• 한국연소학회:학술대회논문집
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• 한국연소학회 2006년도 제32회 KOSCO SYMPOSIUM 논문집
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• pp.149-156
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• 2006

Structure of edge flame established in a mixing layer, formed between two uniformly flowing pure $CH_4$ and pure $O_2$ streams, is numerically investigated by employing a detailed methane-oxidation mechanism. The numerical results exhibited the most outstanding distinction of using pure oxygen in the fuel-rich premixed-flame front, through which the carbon-containing compound is found to leak mainly in the form of CO instead of HC compounds, contrary to the rich $CH_4-air$ premixed flames in which $CH_4$ as well as $C_2H_m$ leakage can occur. Moreover, while passing through the rich premixed flame, a major route for CO production, in addition to the direct $CH_4$ decomposition, is found to be $C_2H_m$ compound formation followed by their decomposition into CO. Beyond the rich premixed flame front, CO is further oxidized into $CO_2$ in a broad diffusion-flame-like reaction zone located around moderately fuel-rich side of the stoichiometric mixture by the OH radical from the fuel-lean premixed-flame front. Since the secondary CO production through $C_2H_m$ decomposition has a relatively strong reaction intensity, an additional heat-release branch appears and the resulting heat-release profile can no longer be seen as a tribrachial structure.

• 한국연소학회지
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• 제11권1호
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• pp.19-26
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• 2006

Structure of edge flame established in a mixing layer, formed between two uniformly flowing pure $CH_4$ and pure $O_2$ streams, is numerically investigated by employing a detailed methane-oxidation mechanism. The numerical results exhibited the most outstanding distinction of using pure oxygen in the fuel-rich premixed-flame front, through which the carbon-containing compound is found to leak mainly in the form of CO instead of HC compounds, contrary to the rich $CH_4-air$ premixed flames in which $CH_4$ as well as $C_2H_m$ leakage can occur. Moreover, while passing through the rich premixed flame, a major route for CO production, in addition to the direct $CH_4$ decomposition, is found to be $C_2H_m$ compound formation followed by their decomposition into CO. Beyond the rich premixed flame front, CO is further oxidized into $CO_2$ in a broad diffusion-flame-like reaction zone located around moderately fuel-rich side of the stoichiometric mixture by the OH radical from the fuel-lean premixed-flame front. Since the secondary CO production through $C_2H_m$ decomposition has a relatively strong reaction intensity, an additional heat-release branch appears and the resulting heat-release profile can no longer be seen as a tribrachial structure.

• 한국연소학회지
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• 제9권2호
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• pp.18-29
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• 2004

Partial quenching structure of diffusion flames in a turbulent mixing layer has been investigated by the method of flame hole dynamics in oder to develope a prediction model for the phenomenon of turbulent flame lift off. The present study is specifically aimed to remedy the shortcoming of the stiff transition of the conditioned partial burning probability across the crossover condition by employing the level-set method which enables us to include the effect of finite flame edge propagation speed. In light of the level-set simulation results with two models for the edge propagation speed, the stabilizing conditions for turbulent lifted flame are suggested. The flame hole dynamics combined with the level-set method yields a temporally evolving turbulent extinction process and its partial quenching characteristics is compared with the results of the previous model employing the flame-hole random walk mapping based on three critical scalar dissipation rates. The probability to encounter reacting state, conditioned with scalar dissipation rate, demonstrated that the conditional probability has a rather gradual transition across the crossover scalar dissipation rate. Such a smooth transition is attributed to the finite response of the flame edge propagation.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2004년도 추계학술대회
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• pp.1162-1165
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• 2004

Size and crystalline phase changes of $Fe_{2}O_{3}$ nanoparticles formed in a $H_{2}/O_{2}$ flame have been investigated. At flame temperatures below $1350^{\circ}C$, the mean particle size increased monotonously with the distance from the burner edge; but in high-temperature flames above $1650^{\circ}C$, it suddenly decreased from 20 nm to ${\sim}3$ nm with the distance from the burner edge. The results of X-ray diffraction and HRTEM showed that this sudden reduction of the size of nanoparticles was accompanied by a partial phase transformation from ${\gamma}$-$Fe_{2}O_{3}$ into ${\alpha}$-$Fe_{2}O_{3}$. We suggest the structural instability due to ${\gamma}-$ to ${\alpha}-phase$ transformation as a mechanism for a rapid fragmentation of 20 nm particles into 3 nm ones.

• 한국연소학회지
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• 제6권1호
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• pp.7-13
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• 2001

Propagation characteristics of tribrachial flames have been studied numerically in a two-dimensional fuel/oxidizer mixing layer. A flame is initiated by imposing a high temperature ignition source. Subsequent propagation of a tribrachial flame is traced. The flow redirection effect at the leading edge of a tribrachial flame increases the propagation speed beyond the corresponding stoichiometric laminar burning velocity. The effect of mixture fraction gradient on the propagation speed of a tribrachial flame is analyzed in a mixing layer considering that mixture fraction gradient increases as a tribrachial flame propagates toward upstream. As the flame curvature at the leading edge increases with decreasing mixture fraction gradient, the flow redirection effect becomes more pronounced on the flame propagation speed. As a result, the propagation speed of a tribrachial flame increases with decreasing mixture fraction gradient.

