• Title/Summary/Keyword: early hardening

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Co-Re-based alloys a new class of material for gas turbine applications at very high temperatures

  • Mukherji, D.;Rosler, J.;Wehrs, J.;Eckerlebe, H.;Gilles, R.
    • Advances in materials Research
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    • v.1 no.3
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    • pp.205-219
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    • 2012
  • Co-Re alloy development is prompted by the search for new materials for future gas turbines which can be used at temperatures considerably higher than the present day single crystal Ni-based superalloys. The Co-Re based alloys are designed to have very high melting range. Although Co-alloys are used in gas turbine applications today, the Co-Re system was never exploited for structural applications and basic knowledge on the system is lacking. The alloy development strategy therefore is based on studying alloying additions on simple model alloy compositions of ternary and quaternary base. Various strengthening possibilities have been explored and precipitation hardening through fine dispersion of MC type carbides was found to be a promising route. In the early stages of the development we are mainly dealing with polycrystalline alloys and therefore the grain boundary embrittlement needed to be addressed and boron addition was considered for improving the ductility. In this paper recent results on the effect of boron on the strength and ductility and the stability of the fine structure of the strengthening TaC precipitates are presented. In the beginning the alloy development strategy is briefly discussed.

Comparison of Strength-Maturity Models Accounting for Hydration Heat in Massive Walls

  • Yang, Keun-Hyeok;Mun, Jae-Sung;Kim, Do-Gyeum;Cho, Myung-Sug
    • International Journal of Concrete Structures and Materials
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    • v.10 no.1
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    • pp.47-60
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    • 2016
  • The objective of this study was to evaluate the capability of different strength-maturity models to account for the effect of the hydration heat on the in-place strength development of high-strength concrete specifically developed for nuclear facility structures under various ambient curing temperatures. To simulate the primary containment-vessel of a nuclear reactor, three 1200-mm-thick wall specimens were prepared and stored under isothermal conditions of approximately $5^{\circ}C$ (cold temperature), $20^{\circ}C$ (reference temperature), and $35^{\circ}C$ (hot temperature). The in situ compressive strengths of the mock-up walls were measured using cores drilled from the walls and compared with strengths estimated from various strength-maturity models considering the internal temperature rise owing to the hydration heat. The test results showed the initial apparent activation energies at the hardening phase were approximately 2 times higher than the apparent activation energies until the final setting. The differences between core strengths and field-cured cylinder strengths became more notable at early ages and with the decrease in the ambient curing temperature. The strength-maturity model proposed by Yang provides better reliability in estimating in situ strength of concrete than that of Kim et al. and Pinto and Schindler.

The Change of Full Width Half Maximum and Residual Stress during Fatigue Process in S45C Steel (피로과정에서 S45C강의 반가폭과 잔류응력의 변화양상)

  • Boo, Myung-Hwan;Park, Young-Chul;Kim, Byeong-Soo;Lee, Jong-Moon
    • Journal of the Korean Society for Nondestructive Testing
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    • v.22 no.5
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    • pp.539-544
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    • 2002
  • The purpose of this study is to examine the change of full width half maximum(FWHM) and residual stress during fatigue process in S45C Steel, by X-ray diffraction. For S45C Steel, the relationship between the change in fatigue damage of the specimen and the FWHM, and residual stress of X-ray diffraction profiles during the fatigue processes has been investigated. The FWHM decreases in the early period of fatigue cycle. The change of FWHM is associated with cyclic work hardening. The change of the FWHM is not significant in $10{\sim}20%$ of ratio of fatigue life. The residual stress is changed with fatigue cycle increasing during the fatigue pro process.

