• Journal of the Korea Concrete Institute
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• v.23 no.3
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• pp.295-301
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• 2011

Recently, the use of UHPC made of superplasticizers, silica fume, and steel fibers has been increasing worldwide. Although UHPC has a very high strength as well as an excellent durability performance due to its dense microstructures, earlyage cracks may occur due to the high heat of hydration and autogenous shrinkage caused by low W/B and high unit cement content. The early-age shrinkage cracking of UHPC can be controlled by using the shrinkage reducers and expansive admixtures having autogenous shrinkage compensation effect. In this paper, ultrasonic pulse velocity of UHPC containing shrinkage reducers and expansive agents was measured to predict its stiffness change. Also, the effect of shrinkage reducers and expansive agents on the autogenous shinkage of UHPC was investigated through the shrinkage test of UHPC specimens. Furthermore, the material coefficients of autogenous shrinkage prediction model were determined using the autogenous shrinkage values of UHPC with age. Consequently, the test results showed that, by adding shrinkage reducers and expansive agents, the stiffness of UHPC was rapidly developed at early-ages and the autogenous shrinkage was considerably reduced.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.533-536
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• 2008

Recently, in Korea, there has been an increasing number of research papers published which are to improve durability of concrete, particularly by analyzing correlation between diffusivity of chloride and porosity/pore size distribution. In these studies, such test methods as mercury intrusion porosimetry(MIP), gas adsorption or image analysis method are used to analyze the microstructure of materials while MIP is most widely used for concrete. This study analyzes the results of porosity and pore size distribution of paste and concrete adding fly ash or blast furnace slag by using MIP equipment which is widely used for determining micro-porosity structure of cementitious materials. A variation in porosity and pore size distribution at the curing day 3, 7 and 28 has been observed by using MIP equipment for cement paste 35%, 40%, 45%, 50%, 55%, 60% of W/C when using $300kg/m^3$ of cement, 35%, 45%, 55% of W/C when replaced 60% with blast-furnace slag, and 35%, 45%, 55% of W/C when replaced 30% with fly ash. For long-term water cured normal OPC concrete and mixed concrete replaced 60% with blast-furnace slag powder, micro-structure of the sample has been analyzed by using MIP equipment when W/C indicated 40%, 45%, 50% respectively and the binder varied $300kg/m^3$, $350kg/m^3$, $400kg/m^3$, and $450kg/m^3$.

• Journal of the Korean Recycled Construction Resources Institute
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• v.3 no.3
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• pp.268-276
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• 2015

In this study, $CO_2$ reduction type quaternary component high fluidity concrete was produced with more than 80% reduction in cement quantity to increase the use of industrial byproducts and enhance construction performance, thereby reducing $CO_2$ emissions. Furthermore, the quality properties, and $CO_2$ reduction performance of this concrete were evaluated. As a result of the quality evaluation of quaternary component blended high fluidity concrete with $CO_2$ reduction, the target performance could be achieved with a 80% or more reduction of cement quantity by mixing a large amount of industrial byproducts. The required performance level was obtained even though the flow, dynamic, and durability characteristics decreased a little compared to conventional mix. In addition, to analyze the $CO_2$ reduction performance of quaternary component blended high fluidity concrete with $CO_2$ reduction, the life cycle assessment (LCA) of the concrete was performed and the results showed that compared to the conventional mix, the carbon emissions decreased by 62.2% and the manufacturing cost by 24.5%.

