• Journal of Korean Society of Environmental Engineers
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• v.36 no.11
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• pp.725-732
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• 2014

Phytoremediation is a technology to mitigate the pollutant concentrations such as metals, pesticides, solvents, oils, or others in contaminated water and soils with plants. The plants absorb contaminants through the root and store them in the root, stems, or leaves. Rapid growth trees such as poplar are used to remove low concentrated contaminants eco-friendly and economically in a wide contaminated region. This study was practiced to evaluate an activated carbon production system by using poplar wood discarded after phytoremediation. Life cycle assessment methodology was used to analyze environmental impacts of the system, and the functional unit was one ton of harvested poplar. It was estimated that the small size rotary kiln for activated carbon production from poplar wood had an environmental benefit in optimized conditions to minimize energy consumptions. The results of an avoided environmental impact analysis show that the system contribute to reduce environmental impacts in comparison with activated carbon production from coconut shell.

• Journal of Korean Society for Atmospheric Environment
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• v.26 no.4
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• pp.443-448
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• 2010

The objective of this study was to assess the catalytic activities of manganese oxide (MnO, $MnO_2$, $Mn_2O_3$, and $Mn_3O_4$) catalysts for odors (acetaldehyde and propionaldehyde) removal. We used a fixed bed reactor as the experimental apparatus and the catalytic performance were carried out over the temperature range of $200{\sim}470^{\circ}C$. The properties and performance of catalysts were characterized by the X-ray diffraction (XRD) and Brunauer Emmett Teller (BET). The catalytic activities of manganese oxide catalysts for acetaldehyde combustion were in the order of MnO < $MnO_2$ < $Mn_2O_3$ < $Mn_3O_4$, and it is similar to that of propionaldehyde combustion. We also confirmed that the reactions have well followed the kinetic model of Power-Rate Law and the reaction order (n) is 1 for both of the acetaldehyde and propionaldehyde combustion. In addition, the reaction activation energy of acetaldehyde and propionaldehyde combustion over $Mn_3O_4$ were found to be $72.42\;kJmol^{-1}$ for 487~503 K and $51.14\;kJmol^{-1}$ for 473~533 K, respectively.

• Journal of Environmental Science International
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• v.28 no.12
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• pp.1147-1156
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• 2019

The purpose of this study was to analyze examples of green infrastructure presented by the American Society of Landscape Architects as a part of basic research to assess hub green spaces in cities. With the specific goal of green infrasturcture in mind, the study samples were classified according to their purpose: 'humanities', 'hydrology', 'ecology', and 'environment'. Based on this we assessed the elements of planning for the target sites and obtained the following results. With regard to the aspect of humanities, planning urban hub green spaces was related to the satisfaction in leisure activities and the 'quality of life' that people expect to enjoy at parks or other green areas in general. Rather than focusing on direct and visible benefits, which might come from green infrastructure's technological elements, people hoped that parks and green areas have macroscopic values. For hydrological characteristics, the 'ecologically manages stormwater' was applied the most in planning hub green spaces in cities, and it mainly took the form of technological elements or factors. Third, the planning elements pertaining to ecological characteristics were identified as a combination of strategies and technological elements that 'reintroduces native plants' and 'habitat for wildlife'. As for the plans to instill eco-friendly aspects, the study found that the research on air, climate, weather, heat reaction, soil, energy efficiency, and use and application of resources is important. However, it was difficult to measure the potential quantitative benefits of 'reusing or recycling materials', 'reducing urban heat', and 'cooling air temperature'. The result of this study is meaningful in that it can be used for the assessment of urban hub green spaces in the future.

• Applied Chemistry for Engineering
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• v.28 no.5
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• pp.513-520
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• 2017

The application possibility of an alternative new method with low energy consumption was studied for the eco-friendly fabrication of foamed glasses from waste glasses. As a result, fabricating temperature can be reduced under $300^{\circ}C$ without using various expensive inorganic oxidants. The foamed glass can be fabricated at a proper mixing ratio of the waste glass powder, water glass, little surfactant and bubble stabilizer by induction heating method. In the experimental range, the assured optimal condition is 4 min heating on the induction machine with a steel-container ($100mm{\times}100mm{\times}20mm$) and followed by evaporating and drying process for 11 min with 110 g of glass powder, 80 g of water glass, 3 g of surfactant and 0.2 g of bubble stabilizer. When the foamed glass was fabricated at the optimal condition, the density of the glass was $0.85g/cm^3$ and the heat conduction was $0.052W/h{\cdot}K$. In addition, the compressive strength of the glass was above $50kg/cm^2$.

