygen plasma caused a noticeable aging effect, which was due to reactions of trapped or isolated radicals with oxygen in air, and was partly responsible for the increased surface area caused by ablation. The use of oxygen plasma is believed to be an advantageous approach to modifying polymeric materials with functionalized surfaces, e.g., for surface grafting of unsaturated monomers and incorporating oxygen-containing groups onto PP.

• 상하수도학회지
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• 제30권3호
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• pp.321-325
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• 2016

The Pressure Retarded Osmosis (PRO) is the next generation desalination technique and is considered as a eco-friendly energy. This was conducted to evaluate the effect of the temperature and pressure on the PRO performance. The flux of the permeation was measured under different operating conditions and estimated the power density. An improvement of PRO performance is depend on increasing solution temperature and optimum pressure. The effect of increasing feed solution temperature has stronger impact on the PRO performance comparing to the draw solution temperature. The reason of the results was due to the change of osmotic power, viscosity, water permeability and structure parameter(s).

• Nuclear Engineering and Technology
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• 제54권6호
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• pp.2173-2187
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• 2022

A 3D thermo-elasto-hydrodynamic model is developed to analyze the sealing performance of a notched mechanical seal applied in the reactor coolant pump. In the model, the generalized Reynolds equation, the energy equation coupled with notch heat balance equation, the heat conduction equations, and the deformation equations of the sealing rings are iteratively solved by the finite element method. The film pressure and temperature distribution are obtained, and the deformation of the sealing rings is revealed to study the mechanism of the notched mechanical seals. A parameterized study is conducted to analyze the sealing performance under different operating conditions. As a comparison, the sealing performance of non-notched seals is also studied. The results show that the hydrostatic effect is dominant in the load-carrying capacity of the fluid film due to the radial mechanical and thermal deformations. The notch can cool the fluid film and influence the thermal deformation of seal rings. The sealing performance is sensitive to the pressure difference, ambient temperature, and rotational speed. It is suggested to set the notches on the softer sealing rings to acquire the greater hydrodynamic effect. Compared with the non-notched, the notched end face holds a better lubrication performance, especially under lower rotational speed.

• International Journal of Automotive Technology
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• 제2권2호
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• pp.77-83
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• 2001

Effect of ethene on the $DeNO_X$ conversion process in a simulated diesel engine operating conditions was investigated experimentally and theoretically. With the addition of even a small amount of ethene the NO to $NO_2$ conversion enhances greatly. The energy required to convert one NO molecule is 27 eV with 250 ppm ethene added, while 137 eV without ethene at 473 K. The effect of energy density, temperature, and the initial concentrations of ethene and oxygen are also discussed and the results show that the increase of the mentioned parameters lead to the promotion of NO oxidation. A kinetic model used in this study shows good agreement with the experimental result. Byproducts like formaldehyde ($CH_2$ 0) and methyl nitrite ($CH_3$ ONO) predicted by model calculation are broken up into CO and $H_2O$ eventually when high energy is delivered to the gas mixture. Sensitivity analysis shows that the main reactions of NO oxidation when ethene is added we: $HO_2+ NO \arrow NO_2 + OH, RO_2 + NO \arrow NO_2 + RO$, where R is a hydrocarbon radical. Also the direct oxidizing reaction of NO with O cannot be neglected.

• 분석과학
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• 제16권3호
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• pp.212-217
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• 2003

높은 온도와 압력의 조건으로 시료를 분해하는 마이크로파 분해 과정에서 분해용기 내로 은과 왕수의 침투에 의한 기억효과에 대해 연구하였다. MDS 180T 프로그램 ($180^{\circ}C$, 220 psi)의 조건으로 은 5 mg을 첨가한 분해용기 내에서 침투 양은 질산과 함께 분해하였을 경우, $0.97{\mu}g/mL$ 그리고 오일 시료와 함께 분해하였을 경우 $0.47{\mu}g/mL$을 나타내었다.

• 한국가스학회지
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• 제19권6호
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• pp.40-46
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• 2015

이론공연비방식 엔진은 삼원촉매를 이용하여 유해배기가스를 매우 효과적으로 저감시킬 수 있는 장점을 가지고 있다. 삼원촉매는 높은 정화효율을 보이는 공연비범위가 좁기 때문에 엔진에서의 공연비 제어가 매우 중요하다. 본 연구에서는 삼원촉매 성능을 평가하기 위하여 다양한 운전영역에서 삼원촉매의 전환효율을 비교 분석하였다. 최적의 전환효율을 보이는 당량비를 확인하기 위하여 당량비 제어값 변화에 의한 전환효율을 살펴보았다. 실험결과 당량비 제어를 통하여 각 운전조건에서 NMHC, CH4, CO 및 NOx의 전환효율이 95%이상 나타내는 최적 운전조건을 찾을 수 있었다. 동등한 배기가스 온도 조건에서는 출력이 증가할수록 최적당량비가 선형적으로 증가하는 경향을 보였다.

• 대한기계학회논문집B
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• 제28권10호
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• pp.1184-1192
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• 2004

Experimental investigations were carried out in an atmospheric pressure, optically accessible and laboratory-scale dump combustor operating on methane gas. The objective of this study was to obtain the phase-resolved gas temperatures at different phases of the oscillating pressure cycle during unstable combustion. CARS temperature measurements were made at several spatial locations under lean premixed conditions to get the information on temperature field within the combustor. Also the effect of incomplete fuel-air mixing on phase-resolved temperature fluctuation was investigated. Results including phase-resolved averaged temperature, normalized standard deviation and temperature probability distribution functions (PDFs) were provided in this paper. Temperature PDFs gave an insight on the flame behavior. And strong correlation between phase-resolved temperature profile and pressure cycle was observed. Results of the phase-resolved high temperature gave an additional information on the perturbation of equivalence ratio at flame as well as the effect of mixing quality on NOx emission characteristics.