Electrodes for contact electric welding of aluminium alloys

  • Bondar, M.P.;Moon, J.G.
    • Proceedings of the KWS Conference
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    • 1997.10a
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    • pp.184-193
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    • 1997
  • Aluminium and aluminium alloys have the high electrical and heat conductivity. It gives rise to difficulties for a choice of electrodes material for their contact electric welding. This paper describes the investigations performed to solve the above problem. The purpose of this investigation was to obtain dispersion-hardening alloys by the internal oxidation method, to optimize their contents and treatment modes, to produce electrodes of these alloys and to test them. The strengthing effect of alloys with oxide particles depends on their size stability at high temperatures. Despite of the fact, that oxides are the most stable of all the non-metallic phases their coagulation takes place. Based on the early results, we chose two types of alloys, first No. 1 Cu - 0,4%Al and second No. 2 Cu - 0,2%Be for production of electrodes. These alloys had not additional alloying elements. These alloys were prepared as 1 mm plates and flake-formed 200 m thick, and also No. 1 as a powder of size 100 mkm (received from Korea). The large samples for electrodes were produced by three methods : explosive welding method, dynamic one including the explosion compression of electrode blank and the quasi-dynamic method including the high-speed compression of dense briquest and the further hot extrusion of a rod.

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Deformation Behavior of Corrosion-Resistant Fe-Cr Alloy

  • Era, Hidenori;Kono, Yusuke;Sasabuchi, Ryota;Miyoshi, Noriko;Tokunaga, Tatsuya;Shinozaki, Nobuya;Lee, Je-Hyun;Shimozaki, Toshitada
    • Applied Microscopy
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    • v.46 no.1
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    • pp.45-50
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    • 2016
  • Iron containing a high amount of chromium is known to be inferior to ductility due to ${\sigma}$ phase formation so that it is generally difficult to apply the plastic deformation process although the alloy possesses a superior characteristics of an excellent corrosion resistance. In this study, Fe-50mass%Cr alloy was melted using high purity powder and the deformation behavior has been investigated by cold rolling and tensile test. The tensile test yielded that the alloy revealed a serration at an early stage of tensile deformation and then the serrated flow vanished to change to a normal work hardening flow at the later stage. The former was governed by twin formation process, the latter by dislocation multiplication one, bringing about a high ductility of 20% or over. The reduction ratio in cold rolling was attained as high as 90%, thus the high corrosion-resistant alloy is able to possess a high ductility.

A Study on the Strength Properties and the Temperature Hysteresis of Winter Concrete according to the difference of Curing Method in Mock-up Test (실물대시험에서의 양생방법 차이에 따른 한중콘크리트의 온도이력 및 강도특성에 관한 연구)

  • Won, Cheol;Han, Cheon-Goo
    • Journal of the Korea Institute of Building Construction
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    • v.3 no.4
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    • pp.87-94
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    • 2003
  • This study is to investigate the temperature hysteresis and development of compressive strength due to the curing conditions and to evaluate the optimum curing condition of test specimens showing the same development of strength to that of real structures in cold weather. The results of temperature curve with curing conditions in mock-up tests showed the trend of decrease plain concrete with insulation form, plain concrete with heating, concrete with accelerator for freeze protection, and control concrete in turn. The strength development of plain concrete of inside and outside of shelter showed the very slow strength gains due to early freezing, but that of concrete with accelerator for freeze protection showed the gradual increase of strength with time. From this, it is clear that accelerator for freeze protection has the effects of refusing the freezing temperature and accelerating the hardening under low temperature. Strength test results of small specimens embedded in members and located in insulation boxes at the site are similar to that of cores drilled from the members at the same ages, thus it is clear that these curing methods are effective for evaluating in-place concrete strength

Effects of Strain Rate and Temperature on Tensile Properties of High Mn Twinning Induced Plasticity Steels (고망간 Twinning Induced Plasticity 강의 인장 특성에 미치는 변형률 속도와 온도의 영향)