• Computers and Concrete
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• v.3 no.5
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• pp.301-312
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• 2006

Experimental research revealed that the spatial dispersion of aggregate grains exerts pronounced influences on the mechanical and durability properties of concrete. Therefore, insight into this phenomenon is of paramount importance. Experimental approaches do not provide direct access to three-dimensional spacing information in concrete, however. Contrarily, simulation approaches are mostly deficient in generating packing systems of aggregate grains with sufficient density. This paper therefore employs a dynamic simulation system (with the acronym SPACE), allowing the generation of dense random packing of grains, representative for concrete aggregates. This paper studies by means of SPACE packing structures of aggregates with a Fuller type of size distribution, generally accepted as a suitable approximation for actual aggregate systems. Mean free spacing $\bar{\lambda}$, mean nearest neighbour distance (NND) between grain centres $\bar{\Delta}_3$, and the probability density function of ${\Delta}_3$ are used to characterize the spatial dispersion of aggregate grains in model concretes. Influences on these spacing parameters are studied of volume fraction and the size range of aggregate grains. The values of these descriptors are estimated by means of stereological tools, whereupon the calculation results are compared with measurements. The simulation results indicate that the size range of aggregate grains has a more pronounced influence on the spacing parameters than exerted by the volume fraction of aggregate. At relatively high volume density of aggregates, as met in the present cases, theoretical and experimental values are found quite similar. The mean free spacing is known to be independent of the actual dispersion characteristics (Underwood 1968); it is a structural parameter governed by material composition. Moreover, scatter of the mean free spacing among the serial sections of the model concrete in the simulation study is relatively small, demonstrating the sample size to be representative for composition homogeneity of aggregate grains. The distribution of ${\Delta}_3$ observed in this study is markedly skew, indicating a concentration of relatively small values of ${\Delta}_3$. The estimate of the size of the representative volume element (RVE) for configuration homogeneity based on NND exceeds by one order of magnitude the estimate for structure-insensitive properties. This is in accordance with predictions of Brown (1965) for composition and configuration homogeneity (corresponding to structure-insensitive and structure-sensitive properties) of conglomerates.

• Clean Technology
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• v.14 no.1
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• pp.61-68
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• 2008

There have been great attentions on polymer electrolyte membrane fuel cell (PEMFC) due to their advantageous characteristics such as zero emission of hazardous pollutant and high energy density. In this work, we evaluated degradation phenomena and stability of single cell performance via one dimensional single cell modeling. Here, CO poisoning on anode on anode was considered for cell performance degradation. Modeling results showed that the performance and stability were highly degraded with CO concentration in fuel gas. In addition, cell performance was reduced by slow oxygen reduction on cathode in long term operation. In order to overcome, it is required to increase ratio o#hydrogen in the fuel gas of anode and high Pt loading contained in the cathodic catalyst layer.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.22 no.6
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• pp.617-625
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• 2009

This study is devoted to the problems of thermal and autogenous expansion stresses in order to avoid cracking using chemically prestressing method. The chemical prestress can be induced by autogenous expansion characteristics of MgO concrete made in specific burning temperature. The volume change induced cracking has great influence on the long-term durability and serviceability. To evaluate risk of cracking, the computer programs for analysis of thermal and autogenous expansion stresses were developed. In these 3-D finite element procedures, long-term autogenous expansive deformation is modeled and its resultant stress is calculated and then verified by comparison with manual calculation results. In this study, the stress development is related to thermal and autogenous expansive deformation. Using the developed program, residual stresses of MgO concrete were compared and analysed in the example From the numerical results it is found that long-term, and temperature dependent expansive concrete with light-burnt MgO is most effective in controlling the risk of cracking of mass concrete because it has high temperature for long period. The developed analysis program can be efficiently utilized as a useful tool to evaluate the thermal and autogenous expansion stresses in mass concrete structures with lightly burnt MgO.

• Journal of Life Science
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• v.19 no.7
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• pp.899-904
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• 2009

