• Title/Summary/Keyword: eco cement

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Surface characteristics for thermal diffusion of FA-BFS-based geopolymer ceramics added alumina aggregate (알루미나 골재를 첨가한 FA-BFS계 지오폴리머 세라믹스의 열확산에 대한 표면 특성)

  • Kim, Jin-Ho;Park, Hyun;Kim, Kyung-Nam
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.2
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    • pp.61-70
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    • 2019
  • Geopolymer is an eco-friendly construction material that has various advantages such as reduced $CO_2$ emission, fire resistance and low thermal conductivity compared to cement. However, it has not been many studies on the thermal behavior of the surface of the geopolymer panel when flame is applied to the surface. In this study, surface characteristics of hardened geopolymer on flame exposure was investigated to observe its characteristics as heat-resistant architectural materials. External structure changes and crack due to the heat shock were not observed during the exposure on flame. According to the residue of calcite and halo pattern of aluminosilicate gel, decarboxylation and dehydration were extremely limited to the surface and, therefore, it is thought that durability of hardened geopolymer was sustained. Gehlenite and calcium silicate portion was inversely proportional to quartz and calcite and significantly directly proportional to BFS replacement ratio. Microstructure changes due to the thermal shock caused decarboxylation and dehydration of crystallization and it was developed the pore and new crystalline phase like calcium silicate and gehlenite. It is thought that those crystalline phase worked as a densification and strengthening mechanism on geopolymer panel surface.

Erosion Characteristics of TGase-added Biopolymers (TGase 첨가 바이오폴리머의 침식특성 연구)

  • Kanghyun Kim;Seunghyun Kim;Dohee Kim;Jongho Shin
    • Journal of the Korean GEO-environmental Society
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    • v.24 no.9
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    • pp.5-13
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    • 2023
  • Cement-based reinforcement materials, which are representative slope reinforcement materials, can cause contamination of ground and groundwater when ground injection or surface application is applied. Accordingly, slope reinforcement materials using eco-friendly biopolymers are attracting attention as a means of replacing existing materials, but the biopolymers currently used are easily dissolved when exposed to groundwater or rainfall environments, reducing strength. In order to solve this problem, the cross-linking of protein between sodium casein and Transglutaminase (TGase, C20H16N4O2S2) was used to increase the water resistance of biopolymers, and a rainfall slope test was conducted to evaluate their usability and applicability as a slope reinforcing material. In the case of reinforcement with only sodium casein, the precipitation dissolved sodium casein, and the slope was completely destroyed in 1 hour. On the other hand, it was observed that the slope reinforced by adding a small amount of TGase (0.5%) do not collapse even after 80 hours of rainfall duration due to increased water resistance. Strength and water resistance increases due to the addition of a small amount of TGase, and its applicability as an eco-friendly reinforcement is confirmed.

Watertightness and Durability Properties of Ultra Rapid Hardening Grout using Bottom-ash (잔골재 대체재로서 바텀애쉬를 이용한 초속경 그라우트재의 수밀성 및 내구특성)

  • Lee, Gun-Cheol;Oh, Dong-Uk;Cho, Byoung-Young;Kim, Young-Geun;Cho, Chung-Ki
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.3
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    • pp.102-109
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    • 2011
  • In this study, in order to develop ultra rapid hardening mortar(URHM) for tunnel repairs using bottom ash of low recycle ratio and Admixture as Eco concept, watertightness and durability properties of URHM on temperature condition of construction field were performed. Test result, seepage quantity and water absorption coefficient regarding watertightness of URHM were as in the following : series II > series I. Seepage quantity for the standard condition were smaller than low temperatures. all specimens were satisfied below 20g as standards of seepage quantity on KS F 4042. Because of the decrease of unit cement content by to replacement of blast furnace slag, the neutrlization resistance for durability properties was reduced. The result of alkali resistance and acide resistance, compressive strengths for specimens soaked in calcium hydroxide solution of seriesI were lower than compressive strengths for specimens not soaked. On the other hand, the case of series II show that the deterioration of compressive strengths for specimens was not almost showed. Compressive strengths of specimens soaked were similar with specimens not soaked except series II-C in $5^{\circ}C$. Therefore, specimens using both blast furnace slag and bottom ash were good in alkali resistance and acide resistance.