• Proceedings of the Materials Research Society of Korea Conference
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• 2012.05a
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• pp.73-73
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• 2012

Modern technology-driven society largely relies on hybrid electric vehicles or electric vehicles for eco-friendly transportation and the use of high technology devices. Lithium rechargeable batteries are the most promising power sources because of its high energy density but still have a challenge. Graphite is the most widely used anode material in the field of lithium rechargeable batteries due to its many advantages such as good cyclic performances, and high charge/discharge efficiency in the initial cycle. However, it has an important safety issue associated with the dendritic lithium growth on the anode surface at high charging current because the conventional graphite approaches almost 0 V vs $Li/Li^+$ at the end of lithium insertion. Therefore, a fundamental solution is to use an electrochemical redox couple with higher equilibrium potentials, which suppresses lithium metal formation on the anode surface. Among the candidates, $Li_4Ti_5O_{12}$ is a very interesting intercalation compound with safe operation, high rate capability, no volume change, and excellent cycleability. But the insulating character of $Li_4Ti_5O_{12}$ has raised concerns about its electrochemical performance. The initial insulating character associated with Ti4+ in $Li_4Ti_5O_{12}$ limits the electronic transfer between particles and to the external circuit, thereby worsening its high rate performance. In order to overcome these weak points, several alternative synthetic methods are highly required. Hence, in this presentation, novel ways using a synergetic strategy based on 1D architecture and surface coating will be introduced to enhance the kinetic property of Ti-based electrode. In addition, first-principle calculation will prove its significance to design Ti-based electrode for the most optimized electrochemical performance.

• Bulletin of the Korean Chemical Society
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• v.34 no.10
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• pp.3065-3072
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• 2013

Direct synthesis of $H_2O_2$ and in situ oxidative desulfurization of model fuel over Au/Ti-HMS and Au/TS-1 catalysts has been comparatively investigated in water or methanol. Maximum amount (82%) of active $Au^0$ species for $H_2O_2$ synthesis was obtained. Au/Ti-HMS and Au/TS-1 exhibited the contrary performances in $H_2O_2$ synthesis as $CH_3OH/H_2O$ ratio of solvent changed. $H_2O_2$ decomposition and hydrogenation in water was inhibited by the introduction of methanol. Effect of $O_2/H_2$ ratio on $H_2O_2$ concentration, $H_2$ conversion and $H_2O_2$ selectivity revealed a relationship between $H_2O_2$ generation and $H_2$ consumption. The highest dibenzothiophene removal rate (83.2%) was obtained over Au/Ti-HMS in methanol at 1.5 of $O_2/H_2$ ratio and $60^{\circ}C$. But removal of thiophene over Au/TS-1 should be performed in water without heating to obtain a high removal rate (61.3%). Meanwhile, $H_2$ conversion and oxidative desulfurization selectivity of $H_2$ were presented.

• Clean Technology
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• v.18 no.2
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• pp.123-143
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• 2012

Supercritical fluid technology (SFT) is recently one of the most new techniques, which has been interested various fields of related chemical industries. SFT is the most effective and practical technology with eco-friendly, energy-savings, and high efficiency as the technique using the advantages of supercritical fluid such as high solvation power, solubility, mass transfer rate, and diffusion rate. Especially, it is necessary to analyze, evaluate, and develop the potential of application techniques using SFT with these characterizations. Therefore in this review, the phase behavior in supercritical fluid at high temperature and pressure of monomers/polymers for the optimization of polymerization process are briefly described, and the preparation of molecularly imprinted polymers (MIPs) in supercritical fluid using supercritical polymerization and the performance evaluation of MIPs are introduced.

