• Proceedings of the Korean Vacuum Society Conference
• /
• 2012.08a
• /
• pp.222-222
• /
• 2012

Metal oxide gas sensors based on semiconductor type have attracted a great deal of attention due to their low cost, flexible production and simple usability. However, most works have been focused on n-type oxides, while the characteristics of p-type oxide gas sensors have been barely studied. An investigation on p-type oxides is very important in that the use of them makes possible the novel sensors such as p-n diode and tandem devices. Monoclinic cupric oxide (CuO) is p-type semiconductor with narrow band gap (~1.2 eV). This is composed of abundant, nontoxic elements on earth, and thus low-cost, environment-friendly devices can be realized. However, gas sensing properties of neat CuO were rarely explored and the mechanism still remains unclear. In this work, the neat CuO layers with highly ordered mesoporous structures were prepared by a template-free, one-pot solution-based method using novel ink solutions, formulated with copper formate tetrahydrate, hexylamine and ethyl cellulose. The shear viscosity of the formulated solutions was 5.79 Pa s at a shear rate of 1 s-1. The solutions were coated on SiO2/Si substrates by spin-coating (ink) and calcined for 1 h at the temperature of $200{\sim}600^{\circ}C$ in air. The surface and cross-sectional morphologies of the formed CuO layers were observed by a focused ion beam scanning electron microscopy (FIB-SEM) and porosity was determined by image analysis using simple computer-programming. XRD analysis showed phase evolutions of the layers, depending on the calcination temperature, and thermal decompositions of the neat precursor and the formulated ink were investigated by TGA and DSC. As a result, the formation of the porous structures was attributed to the vaporization of ethyl cellulose contained in the solutions. Mesoporous CuO, formed with the ink solution, consisted of grains and pores with nano-meter size. All of them were strongly dependent on calcination temperature. Sensing properties toward H2 and C2H5OH gases were examined as a function of operating temperature. High and fast responses toward H2 and C2H5OH gases were discussed in terms of crystallinity, nonstoichiometry and morphological factors such as porosity, grain size and surface-to-volume ratio. To our knowledge, the responses toward H2 and C2H5OH gases of these CuO gas sensors are comparable to previously reported values.

• Journal of Korea Technical Association of The Pulp and Paper Industry
• /
• v.47 no.4
• /
• pp.177-186
• /
• 2015

Until Mandelbrot introduced the concept of fractal geometry and fractal dimension in early 1970s, it has been generally considered that the geometry of nature should be too complex and irregular to describe analytically or mathematically. Here fractal dimension indicates a non-integer number such as 0.5, 1.5, or 2.5 instead of only integers used in the traditional Euclidean geometry, i.e., 0 for point, 1 for line, 2 for area, and 3 for volume. Since his pioneering work on fractal geometry, the geometry of nature has been found fractal. Mandelbrot introduced the concept of fractal geometry. For example, fractal geometry has been found in mountains, coastlines, clouds, lightning, earthquakes, turbulence, trees and plants. Even human organs are found to be fractal. This suggests that the fractal geometry should be the law for Nature rather than the exception. Fractal geometry has a hierarchical structure consisting of the elements having the same shape, but the different sizes from the largest to the smallest. Thus, fractal geometry can be characterized by the similarity and hierarchical structure. A process requires driving energy to proceed. Otherwise, the process would stop. A hierarchical structure is considered ideal to generate such driving force. This explains why natural process or phenomena such as lightning, thunderstorm, earth quakes, and turbulence has fractal geometry. It would not be surprising to find that even the human organs such as the brain, the lung, and the circulatory system have fractal geometry. Until now, a normal frequency distribution (or Gaussian frequency distribution) has been commonly used to describe frequencies of an object. However, a log-normal frequency distribution has been most frequently found in natural phenomena and chemical processes such as corrosion and coagulation. It can be mathematically shown that if an object has a log-normal frequency distribution, it has fractal geometry. In other words, these two go hand in hand. Lastly, applying fractal principles is discussed, focusing on pulp and paper industry. The principles should be applicable to characterizing surface roughness, particle size distributions, and formation. They should be also applicable to wet-end chemistry for ideal mixing, felt and fabric design for papermaking process, dewatering, drying, creping, and post-converting such as laminating, embossing, and printing.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.30 no.1
• /
• pp.17-20
• /
• 2020