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Compressive Strength Properties of Geopolymer Using Power Plant Bottom Ash and NaOH Activator (화력발전소 바텀애쉬와 수산화나트륨 활성화제를 이용해 제작한 지오폴리머의 압축강도 특성)

  • An, Eung-Mo;Cho, Sung-Baek;Lee, Su-Jeong;Miyauchi, Hiroyuki;Kim, Gyu-Yong
    • Korean Journal of Materials Research
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    • v.22 no.2
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    • pp.71-77
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    • 2012
  • When a new bonding agent using coal ash is utilized as a substitute for cement, it has the advantages of offering a reduction in the generation of carbon dioxide and securing the initial mechanical strength such that the agent has attracted strong interest from recycling and eco-friendly construction industries. This study aims to establish the production conditions of new hardening materials using clean bottom ash and an alkali activation process to evaluate the characteristics of newly manufactured hardening materials. The alkali activator for the compression process uses a NaOH solution. This study concentrated on strength development according to the concentration of the NaOH solution, the curing temperature, and the curing time. The highest compressive strength of a compressed body appeared at 61.24MPa after curing at $60^{\circ}C$ for 28 days. This result indicates that a higher curing temperature is required to obtain a higher strength body. Also, the degree of geopolymerization was examined using a scanning electron microscope, revealing a micro-structure consisting of a glass-like matrix and crystalized grains. The microstructures generated from the activation reaction of sodium hydroxide were widely distributed in terms of the factors that exercise an effect on the compressive strength of the geopolymer hardening bodies. The Si/Al ratio of the geopolymer having the maximum strength was about 2.41.

Characteristics of Cyclic Drying-Wetting on Strength of Solidified Soil Mixed Porosity Silica (다공성 실리카를 혼합한 경화토의 건습반복 강도특성)

  • Kim, Donggeun;Bang, Seongtaek;Oh, Sewook
    • Journal of the Korean GEO-environmental Society
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    • v.15 no.10
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    • pp.29-34
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    • 2014
  • In order to examine strength properties depended on climate changes of solidified soil amended by porosity silica which enhance harms of cement, this study conducts a wetting and drying repetition test and then, attempts to verify strength properties before and after solidified soil gets environmental influence. Test pieces for the unconfined compression test changed the mixing ratio of solidified soil compared to mixed soil weigh to 5 %, 10 % and 15 %. For each step, it was created by mixing 0.5 %, 1.0 % and 1.5 % of wood chips, and curing period for 7, 14, and 28 days. Then, the wetting and drying repetition process was repeated 0, 3, 6, and 12 cycles to analyze mechanical properties. To also evaluate changes of relative dynamic elastic modulus before and after the wetting and drying, dynamic elastic modulus tests were conducted when each cycle was completed.

Fabrication Characteristics of Slag Fiber by 4 Wheel System (4휠 시스템을 이용한 슬래그 섬유의 제조)

  • Song, Yeong-Hwan;Seong, Hwan-Goo;Park, Soo-Han;Wang, Xiaosong;Hur, Bo-Young
    • Journal of Korea Foundry Society
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    • v.26 no.5
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    • pp.222-226
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    • 2006
  • Steel making slag has gained a considerable attraction as one candidate of eco-materials in research fields for recycling resources. Thus, many researches have been performed but were limited to development of substitute for cement being used in the construction field. A little research work also has been done on development of higher value-added materials, including heat resistant and sound absorbing materials. For this reason, the present study were focused on macrostructure characterization of fabricated slag fibers which are applicable to heat resistant materials. The slag fibers were fabricated through a modified melt extraction method. The processing variables employed were the wheel speed and molten slag temperature. The synthesized fibers were characterized by optical microscope and scanning electron microscopy. It was found that the wheel speed of 1400 rpm generated better quality of mineral fibers in terms of the relative amount of shot, diameter and length. This was attributed to the relative extent of contact width between the flowing melt and the rotating wheel. The thickness of the slag fibers also were decreased with increasing the slag melt temperature due mainly to significant decrease in the viscosity of the slag melt. In addition, the lower melt temperature caused an increase in number of shots plus the mineral fibers.

A Study on Seepage Cutoff Effect of the Environmentally Friendly SCM (SCM 친환경주입공법에 의한 차수 효과에 관한 연구)

  • Chun, Byung-Sik;Roh, Jong-Ryun;Jooi, Tae-Seong;Do, Jong-Nam
    • Journal of the Korean GEO-environmental Society
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    • v.6 no.4
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    • pp.65-71
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    • 2005
  • Recently, difficulties in soft ground improvement that caused by effectiveness of the ground improvement, the durability and environmentally friendliness of the injection material come to the fore. This paper studies the field applicability of the SCM in reinforcement and seepage cutoff of the back of an existing continuous wall. SCM uses double rod which imposes heavy pressure($10-100kgf/cm^2$) to disturbed, cut, discharge, and mix the ground. It is observed that a bulb is formed by using cement paste and environmentally friendly injection materials with minimal alkali leaching. Unconfined compression test and fish poison tests are performed. Test results indicate that the method results in higher durability, less leaching through use of the environmentally friendly injection material, and faster mobilization of the strength. In addition, field tests confirm the formation of the bulb and the seepage cutoff wall.

