• 멤브레인
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• 제17권2호
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• pp.140-145
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• 2007

본 연구에서는 공기 중의 수분을 선택적으로 제거하기 위해 poly(vinyl alcohol) (PVA) 에 가교제로서 poly(styrene sulfonic acid-eo-maleic acid) (PSSA-MA)와 막의 물에 대한 선택적 분리 특성을 향상시키기 위해 3-(trihydroxysilyl)-1-propanesulfonic acid (THS-PSA) 를 첨가하여 막을 제조하였다. PSSA_MA 와 THS-PSA의 양과 가교온도를 변화시켜 가며 막을 제조하였다. 또한 제조된 막의 분리특성을 살펴보기 위해 동적증기용해도와 증기투과 실험을 수행하였다. 동적증기용해도 실험으로부터 가교온도의 증가는 평형 용해 상태에 도달하는데 더 오래 걸리는 것을 알 수 있었다. $120^{\circ}C$에서 제조 된 PVA/PSSA_MA (3%)/THA-PSA(7%) 막이 $35^{\circ}C$에서 가장 투과도가 높은 480 barrer를 나타내었다.

• 한국수산과학회지
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• 제14권4호
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• pp.189-193
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• 1981

등온흡습곡선측정시의 건제품이 주어진 대상습도에서 평형에 이르는 시간을 단축시키기 위하여 조절기류를 이용하는 장치를 만들고, 이를 이용하여 $25^{\circ}C$에서 말쥐치 건제품의 등온흡습곡선을 측정하였다. 1. 조절기류를 이용함으로써 주어진 수분활성에서보다 높은 수분활성에 이르는 시간을 평균 45 시간으로 단축시킬 수 있었다. 2. 단분자의 수분함양은 고형물 1kg당 0.092kg이었으며, 건조말쥐치의 제품에 대하여 $8.42\%$였다. Symbols used in the text A : surface, $m^2$ $a_w$: water activity $A_s$ : specific surface, $m^2/kg$ dry matter C : constant related to the heat of adsorption $K_g$ : gas film coefficient of mass transfer, $kg water/hr{\cdot}Pa{\cdot}m^2$ n : number of molecular layers $n_s$ : moisture content, kg water /kg dry matter $n_{sa}$ : mean moisture content, kg water/kg dry matter $n_{se}$ : equilibrium moisture content, kg water/kg dry matter $n_{sm}$ : moisture content for monolayer, kg water/kg dry matter $P_g$ : saturated vapor pressure at wet-bulb temperature, Pa $P_a$ : partial vapor pressure of water in air, Pa $R_d$ : resistance factor against diffusion, $m^2{\cdot}hr/kg$ dry matter $R_s$ : resistance factor against drying, $m^2{\cdot}hr/kg$ dry matter R.H. : relative humidity, $\%$ $\varphi$ : R.H./100

• 한국환경보건학회지
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• 제34권3호
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• pp.219-225
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• 2008

Many building materials may contain high concentrations of volatile organic compounds (VOCs) and other hazardous pollutants(HAPs). Specifically, VOCs discharged by indoor building material may cause "new house" syndrome, atopic dermatitis etc. The diffusion coefficient and initially contained total VOC quantity were determined using microbalance experiments and small chamber tests. Interactions between volatile organic compounds (VOCs) and vinyl flooring (VF), a relatively homogenous, diffusion-controlled building material, were characterized. Rapid determination of the material/air partition coefficient (K) and the material-phase diffusion coefficient (D) for each VOC was achieved by placing thin VF slabs in a dynamic microbalance and subjecting them to controlled sorption/desorption cycles. K and D are shown to be independent of concentration for all of the VOCs and water vapor. This approach can be applied to other diffusion-controlled materials and should facilitate the prediction of their source/sink behavior using physically-based models.

• 한국수소및신에너지학회논문집
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• 제32권5호
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• pp.285-292
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• 2021

To study the effect of the mixture ratio of Ni-Pt nanocatalysts on water electrolysis characteristics in anion exchange membrane system, Ni-Pt nanocatalysts were loaded on carbon black by using a spontaneous reduction reaction of acetylacetonate compounds. The loading weight of Ni-Pt nanocatalysts on the carbon black was measured by thermogravimetric analyzer and the elemental ratio of Ni and Pt was estimated by energy dispersive x-ray analyzer. It was found that the loading weight of Ni-Pt nanoparticles was 5.36-5.95 wt%, and the loading weight increased with increasing Pt wt%. As the Ni-Pt loading weight increased, the specific surface area decreased, because Ni-Pt nanoparticles block the pores of carbon black. It was confirmed by BET analysis and dynamic vapor sorption analysis. I-V characteristics were estimated.

• 한국수소및신에너지학회논문집
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• 제23권4호
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• pp.310-315
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• 2012

A simple drying process was developed for the preparation of a Pt/Nafion self-humidifying membrane to be used for a proton-exchange membrane fuel cell (PEMFC). Platinum (II) bis (acetylacetonate), $Pt(acac)_2$ was sublimed, penetrated into the surface of a Nafion film and then reduced to Pt nanoparticles simultaneously without any support of a reducing agent in a glass reactor at $180^{\circ}C$ for 15 min. The process was carried out in $N_2$ atmosphere to prevent the oxidation of Pt nanoparticles at high temperature. The morphology and distribution of the Pt nanoparticles were observed by transmission electron microscopy (TEM) and energy dispersive spectroscopy (EDS), and we found that the average Pt particle size was ca. 3.7 nm, the penetration depth was ca. $17{\mu}m$. Almost all Pt nanoparticles were formed just beneath the surface and the number density decreased rapidly as the penetration depth increased. To estimate water absorption characteristics of the Nafion membranes, water uptake at an isothermal condition was measured by dynamic vapor sorption (DVS), and it was found that water uptake of the Pt/Nafion membrane was higher than that of the neat Nafion membrane.