Developing effective and earth-abundant electrocatalyst for oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) is critical for the commercialization of a water splitting system. In particular, the overpotential of the OER is relatively higher than the HER, and thus, it is considered that one of the important methods to enhance the performance of the electrocatalyst is to reduce the overpotential of the OER. In this work, we present a simple synthetic route for triple perovskite Nd_1.5Ba_1.5CoFeMnO_x with high performance OER and HER activity. This triple perovskite structure which shows high crystallinity through combustion method shows superior bifunctional catalytic performance in alkaline media. We believe that the prepared triple provskite with high performance OER and HER activity can give further feasibility for the commercialization of a water splitting system.

• Journal of the Korean GEO-environmental Society
• /
• v.16 no.1
• /
• pp.37-43
• /
• 2015

Korea has four distinct seasons, showing hot and humidity in summer and cold weather lasted in winter. Domestic research on earth work has been developed according to the seasonal characteristics, and most of research topics have focused on the effect of freezing-thawing on the performance of geo-materials. However, the previous research was performed on the ground compacted at room temperature and therefore, the effect of the sub-zero temperature at the time of construction was not fully investigated. The ground characteristics compacted at freezing temperature can be different from those at room temperature and show different characteristics of strength and deformation caused by freezing and thawing. Therefore, the compaction tests on sandy materials were conducted under various temperature at $-3^{\circ}C$ and $-8^{\circ}C$ with various fine contents of 0%, 5%, 10% and 15% in weight fraction. The effectiveness of soil compaction at below-freezing temperatures were compared with the compaction at room temperature at $18^{\circ}C$ in terms of the maximum dry unit weight and optimum water contents. Based on the test results, the maximum dry unit weight tends to decrease with the freezing temperature and the relative compaction at $-8^{\circ}C$ can not be satisfied with general specification standard.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
• /
• v.5 no.4
• /
• pp.283-295
• /
• 2007

The technical feasibility of a pyroprocessing of PWR spent fuels to recover nuclear fuel materials, uranium and transuranic elements group(TRU), was examined in this study. Also its applicability as a new fuel cycle technology in terms of non-proliferation was investigated. First, various unit processes were combined to a pyroprocess. Then the flow aspects of such materials of issue as uranium, transuraniums, rare earth, noble metals and heat generating elements were examined on the flowsheet, which was obtained by the assumptions on the basis of various experimental results in this work or separation data collected from literatures. Consequently, the calculated results of the material balance for the whole process showed that uranium and TRU could be recovered as products by 98.0 % and 97.0 %, respectively, from a PWR spent fuel while removing the other elemental groups into radioactive wastes. On the one hand, the TRU product was found to emit a considerable amount of ${\gamma}$-ray as well as neutrons favorably contributing to the strategy of proliferation resistance.

• Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
• /
• v.31 no.6_1
• /
• pp.463-469
• /
• 2013

In addition to the VRS-RTK service, FKP-RTK service launched recently in Korea however unlike VRS, it is not yet applied to various surveying tasks. VRS system is operated in two way communication over the mobile Internet. When user send rover position data to network RTK server and the server provides correction data to users continuously. It causes to increase communications load and makes delaying or failure in data transmission depends on server capacity and number of concurrent users. In contrast, since FKP system is one way communication system, user only receives correction data and area correction parameters for the selected Continuous Reference Station from the server. Thus, there is no limitation to the number of concurrent users in FKP system and it would be more efficient than VRS system in terms of economic. To this end, we performed FKP-RTK test for Unified Control Points and Urban Control Points where are located at 5 regions in Korea to evaluate the accuracy. As a result, almost of FKP positioning data are in error range of ${\pm}6.2cm$ in horizontal and it would be enough for construction survey such as for earth work in limited except precise structure survey.