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The Planning of Temporary Housing for Post Application of Mega Sports Facilities - Focused on the 2018 Winter Olympics - (메가스포츠시설의 사후 활용을 위한 임시주거 계획 - 2018평창동계올림픽을 중심으로 -)

  • Lee, Jong-Chan;Kang, Youn-Do;Kim, Byung-Sean
    • KIEAE Journal
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    • v.16 no.4
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    • pp.41-46
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    • 2016
  • Purpose: This is a study on the planning of temporary housing for post application of Mega Sports facilities. The subject of the study is 2018 Pyeongchang Winter Olympics, which is to suggest building an alternative temporary housing using shipping containers(high cube), which solve the lack of accommodations and recycle temporary housing after Olympics, save money and be eco-friendly in Olympics. Method: This study includes this ; research on the a fact-finding survey about Mega sports facilities post application and demand survey on 2018 Pyeongchang Winter Olympics accomodations and an analysis about temporary housing plan. Furthermore we decided temporary housing building plan by analyzing residents' needs and traits of the housing etc. Through this, we made a schematic design for household units. Result: As a result, this study is a plan of making space, forms, and structure. The planned size is $38.4m^2$(L:12m, W:3.2m) except balcony, and indoor height is 2.5m. The space consists of entrance, bathroom, bedroom and living room with folding furniture system. Also there's a detailed floor plan of the ceiling, wall, and floor we drew up. The ceiling and wall consist of dampproof film, noncombustible board, fire proof urethane form, and color-designed sheet. The floor is composed of floor tile, cement mortar, light concrete(with heat coil), insulation, and dampproof film. Additionally, this study is a plan of interior dry wall with detail using modular construction method for work efficiency and quality improvement.

Evaluation of PLA Fiber Dissolution in Cement Paste and Geopolymer (시멘트 페이스트 및 지오폴리머 내의 PLA 섬유의 용해성 평가)

  • Kim, Joo-Hyung;Kwon, Seung-Jun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.2
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    • pp.204-211
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    • 2020
  • Poly-Lactic Acid(PLA) fiber is an eco-friendly material and is biodegradable, so it can be utilized for manufacturing porous construction materia ls with interna l pore connection. In this study, domestic PLA fiber products(0.5mm india meter, 1.0mm in length, 10mm in length) were tested for melting at high temperatures and high alkality, and they were incorporated with FA-based geopolymer. Compressive strength was obtained through high temperature curing and alkali activator, however the complete melting of the PLA fiber was not ensured. The previous study handling PLA fiber with 0.003mm in diameter was completely dissolved, but 0.5mm and 1.0mm in diameter showed 42.5% and 33.3% of dissolution ratio, respectively. In addition, the increasing fiber volume led floating fibers during curing, which had a negative effect on its workability and solubility. Although the properties of PLA fiber may vary depending on the raw materials and production conditions, PLA fiber with 0.1mm or less diameter is recommended for porous construction material.

Development of Eco-friendly Cement using Reverse Osmosis Brine Water and Metakaolin (역삼투압 농축수와 메타카올린을 사용한 친환경 시멘트의 개발)

  • Kim, Taewan;Han, Ki-Bong;Kim, Do-Hyung;Seo, Ki-Young
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.2
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    • pp.216-222
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    • 2021
  • This is an experiment to complement new ways of using concentrated water discharged from the seawater desalination plant. In this study, metakaolin, which has excellent chloride ion immobilization effect, was used as the main binder, and 10% and 20% of calcium oxide were substituted with the activator. In addition, tap-water(TW) and reverse osmosis brine water(RW) were used as mixed water. As a result of the experiment, the mixture using RW showed higher compressive strength than TW. It also showed low water absorption and high density. In the mixture using RW as mixed water, a hydration reaction substance called Friedel's salt could be observed. Considering the corrosion problem of steel, RW is considered to be applicable to products such as non-reinforced concrete, brick, and curb stone. Through this study, it is thought that it is meaningful to propose a new application method other than the ocean release of RW.