We purified crude urushiol from natural lacquer produced in Korea, China, and Japan and then isolated several urushiol congeners known to induce allergic reactions. The 3 major kinds of urushiol congeners that were isolated and purified were RV-l (C$_{21}$H$_{34}$O$_2$, M.W. 314.462), RV-2 ((C$_{21}$H$_{32}$O$_2$, M.W. 316.240) and RV-3 ((C$_{23}$H$_{34}$O$_2$, M.W. 342.515), occupying 80% of total crude urushiol. The content of RV-l was the highest in natural lacquer from China at 70.07%, and was the lowest in that from Japan at 62.38%. However, the content of RV-2 in natural lacquer from Japan was 9.25%, 2$\sim$3 times higher than those from Korea (4.28%) and China (3.09%). As an allergy inducing character, RV-l had strong inducing power and durability in the primary stage, showing slow recovery. RV-2 had weak power in the primary stage and also showed slow recovery. Although RV-3 had comparatively weak power at the primary stage, it induced the strongest allergy contact dermatitis after 48 hr. However, it recovered to nearly the same level as control group 72 hr after sensitization time. Accordingly, we found out that RV-1 is the most influential of urushiol congeners in inducing allergic reactions, natural lacquer from China having the most inducible strength and slowest recovery compared to those from Korea and Japan.

• Membrane Journal
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• v.19 no.4
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• pp.324-332
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• 2009

This study aimed to measure chemical resistance properties of the microfiltration flat-sheet membrane made by Chlorinated Polyvinyl Chloride (CPVC) with respect to the immersed time. The solutions of effective chlorine 0.5 wt% NaClO, HCl 1 wt% and pH 4 buffer under acidic condition, NaOH 4 wt% and pH 10 buffer under alkine condition were used as widely applied chemicals for membrane washing. The CPVC membrane samples were immersed in the above chemical solutions during 1, 3, 5 and 10 days at 5, 25 and $50^{\circ}C$, respectively. After then, the tensile strength and elongation at break as the chemical durability for the samples were measured and evaluated. The tensile strength decreased within 5% at $5^{\circ}C$, but decreased up to 17% at 25 and $50^{\circ}C$ for 0.5 wt% NaClO solution mainly used for membrane cleaning. The chemical resistance of CPVC membrane was good enough for HCl 1 wt% and pH 4 buffer acid solutions, but the most vulnerable for NaOH 4 wt% solution.

• Journal of the Korean Society for Marine Environment & Energy
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• v.17 no.2
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• pp.81-89
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• 2014

The present study aims to design an optimized hull shape of a floating pendulum-type wave energy converter(WEC). The purpose of these structure is to improve the performance and stability of the WEC by reducing its motion under operating and survival wave conditions. In this study, motion reduction structures, like restoring and dampling plates were installed on a floating pendulum WEC that has been the subject of previous studies. Restoring plates were installed to increase the restoring force and shift the natural period to a shorter period. Damping plates were installed to shift the natural period to a longer period by increasing the added mass. The effects of the structures were then analyzed under different incident wave conditions. The design parameters for the motion reduction structures were size, shape, and installed position. The wave-induced motion characteristics and performance of the floating pendulum WEC were also investigated numerically. Based on the simulation results, we are able to optimize the motion reduction structure of the WEC, thus improving its efficiency and durability.

• Journal of the Korea Concrete Institute
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• v.20 no.2
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• pp.185-191
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• 2008

To fundamentally solve the problem of deterioration of concrete structures, it has been researched that the high durable concrete structure reinforced with the FRP rebar can be one of major solution to the newly-developed concrete structure. FRP rebar has lots of advantages such as non-corrosive, high performance and light weight against the conventional steel rebar. Among these kinds of FRP rebars, GFRP rebar has usually been considered as the best reinforcement because of its economic point of view. Even though the material capacity of the GFRP rebar was already investigated, there are some problems such as low modulus of elastic that will be cause for degrade of the serviceability of flexural concrete member reinforced with the GFRP rebar. Thus, the deflection characteristics of the GFRP rebar reinforced concrete structure should be considered then investigated. In this study, ACI 440 guideline (2003), ISIS Canada Design Manual (2001) and Toutanji et al. (2000) was considered for predicting the moment of inertia of the concrete beam reinforced with the GFRP rebar. And it was also evaluated that load-deflection relationship had a good accordance with the test and analysis result. In the result of this study, it could be estimated that the load-deflection relationship using the suggested equation of moment of inertia in this study indicated better accordance with the test result than that of the others until failure.