• 대한기계학회논문집B
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• 제34권5호
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• pp.505-513
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• 2010

삼지화염 구조는 화염 선단의 구조로서 다루어져 왔으며, 많은 연구자들에 의해 해석적인 방법과 실험적인 방법으로 연구가 되어왔다. 그러나 연료의 종류에 따른 가연한계의 차이가 삼지화염의 구조에 미치는 영향에 대한 연구는 깊이 있게 다루어지지 않았다. 본 연구에서는 화염 구조에 대한 비대칭 가연한계의 영향을 예혼합화염과 확산화염에 관한 몇 가지 층류화염 이론에 근거한 간단한 수치 기법을 통해 연구하였다. 고정된 유동장이 사용되었으며, 예혼합 화염 가지에서의 경계조건이 연계되었다. 예혼합 화염 후류의 확산화염의 형성과 소멸을 성공적으로 모사할 수 있었다. 비대칭 가연한계 조건과 열손실에 따른 확산화염의 변화가 연구되었다. 본 연구는 화염의 기초 구조에 대한 이해를 도울 수 있으며, 이후의 연구를 위한 기초로 활용될 수 있을 것이다.

• 한국연소학회지
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• 제8권3호
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• pp.15-23
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• 2003

Partial quenching structure of turbulent diffusion flames in a turbulent mixing layer is investigated by the method of flame hole dynamics in order to develop a prediction model for turbulent flame lift off. The essence of flame hole dynamics is derivation of the random walk mapping, from the flame-edge theory, which governs expansion or contraction of flame holes initially created by local quenching events. The numerical simulation for flame hole dynamics is carried out in two stages. First, a direct numerical simulation is performed for constant-density fuel-air channel mixing layer to obtain the turbulent flow and mixing fields, from which a time series of two dimensional scalar dissipation rate array is extracted at a fixed virtual flame surface horizontally extending from the end of split plate to the downstream. Then, the Lagrangian simulation of the flame hole random walk mapping projected to the scalar dissipation rate array yields temporally evolving turbulent extinction process and its statistics on partial quenching characteristics. The statistical results exhibit that the chance of partial quenching is strongly influenced by the crossover scalar dissipation rate while almost unaffected by the iteration number of the mapping that can be regarded as a flame-edge speed.

• 대한기계학회논문집B
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• 제35권6호
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• pp.633-640
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• 2011

본 연구에서는 고온의 미소농도구배 조건에서의 에지화염의 안정화 및 화염 강도 변화를 실험적으로 관찰하였다. 실험 연소기는 크게 혼합기가 투입되는 슬롯과 석영 채널 및 채널 내부 가열을 위한 추가적인 예혼합 연소기로 구성되어 있다. 실험의 정확성을 위해 각 경계 조건에 대한 정량적인 검증 절차가 수행되었다. 결론적으로 연료 농도 구배의 정량적인 제어와 질소 희석비율을 조절하여 고온의 조건에서도 에지화염을 임의의 위치에 안정화 시킬 수 있었다. 에지화염 내부에 존재하는 확산화염의 화염 강도가 채널 내부의 온도증가에 따라 증가하고 질소의 희석비율 증가에 따라 감소하는 것을 보였다. 연료에 따른 화염 강도 변화를 살펴본 결과 프로판의 경우가 메탄에 비해 강도 변화율이 큰 것을 알 수 있었다.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2004년도 제28회 KOSCO SYMPOSIUM 논문집
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• pp.102-111
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• 2004

Partial quenching structure of turbulent diffusion flames in a turbulent mixing layer is investigated by the method of flame hole dynamics to develope a prediction model for the turbulent lift off. The present study is specifically aimed to remedy the problem of the stiff transition of the conditioned partial burning probability across the crossover condition by adopting level-set method which describes propagating or retreating flame front with specified propagation speed. In light of the level-set simulations with two model problems for the propagation speed, the stabilizing conditions for a turbulent lifted flame are suggested. The flame hole dynamics combined with level-set method yields a temporally evolving turbulent extinction process and its partial quenching characteristics is compared with the results of the previous model employing the flame-hole random walk mapping. The probability to encounter reacting' state, conditioned with scalar dissipation rate, demonstrated that the conditional probability has a rather gradual transition across the crossover scalar dissipation rate in contrast to the stiff transition of resulted from the flame-hole random walk mapping and could be attributed to the finite response of the flame edge propagation.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2014년도 제49회 KOSCO SYMPOSIUM 초록집
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• pp.175-178
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• 2014

The flame cell dynamics in 2-D opposed nonpremixed tubular configuration was investigated using high-fidelity numerical simulations. The diffusive-thermal instability occurs as the $Damk{\ddot{o}}hler$ number, Da, approaches the 1-D extinction limit of the tubular flames and several flame cells are generated depending on Da, and flame radius. In general, the number of flame cells are found close to the largest wave number from the linear stability analysis. It was also found from the displacement speed analysis that during the local flame extinction and cell formation, negative edge flame speed is observed due to small gain from reaction compared to large loss from diffusion.