• Geophysics and Geophysical Exploration
• /
• v.2 no.1
• /
• pp.8-16
• /
• 1999

In terms of high resolution, seismic reflection survey is by far the most significant geophysical method applied to define subsurface structure. In shallow seismic reflection survey, it is, however, difficult to obtain high resolution image due to both the wave attenuation in the unconsolidated layer and the existence of source-generated surface waves Therefore, when collecting data, it is imperative to select proper equipments and choose optimum field data acquisition parameters for acquiring high S/N data. In this survey, a small size hammer was used as a low energy source and 40-Hz vertical geophones were used as receivers. Trigger signal was obtained from the hammer starter attached in the aluminum plate and thus it was possible to control the source onset time for the vertical stack. During the field work, a modified standard CMP technique was introduced to achieve the many-fold CMP data effectively. Data processing was conducted by the 'Seismic Unix' which is mounted on PC with a Linux operating system. The main distinctions were the emphasis and detail placed on near-surface velocity analysis and the extra care exercised in muting.

• Journal of the Korean Society for Aeronautical & Space Sciences
• /
• v.42 no.8
• /
• pp.692-700
• /
• 2014

In this work, satellite FE (finite element) model updating for the prediction of the effect of micro-vibration is described. In the case of satellites launched in low earth orbit, high agility and more mission accomplishments are required by the customer in order to procure many images from satellites. To achieve the goal, many mechanisms, including high capacity wheels and antennas with multi-axis gimbals have been widely adopted, but they become a source of micro-vibration which could significantly deteriorate the quality of images. To investigate the effect due to the micro-vibration in orbit on the ground, a prediction is conducted through an integrated model coupling the measured jitter sources with FE (finite element) model. Before prediction, the FE model is updated to match simulation results with the modal survey test. Subsequently, the quality of FE model is evaluated in terms of frequency deviation error, the resemblance of mode shapes and FRFs (frequency response functions) between test and analysis.

• Journal of the Korean Society for Marine Environment & Energy
• /
• v.13 no.4
• /
• pp.327-334
• /
• 2010

The paper describes the history and the evolution of the conflict of the Saemangeum reclamation project, focusing on the court trial processes. The Saemangeum project is the world largest coastal reclamation work, regarded as the most controversial environmental issue in the recent history of Korea. Due to the severe pollution found in Lake Sihwa in 1996, the Saemangeum project began to receive a large degree of public concern on the water quality of the proposed artificial freshwater lake. Unlike the Sihwa case, the Korean court system intervened to resolve the heated conflicts between stakeholders in the Saemangeum case. Based on the same set of facts, the Korean courts showed different perspectives on the economic feasibility, value of the ecosystem, land use, and water quality, which represents the limit of legal system to address complicated environmental problems. After the final judgment by the Supreme Court, 'the Special Act for the promotion of the Saemangeum reclamation project', was enacted with strong political support from local leaders and congressmen. A more developmental-oriented land use plan came out in 2009 based on this Act. The Saemangeum project walked along the different pathway from the Sihwa case. The area should be managed in sustainable manners to appropriately consider conservation and development for the prosperity of local residents and future generations.

• Journal of Korean Tunnelling and Underground Space Association
• /
• v.16 no.6
• /
• pp.599-614
• /
• 2014

When tunnelling with TBM (Tunnel Boring Machine), accessibility to tunnel face is very limited because tunnel face is mostly occupied by a bunch of machines. Existing techniques that can predict ground condition ahead of TBM tunnel are extremely limited. In this study, the TBM Resistivity Prediction (TRP) system has been developed for predicting anomalous zone ahead of tunnel face utilizing electrical resistivity. The applicability and prediction accuracy of the developed system has been verified by performing field tests at subway tunnel construction site in which an EPB (Earth Pressure Balanced) shield TBM was used for tunnelling work. The TRP system is able to predicts the location, thickness and electrical properties of anomalous zone by performing inverse analysis using measured resistivity of the ground. To make field tests possible, an apparatus was devised to attach electrode to tunnel face through the chamber. The electrode can be advanced from the chamber to the tunnel face to fully touch the ground in front of the tunnel face. In the 1st field test, none of the anomalous zone was predicted, because the rock around the tunnel face has the same resistivity and permittivity with the rock ahead of tunnel face. In the 2nd field test, 5 m thick anomalous zone was predicted with lower permittivity than that of the rock around the tunnel face. The test results match well with the ground condition predicted, respectively, from geophysical exploration, or directly obtained either from drilling boreholes or from daily observed muck condition.