• Journal of Microbiology and Biotechnology
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• v.24 no.4
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• pp.453-464
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• 2014

The current research was focused on the extracellular biosynthesis of bactericidal silver nanoparticles (AgNPs) using cell-free supernatant of a local isolate previously identified as a novel Streptomyces aegyptia NEAE 102. The biosynthesis of silver nanoparticles by Streptomyces aegyptia NEAE 102 was quite fast and required far less time than previously published strains. The produced particles showed a single surface plasmon resonance peak at 400 nm by UV-Vis spectroscopy, which confirmed the presence of AgNPs. Response surface methodology was chosen to evaluate the effects of four process variables ($AgNO_3$ concentration, incubation period, pH levels, and inoculum size) on the biosynthesis of silver nanoparticles by Streptomyces aegyptia NEAE 102. Statistical analysis of the results showed that the linear and quadratic effects of incubation period, initial pH, and inoculum size had a significant effect (p < 0.05) on the biosynthesis of silver nanoparticles by Streptomyces aegyptia NEAE 102. The maximum silver nanoparticles biosynthesis (2.5 OD, at 400 nm ) was achieved in runs number 5 and 14 under the conditions of 1 mM $AgNO_3$ (1-1.5% (v/v)), incubation period (72-96 h), initial pH (9-10), and inoculum size (2-4% (v/v)). An overall 4-fold increase in AgNPs biosynthesis was obtained as compared with that of unoptimized conditions. The biosynthesized silver nanoparticles were characterized using UV-VIS spectrophotometer and Fourier transform infrared spectroscopy analysis, in addition to antimicrobial properties. The biosynthesized AgNPs significantly inhibited the growth of medically important pathogenic gram-positive (Staphylococcus aureus) and gram-negative bacteria (Pseudomonas aeruginosa) and yeast (Candida albicans).

• Journal of the Korea Safety Management & Science
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• v.12 no.4
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• pp.41-51
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• 2010

This paper describes the development of various lighting equipment adapting Ultra Constant Discharge Lamp that has newly been on commercial supply in the market. Meeting the required conditions of lighting equipment, various types of UCD Lamp equipment with excellent performances could be successfully developed. In order to provide a guideline for the economical lighting product selection, the analyzed data comparison between Hi-pressure Sodium Lamp which has been the most popular lamp for street lighting and UCD Lamp is provided. The conclusions of the study are made as follows; (1) The performance measurement result of UCD Lamp shows excellent Luminous Efficacy as 108Lm/W, daylight-like Color Rendering Index as 90Ra, and the best operating temperature range as $-50^{\circ}C{\sim}+85^{\circ}C$. Comparing to the Hi-pressure Sodium Lamp, UCD could be evaluated as much superior products. (2) In an assembled status with the lighting fixture (Type STB형-60W), UCD Lamp was tested OK for one hour duration at the temperature range form $-50^{\circ}C$ to $+85^{\circ}C$ and the humidity of 98%. The operation at the extremely low temperature can be an excellent feature to enable the export to the cold temperature regions such as Northern Europe and Russia and the specific applications for defense systems and special industry. (3) As UCD Lamp is a genuine Korea made product following Energy-saving and Eco-friendly policy, it should be appreciated as one of the best $CO^2$ reduction Green product.

• Journal of Adhesion and Interface
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• v.20 no.4
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• pp.140-145
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• 2019

In view of environmental considerations, the control of carbon dioxide (CO₂) and volatile organic compounds (VOCs) is one of important issues in the film and coating industries. Therefore, UV-curable system has been developed due to minimize emissions of VOCs and reduce CO₂ emission due to low energy consumption from fast curing. Also, biodegradable polymers economically are attractive because of environmental and economic concerns associated with huge waste plastics. In this study, UV-curable polyurethane acrylates with different compositions of biodegradable polylactide (PLA) diol and poly(ethylene glycol) as diols were synthesized and curing reaction of their end-capped acrylates was performed by UV exposure. Tensile strength, elongation, and Tg of the UV-cured polyurethane acrylates increased with PLA diol content in the diol while their hydrophilicity and thermal stability increased with the PEG content. These results indicated a property of UV-cured polyurethane acrylates could be controlled by environment-friendly diols.