  • Lee, Junghoon;Lee, Sunghak;Shin, Sang Yong
    • Korean Journal of Materials Research
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    • v.27 no.12
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    • pp.643-651
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    • 2017
  • Four types of high Mn TWIP(Twinning Induced Plasticity) steels were fabricated by varying the Mn and Al content, and the tensile properties were measured at various strain rates and temperatures. An examination of the tensile properties at room temperature revealed an increase in strength with increasing strain rate because mobile dislocations interacted rapidly with the dislocations in localized regions, whereas elongation and the number of serrations decreased. The strength decreased with increasing temperature, whereas the elongation increased. A martensitic transformation occurred in the 18Mn, 22Mn and 18Mn1.6Al steels tested at $-196^{\circ}C$ due to a decrease in the stacking fault energies with decreasing temperature. An examination of the tensile properties at $-196^{\circ}C$ showed that the strength of the non-Al added high Mn TWIP steels was high, whereas the elongation was low because of the martensitic transformation and brittle fracture mode. Although a martensitic transformation did not occur in the 18Mn1.9Al steel, the strength increased with decreasing temperature because many twins formed in the early stages of the tensile test and interacted rapidly with the dislocations.

Physical Properties and Quality Control of Foamed Concrete with Fly Ash for Cast-in-Site (플라이애쉬를 혼입한 현장타설 경량기포콘크리트의 물리적 특성 및 품질관리)

  • 이도헌;전명훈;고진수
    • Journal of the Korea Concrete Institute
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    • v.13 no.1
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    • pp.69-76
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    • 2001
  • Foamed concrete for cast-in-site, which shows excellent lightweight, thermal insulation, noise insulation, constructability and cost efficiency, has been applied as thermal insulation or filling material for On-dol. However, the technology is too insufficient to obtain the high level of quality, and serious problems often occur in quality control at sites. It, thus, is necessary to establish the proper and reasonable quality control method for ensuring the required quality, based on the investigation on the physical properties and their reciprocal relation. This study aims to settle the quality control method in case of applying FA foamed concrete replacing 40% by weight with fly-ash as the filling material for On-dol. The results of the study include the correlation among flow, as-placed density and foam ratio of fresh foamed concrete, the correlation between physical properties before hardening and after 28-day, provision of an equation to estimate 28-day compressive strength early with 7-day compressive strength, and suggestion of quality criteria for the revision of KS on foamed concrete for cast-in-site.

Strength Development and Freeze-Thaw Resistance of Concrete Incorporating High Volume Blast-Furnace Slag Subjected to Initial Frost Damage (초기동해를 받은 고로슬래그 다량 혼입 콘크리트의 강도발현 및 동결융해 저항성)

  • Koh, Kyung-Taek;Ryu, Gum-Sung
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.3
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    • pp.79-87
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    • 2011
  • Concrete incorporating high volume blast-furnace slag placed in cold weather regions might be in danger of initial frost damage because dependently on the mix proportions, the setting and the hardening would be remarkably delayed. Therefore, this study investigated to effect of the degree of frost on the strength development and the resistance to freezing and thawing of the concrete incorporating blast-furnace slag when being subjected to freeze at early age. As the experimental results, the concrete incorporating blast-furnace slag attacked by initial frost damage showed the remarkable reduction of both the compressive strength development and the resistance to freezing and thawing. Especially, the resistance to freezing-thawing of the concrete incorporating high volume blast-furnace slag became much lower than that of the normal concrete.

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A Moisture Diffusivity Model of Hardening Concrete (경화하는 콘크리트의 수분확산도 모형)

  • Jeong, Jin-Hoon
    • International Journal of Highway Engineering
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    • v.7 no.1 s.23
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    • pp.31-38
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    • 2005
  • Concrete has higher vapor pressure than its surrounding ambient air immediately after placement. Moisture at concrete surface evaporates to the ambient air to adjust equilibrium of the vapor pressure between them. The moisture inside the concrete moves to the surface because the evaporation at the surface causes gradient of vapor pressure inside the concrete. Plastic cracking, degree of hydration, strength development, and others caused by velocity of the moisture movement significantly influences quality of concrete. In this paper, the moisture diffusivity of early-age concrete was back-calculated using governing equation of the moisture diffusion, and temperature and relative humidity of concrete measured in a laboratory. The moisture diffusivity of the concrete was modeled using the back-calculated moisture diffusivity. The relative humidity of the concrete calculated by finite element method (FEM) using the modeled moisture diffusivity as Input data coincided with the measured relative humidity well.

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